scholarly journals Construction of a (NNN)Ru-Incorporated Porous Organic Polymer with High Catalytic Activity for β-Alkylation of Secondary Alcohols with Primary Alcohols

Polymers ◽  
2022 ◽  
Vol 14 (2) ◽  
pp. 231
Author(s):  
Yao Cui ◽  
Jixian Wang ◽  
Lei Yu ◽  
Ying Xu ◽  
David J. Young ◽  
...  
Keyword(s):  
Functional Group ◽  
Catalytic Efficiency ◽  
Organic Polymer ◽  
Pincer Ligands ◽  
High Catalytic Activity ◽  
Secondary Alcohols ◽  
Primary Alcohols ◽  
Solid Supports ◽  
Porous Organic Polymer ◽  
Heterogeneous And Homogeneous Catalysis

Solid supports functionalized with molecular metal catalysts combine many of the advantages of heterogeneous and homogeneous catalysis. A (NNN)Ru-incorporated porous organic polymer (POP-bp/bbpRuCl3) exhibited high catalytic efficiency and broad functional group tolerance in the C–C cross-coupling of secondary and primary alcohols to give β-alkylated secondary alcohols. This catalyst demonstrated excellent durability during successive recycling without leaching of Ru which is ascribed to the strong binding of the pincer ligands to the metal ions.

scholarly journals Palladium/phosphorus-functionalized porous organic polymer with tunable surface wettability for water-mediated Suzuki–Miyaura coupling reaction

RSC Advances ◽  
2019 ◽  
Vol 9 (63) ◽  
pp. 36600-36607 ◽  
Author(s):  
Yizhu Lei ◽  
Zaifei Chen ◽  
Guangxing Li
Keyword(s):  
Catalytic Activity ◽  
Coupling Reaction ◽  
Surface Wettability ◽  
Organic Polymer ◽  
High Catalytic Activity ◽  
Aryl Chlorides ◽  
Porous Organic Polymer

A palladium/phosphorus-functionalized porous organic polymer with tunable surface wettability was successfully prepared. The catalyst displayed high catalytic activity for the water-mediated Suzuki–Miyaura coupling reaction of aryl chlorides.

A three-dimensional porphyrin-based porous organic polymer with excellent biomimetic catalytic performance

2017 ◽  
Vol 8 (30) ◽  
pp. 4327-4331 ◽  
Author(s):  
Wei Zhu ◽  
Zheng-Dong Ding ◽  
Xuan Wang ◽  
Tao Li ◽  
Rui Shen ◽  
...  
Keyword(s):  
High Stability ◽  
Three Dimensional ◽  
Catalytic Efficiency ◽  
Catalytic Performance ◽  
Organic Polymer ◽  
Diamond Structure ◽  
Porous Organic Polymer ◽  
Biomimetic Catalyst

A porphyrin-based porous organic polymer PPOP-1(Fe) with a three-dimensional diamond structure was synthesized, which exhibits high stability and excellent catalytic efficiency as a biomimetic catalyst.

A porphyrin porous organic polymer with bicatalytic sites for highly efficient one-pot tandem catalysis

2019 ◽  
Vol 55 (6) ◽  
pp. 822-825 ◽  
Author(s):  
Rui Shen ◽  
Wei Zhu ◽  
Xiaodong Yan ◽  
Tao Li ◽  
Yong Liu ◽  
...  
Keyword(s):  
High Stability ◽  
Catalytic Efficiency ◽  
Suzuki Coupling ◽  
Catalytic Reactions ◽  
Organic Polymer ◽  
Tandem Catalysis ◽  
One Pot ◽  
Porous Organic Polymer ◽  
Highly Efficient ◽  
Catalytic Sites

A porphyrin-based porous organic polymer with bifunctional catalytic sites was synthesized, and exhibits high stability and excellent catalytic efficiency for tandem catalytic reactions of C–H arylation and Suzuki coupling.

Fabrication of acylsemicarbazide-based porous organic polymer for selective enrichment of glycopeptides

2017 ◽  
Vol 35 (7) ◽  
pp. 688
Author(s):  
Hongwei WANG ◽  
Zhongshan LIU ◽  
Xiaojun PENG ◽  
Junjie OU ◽  
Mingliang YE
Keyword(s):  
Organic Polymer ◽  
Selective Enrichment ◽  
Porous Organic Polymer

Phosphorus Containing Porous Organic Polymers: Synthetic Techniques and Applications in Organic Synthesis and Catalysis

2021 ◽  
Author(s):  
Pramod Kumar ◽  
Animesh Das ◽  
Biplab Maji
Keyword(s):  
Organic Synthesis ◽  
Homogeneous Catalysis ◽  
Heterogeneous Catalysts ◽  
Organic Polymer ◽  
Organic Polymers ◽  
Porous Organic Polymers ◽  
Porous Organic Polymer ◽  
Phosphorus Containing

The phosphorous-containing porous organic polymer is a trending material for the synthesis of heterogeneous catalysts. Decades of investigations have established phosphines as versatile ligands in homogeneous catalysis. Recently, phosphine-based heterogeneous...

Integrating Single Atoms with Different Microenvironments into One Porous Organic Polymer for Efficient Photocatalytic CO 2 Reduction

2021 ◽  
pp. 2101568
Author(s):  
Xiao‐Yu Dong ◽  
Ya‐Nan Si ◽  
Qian‐You Wang ◽  
Shan Wang ◽  
Shuang‐Quan Zang
Keyword(s):  
Organic Polymer ◽  
Porous Organic Polymer ◽  
Single Atoms

Preparation of functional magnetic porous organic polymer as sorbents for mercury speciation followed by HPLC-ICP-MS analysis

2021 ◽  
Author(s):  
Yifeng He ◽  
Man He ◽  
Beibei Chen ◽  
Bin Hu
Keyword(s):  
High Performance ◽  
Solid Phase ◽  
Magnetic Solid Phase Extraction ◽  
Mercury Speciation ◽  
Organic Polymer ◽  
Phase Extraction ◽  
Porous Organic Polymer ◽  
Icp Ms ◽  
Magnetic Solid ◽  
Sulfur Containing

A novel sulfur-containing functional core-shell magnetic porous organic polymer (Fe3O4@BD-TpMA-S-SH MOPs) was synthesized as magnetic solid phase extraction (MSPE) sorbent for mercury speciation followed by high performance liquid chromatography (HPLC)...

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