scholarly journals Activated Carbon for Pharmaceutical Removal at Point-of-Entry

Processes ◽  
2021 ◽  
Vol 9 (7) ◽  
pp. 1091
Author(s):  
Michelle Finn ◽  
Gabrielle Giampietro ◽  
David Mazyck ◽  
Regina Rodriguez

Pharmaceuticals are an increasing problem in waterways due to improper disposal and lack of removal at wastewater treatment plants. Long-term exposure impacts to humans are unknown but have been observed in model organisms (i.e., fish), impacting reproduction, changing temperament, and causing organ damage. The application of activated carbon (AC) for organic contaminant removal is widespread and applied successfully for water treatment. The objective of this study is to rapidly adsorb ibuprofen using AC to determine the feasibility as a point-of-entry treatment option for removal of pharmaceuticals in the toilet. AC factors analyzed include type of AC raw material, adsorbent particle size, contact time, and competitive adsorption of ibuprofen and common toilet bowl cleaner components such as chlorine and methylene blue dye. A coconut-based AC with a high surface area adsorbed the highest quantity of ibuprofen. There was no significant impact to ibuprofen adsorption upon the introduction of other compounds to the solution, thus demonstrating rapid adsorption and the potential for application at the point-of-entry.

2015 ◽  
Vol 34 (7) ◽  
pp. 667-674
Author(s):  
Jian Wu ◽  
Hongying Xia ◽  
Libo Zhang ◽  
Yi Xia ◽  
Jinhui Peng ◽  
...  

Abstract The present study reports the effect of microwave power and microwave heating time on activated carbon adsorption ability. The waste bamboo was used to preparing high surface area activated carbon via microwave heating. The bamboo was carbonized for 2 h at 600°C to be used as the raw material. According to the results, microwave power and microwave heating time had a significant impact on the activating effect. The optimal KOH/C ratio of 4 was identified when microwave power and microwave heating time were 700 W and 15 min, respectively. Under the optimal conditions, surface area was estimated to be 3441 m2/g with pore volume of 2.093 ml/g and the significant proportion of activated carbon was microporous (62.3%). The results of Fourier transform infrared spectroscopy (FTIR) were illustrated that activated carbon surface had abundant functional groups. Additionally the pore structure is characterized using Scanning Electron Microscope (SEM).


2019 ◽  
Vol 6 (9) ◽  
pp. 190523 ◽  
Author(s):  
Lu Luo ◽  
Xi Wu ◽  
Zeliang Li ◽  
Yalan Zhou ◽  
Tingting Chen ◽  
...  

Activated carbon (AC) was successfully prepared from low-cost forestry fir bark (FB) waste using KOH activation method. Morphology and texture properties of ACFB were studied by scanning and high-resolution transmission electron microscopies (SEM and HRTEM), respectively. The resulting fir bark-based activated carbon (ACFB) demonstrated high surface area (1552 m 2 g −1 ) and pore volume (0.84 cm 3 g −1 ), both of which reflect excellent potential adsorption properties of ACFB towards methylene blue (MB). The effect of various factors, such as pH, initial concentration, adsorbent content as well as adsorption duration, was studied individually. Adsorption isotherms of MB were fitted using all three nonlinear models (Freundlich, Langmuir and Tempkin). The best fitting of MB adsorption results was obtained using Freundlich and Temkin. Experimental results showed that kinetics of MB adsorption by our ACFB adsorbent followed pseudo-second-order model. The maximum adsorption capacity obtained was 330 mg g −1 , which indicated that FB is an excellent raw material for low-cost production of AC suitable for cationic dye removal.


2018 ◽  
Vol 37 (1) ◽  
pp. 59-68 ◽  
Author(s):  
Song Cheng ◽  
Libo Zhang ◽  
Shengzhou Zhang ◽  
Hongying Xia ◽  
Jinhui Peng

AbstractThe spent phenolic resin is as raw material for preparing high surface area activated carbon (HSAAC) by microwave-assisted KOH activation. The effects of microwave power, activation duration and impregnation ratio (IR) on the iodine adsorption capability and yield of HSAAC were investigated. The surface characteristics of HSAAC were characterized by nitrogen adsorption isotherms, FTIR, SEM and TEM. The operating variables were optimized utilizing the response surface methodology (RSM) and were identified to be microwave power of 700 W, activation duration of 15 min and IR of 4, corresponding to a yield of 51.25 % and an iodine number of 2,384 mg/g. The pore structure parameters of the HSAAC, i. e., Brunauer–Emmett–Teller (BET) surface area, total pore volume, and average pore diameter were estimated to be 4,269 m2/g, 2.396 ml/g and 2.25 nm, respectively, under optimum conditions. The findings strongly support the feasibility of microwave-assisted KOH activation for preparation of HSAAC from spent phenolic resin.


2011 ◽  
Vol 110-116 ◽  
pp. 2124-2130 ◽  
Author(s):  
Abdul Rahim Yacob ◽  
Hassan M. Al Swaidan

High surface area activated carbon has always fascinated researchers for its application as adsorbent, for water purification, medical and industrial. Date is the major export of Saudi Arabia, while tons of date foliar and fronds are troublesome and yet to be disposed. Transforming this waste into usable activated carbon can be a good idea for recycling, sustainable and green chemistry. In this study, date tree frond is selected to prepare activated carbon, while the effect of phosphoric acid in chemical activation is studied. Using thermogravimetry analysis, it was found that 400oC was the best temperature to convert date frond to carbon. This is supported by FTIR spectroscopy. Various concentration of phosphoric acid is used to optimize the product high surface area carbon obtained and it was found the best is at 60% phosphoric acid with the highest surface area of 1139 m2g-1. This result is also supported by FTIR spectroscopy, which indicates the similarities between commercial carbon and the carbon prepared. FESEM pictographs show chemical activation using phosphoric acid can easily open up pores and cavity of the prepared activated carbon the get the high surface area. It is thus suggested that for mass production of high surface area carbon, date palm frond is used as the source of raw material, due to its abundance and availability comes from the pruning process on the date palm tree, while chemically activated to get the high surface area.


2021 ◽  
Vol 8 (1) ◽  
pp. 311-332
Author(s):  
Ahmed El Nemr ◽  
Amany G. M. Shoaib ◽  
Amany El Sikaily ◽  
Alaa El-Deen A. Mohamed ◽  
Asaad F. Hassan

2019 ◽  
Author(s):  
Chem Int

Activated carbon was prepared from molasses, which are natural precursors of vegetable origin resulting from the sugar industry. A simple elaboration process, based on chemical activation with phosphoric acid, was proposed. The final product, prepared by activation of molasses/phosphoric acid mixture in air at 500°C, presented high surface area (more than 1400 m2/g) and important maximum adsorption capacity for methylene blue (625 mg/g) and iodine (1660 mg/g). The activated carbon (MP2(500)) showed a good potential for the adsorption of Cr(VI), Cu(II) and Pb(II) from aqueous solutions. The affinity for the three ions was observed in the following order Cu2+ Cr6+ Pb2+. The process is governed by monolayer adsorption following the Langmuir model, with a correlation coefficient close to unity.


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