scholarly journals Manufacturing and Characterization of Environmentally Friendly Wood Plastic Composites Using Pinecone as a Filler into a Bio-Based High-Density Polyethylene Matrix

Polymers ◽  
2021 ◽  
Vol 13 (24) ◽  
pp. 4462
Author(s):  
Maria del Carmen Morcillo ◽  
Ramón Tejada ◽  
Diego Lascano ◽  
Daniel Garcia-Garcia ◽  
David Garcia-Sanoguera

The use of wood plastic composites (WPC) is growing very rapidly in recent years, in addition, the use of plastics of renewable origin is increasingly implemented because it allows to reduce the carbon footprint. In this context, this work reports on the development of composites of bio-based high density polyethylene (BioHDPE) with different contents of pinecone (5, 10, and 30 wt.%). The blends were produced by extrusion and injection-molded processes. With the objective of improving the properties of the materials, a compatibilizer has been used, namely polyethylene grafted with maleic anhydride (PE-g-MA 2 phr). The effect of the compatibilizer in the blend with 5 wt.% has been compared with the same blend without compatibilization. Mechanical, thermal, morphological, colorimetric, and wettability properties have been analyzed for each blend. The results showed that the compatibilizer improved the filler–matrix interaction, increasing the ductile mechanical properties in terms of elongation and tensile strength. Regarding thermal properties, the compatibilizer increased thermal stability and improved the behavior of the materials against moisture. In general, the pinecone materials obtained exhibited reddish-brown colors, allowing their use as wood plastic composites with a wide range of properties depending on the filler content in the blend.

2013 ◽  
Vol 34 (1) ◽  
pp. 39-54 ◽  
Author(s):  
Ljerka Kratofil Krehula ◽  
Zvonimir Katančić ◽  
Anita Ptiček Siročić ◽  
Zlata Hrnjak-Murgić

2017 ◽  
Vol 267 ◽  
pp. 76-81 ◽  
Author(s):  
Janis Kajaks ◽  
Karlis Kalnins ◽  
Anita Zagorska ◽  
Juris Matvejs

One type of birch wood plywood by-product: plywood sanding dust (PSD) and recycled high density polyethylene (rHDPE) composites physical mechanical properties (tensile, flexural strength and modulus, impact strength and microhardness), water resistance and fluidity of the composite melts, were evaluated. These studies showed the possibility of the usage of presented by-product as an excellent reinforcement for recycled high density polyethylene matrix. It was observed that the modulus of the tensile for unmodified rHDPE+PSD composites increased up to 2.3 times, the modulus of flexural till 4 times, but the microhardness only 1.4 times. Optimal content of the PSD in recycled high density polyethylene composites could be 50 wt. %. As a coupling agent, the maleated polyethylene (MAPE) for modifying of the rHDPE+50 wt. % PSD composite was used. Due to the MAPE additives, the improvement (30-50 %) of the investigated exploitation properties was observed, but in comparison with unmodified composites the resistance of water increased up to 3.0 times. Optimal content of MAPE in rHDPE+50 wt. % PSD composition could be 3 wt.%.


2013 ◽  
Vol 750-752 ◽  
pp. 38-42
Author(s):  
Wang Wang Yu ◽  
Juan Li ◽  
Yun Ping Cao

In this study, the silvergrass (SV) was used to reinforce HDPE composites. The effects of polymeric methylene diphenyl diisocyanate (PMDI) content, slivergrass fibers content on the mechanical, water absortion of wood plastic composites (WPCs) were investigated. It was found that the mechanical properties of the SV reinforced HDPE composites can be improved by PMDI treatment. The highest tensile strength and flexural strength of the composites can be reached with 50% SV contents at the SV: PMDI=6:1. It has been proved that the hydroxyl groups of SV fibers which can react with the-NCO by FTIR. It also can be concluded that the water absorption of PMDI treated WPCs was lower than untreated ones.


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