scholarly journals Continuous Bamboo Fibers/Fire-Retardant Polyamide 11: Dynamic Mechanical Behavior of the Biobased Composite

Polymers ◽  
2022 ◽  
Vol 14 (2) ◽  
pp. 299
Author(s):  
Louise Lods ◽  
Tutea Richmond ◽  
Jany Dandurand ◽  
Eric Dantras ◽  
Colette Lacabanne ◽  
...  
Keyword(s):  
Flame Retardant ◽  
Security Requirements ◽  
Shear Mode ◽  
Calorimetric Study ◽  
Experimental Conditions ◽  
Polyamide 11 ◽  
Melamine Cyanurate ◽  
Dynamic Mechanical ◽  
The Matrix ◽  
Bamboo Fibers

A biobased composite was generated from bamboo fibers (BF) and a polyamide 11 (PA11) matrix. In order to fulfill security requirements, a PA11 already containing a flame retardant (FR) was chosen: This matrix is referred as PA11-FR. In this work, the effects of flame retardant (melamine cyanurate) on the composite properties were considered. In the calorimetric study, the glass transition and melting temperatures of PA11-FR were the same as those of PA11. The melamine cyanurate (MC) had no influence on these parameters. Thermogravimetric analysis revealed that PA11-FR was less stable than PA11. The presence of MC facilitated thermal decomposition regardless of the analysis atmosphere used. It is important to note that the presence of FR did not influence processing conditions (especially the viscosity parameter) for the biosourced composite. Continuous BF-reinforced PA 11-FR composites, single ply, with 60% of fibers were processed and analyzed using dynamic mechanical analysis. In shear mode, comparative data recorded for BF/PA11-FR composite and the PA11-FR matrix demonstrated that the shear glassy modulus was significantly improved: multiplied by a factor of 1.6 due to the presence of fibers. This result reflected hydrogen bonding between reinforcing fibers and the matrix, resulting in a significant transfer of stress. In tensile mode, the conservative modulus of BF/PA11-FR reached E’ = 8.91 GPa. Upon BF introduction, the matrix tensile modulus was multiplied by 5.7. It can be compared with values of a single bamboo fiber recorded under the same experimental conditions: 31.58 GPa. The difference is partly explained by the elementary fibers’ lack of alignment in the composite.

scholarly journals Influence of Thermal Treatment on Mechanical and Morphological Characteristics of Polyamide 11/Cellulose Nanofiber Nanocomposites

2015 ◽  
Vol 2015 ◽  
pp. 1-11 ◽  
Author(s):  
Denis Mihaela Panaitescu ◽  
Raluca Augusta Gabor ◽  
Adriana Nicoleta Frone ◽  
Eugeniu Vasile
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Thermal Treatment ◽  
Cellulose Nanofibers ◽  
Morphological Characteristics ◽  
Nanocomposite Films ◽  
Polyamide 11 ◽  
Dynamic Mechanical ◽  
The Matrix ◽  
The Impact

Nanocomposite films were prepared from polyamide 11 (PA11) and cellulose nanofibers (CN) by melt compounding and compression molding. The impact of thermal treatment on the morphology and mechanical behavior of PA11 and nanocomposite films was studied using dynamic mechanical analysis, tensile tests, X-ray diffraction (XRD), and peak force (PF) QNM technique. Slightly higher storage modulus values were obtained for nanocomposites compared to the matrix before the treatment, but a noticeable increase was observed after the treatment. Although CN addition determined increased tensile strength and modulus both before and after the treatment, the increase was much more significant in the case of treated films. The best mechanical properties were shown by treated PA11 films containing 5 wt% CN, with 40% higher Young’s modulus and with 35% higher tensile strength compared to the matrix. Some of the changes pointed out by static and dynamic mechanical tests were explained by the morphological changes determined by the thermal treatment and emphasized by PF QNM and by the increase of XRD crystallinity. A transition from lamellar stack morphology to one involving spherulites was highlighted by AFM. Thermal treatment has proved a valuable method for improving the mechanical properties of PA11/CN composites.

Electrolytic Isolation of Twin-Type Shock Deformation Structures

1967 ◽  
Vol 25 ◽  
pp. 318-319
Author(s):  
F. I. Grace ◽  
L. E. Murr
Keyword(s):  
Grain Boundaries ◽  
Thin Foil ◽  
Electrolyte Composition ◽  
Experimental Conditions ◽  
Average Current Density ◽  
Electron Transmission ◽  
Deformation Structures ◽  
The Matrix ◽  
Average Current ◽  
Specimen Edge

During the course of electron transmission investigations of the deformation structures associated with shock-loaded thin foil specimens of 70/30 brass, it was observed that in a number of instances preferential etching occurred along grain boundaries; and that the degree of etching appeared to depend upon the various experimental conditions prevailing during electropolishing. These included the electrolyte composition, the average current density, and the temperature in the vicinity of the specimen. In the specific case of 70/30 brass shock-loaded at pressures in the range 200-400 kilobars, the predominant mode of deformation was observed to be twin-type faults which in several cases exhibited preferential etching similar to that observed along grain boundaries. A novel feature of this particular phenomenon was that in certain cases, especially for twins located in the vicinity of the specimen edge, the etching or preferential electropolishing literally isolated these structures from the matrix.

SEBS-based thermoplastic elastomers containing aluminum hypophosphite and melamine cyanurate: Thermal degradation, flame retardancy, and mechanical properties

2019 ◽  
Vol 37 (2) ◽  
pp. 137-154 ◽  
Author(s):  
Xi Cheng ◽  
Jianming Wu ◽  
Yulin Li ◽  
Chenguang Yao ◽  
Guisheng Yang
Keyword(s):  
Flame Retardant ◽  
Thermoplastic Elastomers ◽  
Char Residue ◽  
Melamine Cyanurate ◽  
Char Layer ◽  
Phenylene Oxide ◽  
Peak Heat Release Rate ◽  
Ul 94 ◽  
Flame Retardant Properties ◽  
Aluminum Hypophosphite

Aluminum hypophosphite combined with melamine cyanurate and poly(phenylene oxide) was applied to flame-retard TPE-S system (blends of SEBS and polyolefin). The flame-retardant properties of the TPE-S/AHP/MCA/PPO were investigated by LOI and vertical burning test (UL-94). The results indicated that TPE-S containing 16 wt% AHP, 20 wt% MCA, and 10 wt% PPO reached a V-0 rating in the UL-94 test, and its LOI value was 28.2%. It performed well in the cone calorimeter (reduction in peak heat release rate from 2001 to 494 kW m−2). Thermogravimetric-Fourier transform infrared spectroscopy tests showed that AHP and MCA acted in gaseous phase, while AHP and PPO helped to form char residue. The SEM graphs demonstrated that continuous and compact films cover bubbles of the char layer in TPE-S/AHP/MCA/PPO. The proposed flame-retardant mechanisms of such systems were summarized.

Effect of Excess PbO on the Kinetics of the Growth of PMNT Polycrystals by Templated Grain Growth Method

2005 ◽  
Vol 475-479 ◽  
pp. 1137-1140
Author(s):  
Lili Zhao ◽  
Feng Gao ◽  
Wei Min Wang ◽  
Chang Sheng Tian
Keyword(s):  
Grain Growth ◽  
Templated Grain Growth ◽  
Experimental Conditions ◽  
Precipitation Mechanism ◽  
Oriented Structure ◽  
Diffusion Controlled ◽  
The Matrix ◽  
Growth Method ◽  
Final Composition ◽  
Kinetics Of

The oriented 0.67Pb (Mg1/3Nb2/3)O3-0.33PbTiO3 (PMNT) polycrystals were prepared by the conventional ceramic technique and the templated grain growth method adding excess PbO in the matrix. Kinetics of the development of oriented structure was investigated systemically. In the presence of PbO liquid phase, the oriented PMNT polycrystals mainly grow by the dissolution-precipitation mechanism. The diffusion is determined by the sintering temperature and the PbO-excess content in the matrix. The thickness of oriented PMNT polycrystals displays a t1/3 dependence, which is characteristic of diffusion-controlled growth. For the thicker oriented structure, 20% excess PbO in the PMNT matrix and 1150oC for 10h are the proper experimental conditions. Moreover, the addition of PbO in the matrix hardly affects the final composition of ceramic matrix.

Analisa Kekuatan Bahan Komposit Yang Diperkuat Serat Bambu Menggunakan Resin Polyester Dengan Memvariasikan Susunan Serat Secara Acak Dan Lurus Memanjang

2020 ◽  
Vol 2 (1) ◽  
pp. 28-35
Author(s):  
Rokki Manurung ◽  
Sutan Simanjuntak ◽  
Jesayas Sembiring ◽  
Richard A.M. Napitupulu ◽  
Suriady Sihombing
Keyword(s):  
Polymer Composites ◽  
Polyester Resin ◽  
Natural Fibers ◽  
Resin Matrix ◽  
Strength Increase ◽  
Test Results ◽  
The Matrix ◽  
Bamboo Fibers ◽  
Reinforcing Material

Composites are materials which are mixed with one or more different and heterogeneous reinforcement. Matrix materials can generally be polymers, ceramics and metals. The matrix in the composite serves to distribute the load into all reinforcing material. Matrix properties are usually ductile. The reinforcing material in the composite has the role of holding the load received by the composite material. The nature of the reinforcing material is usually rigid and tough. Strengthening materials commonly used so far are carbon fiber, glass fiber, ceramics. The use of natural fibers as a type of fiber that has advantages began to be applied as a reinforcing material in polymer composites. This study seeks to see the effect of the use of bamboo natural fibers in polyester resin matrix on the strength of polymer composites with random and straight lengthwise fiber variations. From the tensile test results it can be seen that bamboo fibers can increase the strength of polymer composites made from polyester resin and the position of the longitudinal fibers gives a significantly more strength increase than random fibers.

scholarly journals Properties of Latex Polymer Modified Mortars Reinforced with Waste Bamboo Fibers from Construction Waste

Buildings ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 149 ◽  
Author(s):  
Banjo Akinyemi ◽  
Temidayo Omoniyi
Keyword(s):  
Mechanical Properties ◽  
High Strength ◽  
Latex Paint ◽  
Construction Waste ◽  
Calcium Silicate Hydrates ◽  
Cement Mortars ◽  
The Matrix ◽  
Bamboo Fibers ◽  
Pre Treatment ◽  
Scanning Electron

This study evaluated the properties of latex modified cement mortars from ordinary paints which were reinforced with treated bamboo fibers from construction waste. Fiber variations of 0, 0.5, 1 and 1.5% at 10% of the weight of cement were utilized. Mechanical properties were determined according to standards; similarly, scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) were used to analyze the microstructural and elemental properties of the samples. The experimental results revealed that the addition of 1.5% bamboo fibers and 10% latex solution produced excellent mechanical properties. This was as a result of improved fiber adhesion to the matrix through pre-treatment, coupled with the contributed high strength from the latex paint modified mortars. The micrograph showed that latex precipitated in the voids and on the surface of the bamboo fibers as well as gels of calcium silicate hydrates which contributed to the observed improvement in strength of the tested samples.

Flame Retardant Intumescent Polyamide 11-Carbon Nanofiber Nanocomposites: Thermal and Flammability Properties

2007 ◽  
Vol 1056 ◽  
Author(s):  
Si Chon Lao ◽  
Joseph H Koo ◽  
Alexander Morgan ◽  
Hung-Kai Jor ◽  
Khiet Nguyen ◽  
...  
Keyword(s):  
Heat Resistance ◽  
Flame Retardant ◽  
Carbon Nanofiber ◽  
High Strength ◽  
High Heat ◽  
Melt Processing ◽  
Test Method ◽  
Fire Retardancy ◽  
High Heat Resistance ◽  
Polyamide 11

ABSTRACTCurrent polyamide 11 and 12 are lacking in fire retardancy and high strength/high heat resistance characteristics for fabricated parts that are required for performance driven applications. The introduction of selected nanoparticles such as carbon nanofibers (CNFs), combined with a conventional intumescent flame retardant (FR) additive into the polyamide 11/polyamide 12 (PA11/PA12) by melt processing conditions has resulted in a family of intumescent polyamide nanocomposites. These intumescent PA11 and PA12 nanocomposites exhibit enhanced polymer performance characteristics, i.e., fire retardancy, high strength, and high heat resistance and are expected to expand the market opportunities for resin manufacturers. The overall objective of this research is to develop improved PA11 and PA12 polymers with enhanced flame retardancy, thermal, and mechanical properties for selective laser sintering (SLS) rapid manufacturing. Arkema RILSAN® PA11 polymer was examined with CNFs and Clairant Exolit® OP 1230 intumescent FR additive. They were used to create a family of FR intumescent PA11-CNF nanocomposites. Transmission electron microscopy (TEM) was used to determine the degree of CNFs and intumescent FR additive dispersion in PA11. Injection molded specimens were fabricated for material properties measurements. Thermal stability of these polymer nanocomposites (PNs) was examined by TGA. Flammability and thermal properties of these PNs were obtained using the cone calorimeter, UL 94 test method, and heat deflection temperature.

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