scholarly journals Algorithmic Modelling of Advanced Chlorination Procedures for Multimetal Recovery

Metals ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 1595
Author(s):  
Lukas Höber ◽  
Roberto Lerche ◽  
Stefan Steinlechner

In the course of developing an innovative process for CO2-optimised valuable metal recovery from precipitation residues accumulating in the zinc industry or nickel industry, the chlorination reactions were investigated. As the basis of small-scale pyrometallurgical experiments, the selected reaction systems were evaluated by means of thermodynamic calculations. With the help of the thermochemical computation software FactSage (Version 8.0), it is possible to simulate the potential valuable metal recovery from residual materials such as jarosite and goethite. In the course of the described investigations, an algorithmically supported simulation scheme was developed by means of Python 3 programming language. The algorithm determines the optimal process parameters for the chlorination of valuable metals, whereby up to 10,000 scenarios can be processed per iteration. This considers the mutual influences and secondary conditions that are neglected in individual calculations.

2020 ◽  
Vol 898 ◽  
pp. 23-28
Author(s):  
Himawan Tri Bayu Murti Petrus ◽  
Hotden Manurung ◽  
Rivky Juarsa Aditya ◽  
Rifani Amanda ◽  
Widi Astuti

Spent catalyst is listed as one of the hazardous wastes. Based on the toxicity characteristic shows that spent catalyst contains some heavy metals at concentration above the regulations limits. This situattion becomes an important issue in nowadays. In this research, fungus Aspergillus niger was investigated to produce weak organic acid (citric acid). Batch experiments were performed to compare the leaching efficiency from spent catalyst of pulp density (2% and 4%) and particle size (212 µm, 150 µm and 75 µm). Result showed that after direct bioleaching process, maximum recovery of valuable metal 24.94%, 7.42%, 1.09%, 3.51%, 4.87% and 1.66% were achieved for aluminum, calcium, iron, copper, silver and platinum respectively at 2% pulp density. Overall data shows that metal recovery at pulp density 2% are higher than 4% pulp density. The maximum recovery based on particle size shows that the smaller particle (75 µm) the higher metal recovery (Al, Ag and Pt) and for some metals was different such as Fe, Cu and Ca.


2018 ◽  
Vol 775 ◽  
pp. 419-426 ◽  
Author(s):  
Wei Sheng Chen ◽  
Hsing Jung Ho

The paper concerns an approach about using environmental technology and hydrometallurgical process to the recovery of valuable metal from waste cathode material produced during the manufacture of lithium-ion batteries. It is noteworthy that the content of nickel, manganese and cobalt from cathode material are in the extraordinary large proportion. In the acid leaching step, the essential effects of H2SO4 concentration, H2O2 concentration, leaching time, liquid-solid mass ratio and reaction temperature with the leaching percentage were investigated. The cathode material was leached with 2M H2SO4 and 10 vol.% H2O2 at 70 °C and 300 rpm using a liquid-solid mass ratio of 30 ml/g and the leaching efficiency of cobalt was 98.5%, lithium was 99.8%, nickel was 98.6% and manganese was 98.6% under optimum conditions. Kinetic study demonstrates the activation energies for those analyzed metals with Arrhenius equation and manifests the data with hybrid reaction control mechanism. The process was proved from activation energies ranged from 27.79 to 47.25 kJ/mol. Finally, the valuable metals will be leached in sulfuric acid effectively.


2012 ◽  
Vol 588-589 ◽  
pp. 1671-1676
Author(s):  
Shao Jun Bai ◽  
Shu Ming Wen ◽  
Qi Cheng Feng ◽  
Yu Chen ◽  
Jian Liu

A new technology of pellet production-drying-chloridizing roasting is proposed for valuable metal recovery from pyrite cinder with high content of lead and zinc. The pyrite cinder, containing 60.15% Fe, 2.02% Pb and 2.15% Zn, was pelletized with addition of 2% bentonite in pan pelletizer. Green balls after drying were roasting at 1100 °C for 60 min with 5 wt % of CaCl2 addition in tube furnace. The results demonstrate that pellets with 61.58% of TFe, lead and zinc volatile ratios of 98.02% and 96.83% were obtained. Key technique is that CaCl2 reacts with lead and zinc compounds and the chloride can be volatilized at moderate temperatures. This new technology can recover the valuable metal fully from pyrite cinder and produce qualified concentrate as iron-bearing feed for steel industry, which will help to solve the pollution of pyrite cinder and extend raw material sourcing for Chinese steel industry.


2017 ◽  
Vol 730 ◽  
pp. 226-230 ◽  
Author(s):  
Xing Lan Cui ◽  
Hao En Zuo ◽  
Jian Kang Wen

The experiment focused on the Deerni pyrite roasting residues mainly made of magnetic materials such as hematite and magnetite in Qinghai Deerni Copper Deposit. The method of bioleaching sulfuric acid residue by bacteria was proposed for roasting residues desulfurization and valuable metal extraction. First of all, the study systematically performed multi-elements analysis, which provided scientific and technique basis for extraction of valuable metals. Subsequently, the effect of the pH value on the bacterial growth was investigated. The data revealed that pH at 1.2 was the optimum culture condition for the bacteria. The concentration of the bacteria at the best culture condition reached 8.5×107 cells/mL. Finally, the bioleaching experiments were performed to explore the ability of the NB bacteria to oxidize the Deerni pyrite roasting residues. The study demonstrated that the microorganism was able to effectively extract valuable metals such as copper and zinc. The total Fe and sulfur contents of the bioleaching residues account for 68.38% and 0.39%, respectively. The desulfurization effects are evident and bioleaching residues meet the requirements as magnetic materials in steel making industry.


Author(s):  
Michael Schlüter ◽  
Sonja Herres-Pawlis ◽  
Ulrich Nieken ◽  
Ute Tuttlies ◽  
Dieter Bothe

Improving the yield and selectivity of chemical reactions is one of the challenging tasks in paving the way for a more sustainable and climate-friendly economy. For the industrially highly relevant gas–liquid reactions, this can be achieved by tailoring the timescales of mixing to the requirements of the reaction. Although this has long been known for idealized reactors and time- and space-averaged processes, considerable progress has been made recently on the influence of local mixing processes. This progress has become possible through joint research between chemists, mathematicians, and engineers. We present the reaction systems with adjustable kinetics that have been developed, which are easy to handle and analyze. We show examples of how the selectivity of competitive-consecutive reactions can be controlled via local bubble wake structures. This is demonstrated for Taylor bubbles and bubbly flows under technical conditions. Highly resolvednumerical simulations confirm the importance of the bubble wake structure for the performance of a particular chemical reaction and indicate tremendous potential for future process improvements.


2019 ◽  
Vol 8 (2) ◽  
pp. 958-965 ◽  
Author(s):  
Yang Zhang ◽  
Xuefeng Peng ◽  
Bingqiang Fan ◽  
Nan Zang ◽  
Shili Zheng ◽  
...  

2018 ◽  
Vol 64 ◽  
pp. 08003
Author(s):  
Brito António ◽  
Neves Luís

The production of energy under a special regime of renewable origin has had a sustainable evolution in Portugal. Since the 1990s, the percentage of renewables has been growing steadily, with special emphasis being given to wind, photovoltaic, mini-hydro, biogas and high-efficiency cogeneration [1]. More recently there has been a strong push in promoting small scale production and self-consumption [2]. There are several periods of time when the country’s electricity load is 100% supplied by renewable energy. There are also periods when surplus renewable energy is exported to Spain. However, there are some periods when production exceeds consumption and it is then necessary to reduce wind power production. In Portugal there is an innovative process underway to carry out this reduction, which was systematized by the General Department of Energy and Geology in Order No. 8810/2015, of August 10. Thus, in the case of wind power plants that receive power reduction orders, the remuneration equivalent to that which is lost is paid by the other producers, through the Last Resort Supplier. Those power plants that have not been interrupted pay a percentage of their power produce to the Last Resort Supplier, to compensate those that have been interrupted. The total of the payments made to the producers whose power plants were interrupted must equal the receipts from those plants that continued to produce energy. This new concept is exemplified in this paper by the wind power cut that occurred on March 12 and 13, 2017 in Portugal. An explanation of what occurred on that day is presented, to understand why this cut was made, having been reached the limits of energy exports to Spain. To implement this new interruptible compensation model it was necessary to develop a mathematical algorithm and include it in the computer application named GPCE - Producers’ Management and Energy Purchase, that belongs to the Last Resort Supplier. When the interruption occurred in March 2017, the computer system worked correctly. The sum of the payments made equaled the sum of the receipts. It should be noted that there was a high degree of discipline shown by the producers.


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