scholarly journals Hydrothermal Synthesis and Characterization of Zeolite A from Corn (Zea Mays) Stover Ash

Materials ◽  
2021 ◽  
Vol 14 (17) ◽  
pp. 4915
Author(s):  
Norway Pangan ◽  
Susan Gallardo ◽  
Pag-asa Gaspillo ◽  
Winarto Kurniawan ◽  
Hirofumi Hinode ◽  
...  
Keyword(s):  
Hydrothermal Synthesis ◽  
Cation Exchange ◽  
Corn Stover ◽  
Cation Exchange Capacity ◽  
Thermo Gravimetric Analysis ◽  
Exchange Capacity ◽  
Gravimetric Analysis ◽  
Curing Time ◽  
Zeolite A ◽  
The Impact

This study deals with the impact of calcination, alkalinity, and curing time parameters on the hydrothermal synthesis of zeolite A. The zeolite A sample, produced from corncob-stalk-and-leaves (corn stover) ash was characterized using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), thermo-gravimetric analysis (TGA), and scanning electron microscopy (SEM). The results showed that calcination, alkalinity, and curing time have significant effects on the crystallization and the morphology of zeolite A. In addition, these parameters also impacted the cation exchange capacity. Furthermore, the synthesized zeolite A was obtained using a calcination temperature of 5000 °C within two hours of airflow, which is much lower than the temperatures previously reported in the literature for an agricultural waste and other waste materials. A fusion ratio of corn stover ash:NaOH of 1.0:1.5 and a curing time of nine hours were achieved. This is a major result as this curing time is much lower than those featured in other studies, which can reach up to twenty-four hours. In this paper, cubic crystal with rounded edge of zeolite A, having a cation exchange capacity of 2.439 meq Na+/g of synthesized anhydrous zeolite A, was obtained, which can be a good candidate for ion-exchange separation.

The Impact of Plant Hedgerow in Three Gorges on the Soil Chemicophysical Properties and Soil Erosion

2012 ◽  
Vol 500 ◽  
pp. 142-148 ◽  
Author(s):  
Wen Xing Lü ◽  
Hong Jiang Zhang ◽  
Yu He Wu ◽  
Jin Hua Cheng ◽  
Jian Qiang Li ◽  
...  
Keyword(s):  
Organic Matter ◽  
Soil Erosion ◽  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
Exchange Capacity ◽  
Citrus Reticulata ◽  
Three Gorges ◽  
Zanthoxylum Bungeanum ◽  
The Impact ◽  
Nitrogen Phosphorus

Through the research and sampling analysis on different plant hedgerow in sloped farmland in Three Gorges reservoir area, we will conduct research on the impact of plant hedgerow in Three Gorges on the chemicophysical properties of soil and soil erosion. The results show that the plant hedgerow mainly composed by Morus alba, Citrus reticulata, Zanthoxylum bungeanum, Vitex negundoand Begonia fimbristipula can decrease the soil density as well as sand content and increase soil porosity, soil water content, silt content and clay content to some extent. The organic matter, nitrogen, phosphorus, potassium and cation exchange capacity and other chemical indices of soil in different locations in plant hedgerow indicate as maximum in on-band, minimum in inter-band, middle both upper-band and below-band. In the same slop with no plant hedgerow, the organic matter, nitrogen, phosphorus, potassium and cation exchange capacity and other chemical indices of soil show a trend of increasing from the top to the bottom of the slop, which reveals that these substances own a feature of accumulation by moving to the bottom. The strength of soil anti-corrosion in different plant hedgerow is: Vitex negundoand (79.2%)> Citrus reticulata (36.4%)> Morus alb (22.4%)> Zanthoxylum bungeanum (18.9%)> Begonia fimbristipula (15.3%)> CK (8.7%), and the soil anti-corrosion indices in plant hedgerow are decreasing with the increase of soil immersion time, besides, the former and the latter are 3 times polynomial function. For those 5 plant hedgerows, Vitex negundoand owns the best impact on improving soil chemicophysical properties and reducing soil erosion.

Impacts of whole-tree harvesting and winter windrowing on soil pH and base status of clayey sites of northwestern Quebec

1995 ◽  
Vol 25 (6) ◽  
pp. 997-1007 ◽  
Author(s):  
S. Brais ◽  
C. Camiré ◽  
D. Paré
Keyword(s):  
Cation Exchange ◽  
Soil Ph ◽  
Forest Floor ◽  
Cation Exchange Capacity ◽  
Exchange Capacity ◽  
Exchangeable Ca ◽  
Whole Tree Harvesting ◽  
The Impact ◽  
Whole Tree ◽  
Tree Harvesting

To assess the impact of forest operations on soil nutrient status, modifications to forest floor, to 0–10 and 10–20 cm mineral soil base status, and to pH were evaluated 5–12 years following whole-tree harvesting and winter windrowing on dry to fresh and moist clayey sites in the clay belt region of northwestern Quebec. Whole-tree harvesting had few impacts on base concentrations and soil pH of dry to fresh sites. On moist sites, significant decreases in pH (−0.60 to −0.84 units), exchangeable Ca, total Ca, and, exchangeable Mg concentrations, base saturation, and effective cation exchange capacity were observed following harvesting. On dry to fresh sites, a decrease in the forest floor weight (−55%) accounted for significant reductions in exchangeable Ca (−55%), total Ca (−61%), and exchangeable K (−40%) pools in this layer, while reserves of both mineral layers were not affected. On moist sites, significant decreases in exchangeable Ca (−42 to −65%) and Mg (−35 to −56%) reserves occurred in all soil layers, while forest floor reserves of total Ca, Mg, and K decreased by 67, 48, and 40%, respectively. These reductions were caused by a loss of substrate in the forest floor (−44%) and a decrease in effective cation exchange capacity, exchangeable Ca saturation, and total Ca concentrations. Impacts of windrowing following whole-tree harvesting were limited to a reduction in reserves of exchangeable Ca (−22%), exchangeable Mg (−27%), total Ca (−20%), and total Mg (−29%) pools of the forest floor of moist sites. Values reported here are much greater than values generally predicted by a balance sheet approach and underline the need for more process-oriented studies. Impacts of these losses on long-term site productivity remain to be investigated.

Recycling of Municipal Solid Waste Ash Through an Innovative Technology to Produce Commercial Zeolite Material of High Cation Exchange Capacity

2008 ◽  
Author(s):  
Maysson Sallam ◽  
Robert P. Carnahan ◽  
Abla Zayed ◽  
Sermin Sunol
Keyword(s):  
Municipal Solid Waste ◽  
Cation Exchange ◽  
Solid Waste ◽  
Cation Exchange Capacity ◽  
Exchange Capacity ◽  
Ammonia Removal ◽  
Innovative Technology ◽  
Acetate Solution ◽  
Zeolite A ◽  
Solid Waste Ash

Municipal solid waste ash (MSW ash) samples, obtained from a local incinerator in Florida, were converted via a chemical process into zeolite material. The conversion process was performed by applying a two step treatment. The ash samples were fused at 550°C under alkaline conditions and then the fused ash samples were treated hydro-thermally at 60 °C and 100°C for different periods. This innovative technology involves adjusting the SiO2/Al2O3 ratio of the ash from 13.9 to 2.5 by adding sodium aluminates and by using a solid to liquid ratio of 10. The fusion step formed sodium silicate and sodium aluminum silicate phases. These phases acted as precursors to the formation of zeolite A. Zeolite A was successfully formed within the ash matrix when samples were fused and SiO2/Al2O3 was adjusted. The maximum cation exchange capacity, CEC, was measured by using ammonium acetate solution. The CEC of the produced zeolitic ash material has increased significantly from 17 meq/100g for non-treated ash up to 212 meq/100g for the treated ash. The cation exchange capacity of the produced zeolite ash material is close to that available from commercial zeolite materials which have a CEC of 245meq/100g. Zeolite A formation within the ash matrix increased the potential of using the ash as an adsorbent for industrial and environmental applications including ammonia removal from waste water or any other similar application that involves cation exchange.

scholarly journals Effect of Salmonella on Decomposition of Poultry Litter

2018 ◽  
Vol 10 (1) ◽  
pp. 51-60 ◽  
Author(s):  
M. Mushtaq ◽  
H. Kasur ◽  
R. A. Khan ◽  
A. Khalid ◽  
M. K. Iqbal
Keyword(s):  
Physicochemical Properties ◽  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
Poultry Litter ◽  
Exchange Capacity ◽  
Degree Of Polymerization ◽  
Human Pathogens ◽  
Humification Index ◽  
Nitrogen Ratio ◽  
The Impact

Chicken litter is a significant source of nutrients for production of crops and to reduce the impact of human pathogens on environment. The physicochemical properties of poultry litter mixture compost was assessed against the maturity and stability indices such as carbon nitrogen ratio (C/N), nitrate (NO3), ammonia (NH3), ash, Cation Exchange Capacity (CEC), Humification Index (HI), Humification Rate (HR) and Degree of Polymerization (DP). The use of Salmonella significantly improves the humification process and physicochemical properties of final compost product are better in comparison to control trial. The most prominent effects was the fast rise in temperature from mesophilic to thermophilic stage was accompanied by an increase in NH4+-N that gradually decrease near the maturation phase. Moreover, the decrease in carbon and nitrogen ratio and increase in DP, CEC, HI, HR, phosphorous and potassium was also observed. A significant correlation was found between the maturity and stability parameters like C: N ratio, cation exchange capacity, humification index, degree of polymerization, humification rate and nitrate. Therefore, it is acclaimed that isolated microorganisms Salmonella from poultry litter promote the stable compost formation.

scholarly journals Management of Solid Waste Deposited in Landfill of Used Motor Oil Recovery Units Via Production of Zeolite A With Proper Cation Exchange Capacity by Fusion Technique

2021 ◽  
Author(s):  
Fatemeh Amir Aslanzadeh Mamaghani ◽  
Amin Salem ◽  
Shiva Salem
Keyword(s):  
Cation Exchange ◽  
Solid Waste ◽  
Oil Recovery ◽  
Cation Exchange Capacity ◽  
Morphological Evolution ◽  
Exchange Capacity ◽  
Motor Oil ◽  
Zeolite A ◽  
Fusion Technique ◽  
Used Motor Oil

Abstract The efficient management of solid waste deposited in the landfill of used motor oil recovery units is an important environmental challenge which is originated from the regeneration by bentonite as an effective adsorbent. The current study was attempted to convert the black waste into zeolite based compounds through fusion technique. The collected waste powder were mixed with sodium hydroxide, and boehmite followed by treatment at different temperatures, 600-800 °C. Then, the obtained precursors were hydrothermally converted to zeolite A or hydroxysodalite. The effect of parameters like alkalinity, boehmite, and sodium aluminate ratios, fusion temperature, and aging time on structural characteristics, and cation exchange capacity (CEC) were studied in details. The potential of solid waste in the production of zeolite A is significantly affected by mentioned factors which govern on purity, crystallinity, morphology, and CEC. The cation exchange capacity about 190 mg g-1 can be achieved by alkali, and boehmite ratios of 2.00, and 0.53, respectively. The microstructural analyses showed the morphological evolution from rounded shape to sharp edges by fusion at 800 °C due to appropriate recrystallization. Besides, hydrosodalite powder with extended surface area, 77 m2 g-1, could be produced by limited content of boehmite in the presence of NaAlO2.

scholarly journals Synthesis of Zeolitic Material with High Cation Exchange Capacity from Paper Sludge Ash Using EDTA

2021 ◽  
Vol 11 (23) ◽  
pp. 11231
Author(s):  
Takaaki Wajima
Keyword(s):  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
Ethylenediaminetetraacetic Acid ◽  
Exchange Capacity ◽  
Paper Sludge ◽  
Zeolite Synthesis ◽  
Zeolite A ◽  
Paper Sludge Ash ◽  
Sludge Ash ◽  
High Cation Exchange Capacity

Paper sludge ash (PSA) typically has a low Si abundance and significant Ca content because of the presence of calcite fillers, which interfere with the zeolitic conversion of PSA. Ca-masking with ethylenediaminetetraacetic acid (EDTA) was used to reduce Ca interference during zeolite synthesis so that a zeolitic product with a high cation exchange capacity (CEC) could be synthesized. Hydroxysodalite, zeolite-P, hydroxycancrinite, tobermorite, and zeolite-A can be synthesized from PSA by an alkali reaction with EDTA. With the addition of EDTA, calcium ions in the solution were trapped by chelation, and the number of zeolitic crystals with low Si/Al (Si/Al = 1), zeolite-A, increased owing to the promotion of the synthesis reaction. A product with a high CEC that has a high zeolite-A content was obtained. The chelating agent can inhibit Ca interference for zeolite synthesis by Ca-masking, and a product with a high zeolite-A content can be obtained from PSA using EDTA.

EVALUASI PERUBAHAN KUALITAS TANAH PADA LAHAN BEKAS PENAMBANGAN NIKEL DI PULAU GEBE

2018 ◽  
Vol 4 (1) ◽  
Author(s):  
Mardi Wibowo
Keyword(s):  
Organic Carbon ◽  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
Exchange Capacity ◽  
Mining Activity ◽  
Evaluation Activity ◽  
Land Quality ◽  
Environment Quality

Since year 1977 until 2005, PT. ANTAM has been exploited nickel ore resources at Gebe Island – Center ofHalmahera District – North Maluku Province. Mining activity, beside give economically advantages also causedegradation of environment quality espicially land quality. Therefore, it need evaluation activity for change ofland quality at Gebe Island after mining activity.From chemical rehabilitation aspect, post mining land and rehabilitation land indacate very lack and lackfertility (base saturated 45,87 – 99,6%; cation exchange capacity 9,43 – 12,43%; Organic Carbon 1,12 –2,31%). From availability of nutrirnt element aspect, post mining land and rehabilitation land indicate verylack and lack fertility (nitrogen 0,1 – 1,19%). Base on that data, it can be concluded that land reclamationactivity not yet achieve standart condition of chemical land.Key words : land quality, post mining lan

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