scholarly journals STRUCTURE FORMATION OF C-S-H FROM THE POSITION OF MICROMECHANICS OF COMPOSITE MEDIA

2021 ◽  
Vol 4 (5) ◽  
pp. 5-15
Author(s):  
R. Fedyuk ◽  
D.-Y. Yoo

the creation of an environmentally friendly building material to protect the human environment can only be carried out from the position of a transdisciplinarity approach, taking into account modern achievements in geomimetics and micromechanics of composite media. A wide range of basalt-fiber-reinforced concrete based on composite binders has been developed, which have increased characteristics of impermeability and durability under extreme operating conditions. The nature of the influence of the composition and manufacturing technology of cement composites on the pore structure of the composite has been established, which has a positive effect on the charac-teristics of gas, water and vapor permeability. High early strength was obtained, which allows the use of materials for operational repair and construction in emergency situations. The positive influence of the composition of the developed composite on the performances has been proved. The water resistance of the modified composite provides a water pressure of 2 MPa for 148 hours, which corresponds to the W18 grade (for the control sample – W8), the frost resistance grade – F300. It was found that the water absorption of the modified concrete samples was lower than that of the control sample, which is explained by the decrease in the pore structure index λ by 28.4 times, and the average pore diameter by 3.05 times. The total pore volume of the modified concrete was lower and decreased with increasing dose of nanosilica.

Materials ◽  
2020 ◽  
Vol 13 (14) ◽  
pp. 3238
Author(s):  
Yue Li ◽  
Aiqin Shen ◽  
Hua Wu

In this study, we focused on exploring the correlations between the pore surface fractal dimensions and the pore structure parameters, strength and shrinkage properties of basalt fiber-reinforced concrete (BFRC). The pore structure of BFRCs with various fiber contents and fiber lengths was investigated using mercury intrusion porosimetry (MIP) measurements. Through Zhang’s model, the fractal characteristics of BFRCs in the whole pore size range and in different pore size ranges were calculated from the MIP test data. The results showed that the addition of BF increased the total porosity, total pore volume and pore area but decreased the average pore diameter, indicating that BFs refined the pore structure of the concrete. BFRC presented obvious fractal characteristics in the entire pore-size range and individual pore-size ranges; generally, the fractal dimension increased with increasing fiber content. Moreover, correlation analysis suggested that the fractal dimension of BFRC in the whole pore-size range (FD) was closely related to the fractal dimension in the macropore region (Dm) and average pore diameter (APD). The influence of pore structure factors on mechanical strength and shrinkage was studied by grey correlation theory, and the results showed that Dm showed positive correlations with strength and fracture energy, with increasing Dm tending to strengthen and toughen the concrete. An increase in fiber content and length was detrimental to reducing the drying shrinkage strain. In the transition pore region, the fractal dimension (Dt) at diameters ranging from 20 to 50 nm and shrinkage strain exhibited a highly linear relation. These results merit careful consideration in macro-property evaluation by using the pore surface fractal dimension in a specific region instead of the whole region. Finally, grey target theory was applied to evaluate the rank of the mechanical strength and shrinkage of concrete, and the results showed that the overall properties of concrete with a BF length of 18 mm and a BF content of 0.06% ranked the best.


Vestnik MGSU ◽  
2021 ◽  
pp. 1346-1356
Author(s):  
Valery S. Lesovik ◽  
Roman S. Fediuk

Introduction. The purpose of the article is to expand the range of compositions for special structures, which will allow them to be operated in extreme conditions. To achieve this goal, a number of tasks have been solved containing ways to improve the efficiency of composites, incl. low-permeability ones. Materials and methods. The research methodology includes a system of transdisciplinary approaches that evaluate the composite as a complex system, taking into account the provisions of geomimetics, such as the law of similarity, the law of affinity of structures, technogenic metasomatism, and micromechanics of composite media. Results. A wide range of cement concretes has been created for unique objects: low-permeability (for protective objects, reservoirs and hydraulic structures). The developed composites have the following performance characteristics (the results for the control sample are given in parentheses): water absorption by weight — 2.5 % (6.1 %), waterproof grade — W14 (W10), air permeability — 0.0253 cm3/s (0.0565 cm3/s), vapor permeability — 0.0021 mg/(m-h-Pa) (0.0030 mg/(m-h-Pa)), effective diffusion coefficient — 1.34 · 10–4 cm2/s (1.56 · 10–4 cm2/s). Conclusions. The similarity in the work of the components of different composite binders, incl. During the two-stage hydration of clinker minerals, in particular, in the first phase, the formation of low-density compounds of different phases occurs, and in the second phase, the binding of calcium hydroxide to low-basic crystalline hydrates occurs. The increase in the activity of the composite binder is due to the synergistic effect of a number of reasons: amorphous silica-containing components bind Ca(OH)2, released during the hydration of clinker minerals, in the second generation CSH(I); limestone particles clog the pores, compacting the structure; and fly ash microspheres are centers of crystallization of new growths.


Crystals ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 779
Author(s):  
Seyed Esmaeil Mohammadyan-Yasouj ◽  
Hossein Abbastabar Ahangar ◽  
Narges Ahevani Oskoei ◽  
Hoofar Shokravi ◽  
Seyed Saeid Rahimian Koloor ◽  
...  

The sustainability of reinforced concrete structures is of high importance for practitioners and researchers, particularly in harsh environments and under extreme operating conditions. Buildings and tunnels are of the places that most of the fire cases take place. The use of fiber in concrete composite acts as crack arrestors to resist the development of cracks and enhance the performance of reinforced concrete structures subjected to elevated temperature. Basalt fiber is a low-carbon footprint green product obtained from the raw material of basalt which is created by the solidification of lava. It is a sustainable fiber choice for reinforcing concrete composite due to the less consumed energy in the production phase and not using chemical additives in their production. On the other hand, alginate is a natural anionic polymer acquired from cell walls of brown seaweed that can enhance the properties of composites due to its advantage as a hydrophilic gelling material. This paper investigates the thermal performance of alginate concrete reinforced with basalt fiber. For that purpose, an extensive literature review was carried out then two experimental phases for mix design and to investigate the compressive strength of samples at a temperature range of 100–180 °C were conducted. The results show that the addition of basalt fiber (BF) and/or alginate may slightly decrease the compressive strength compared to the control concrete under room temperature, but it leads to control decreasing compressive strength during exposure to a high temperature range of 100–180 °C. Moreover, it can be seen that temperature raise influences the rate of strength growth in alginate basalt fiber reinforced concrete.


2013 ◽  
Vol 834-836 ◽  
pp. 730-737
Author(s):  
Hai Liang Wang ◽  
Yao Hai Zhong

With the characteristics of wide range of sources of raw materials, environmental protection and cost-effective, Basalt Fiber, which is used as a kind of reinforced material of concrete, has received the attention of civil engineering. This paper summarizes the research status of Basalt Fiber Reinforced Concrete in China and abroad, and put forward proposals for the research of Basalt Fiber Reinforced Concrete.


2017 ◽  
Vol 2017 ◽  
pp. 1-13 ◽  
Author(s):  
Roman Fediuk ◽  
Aleksey Smoliakov ◽  
Aleksandr Muraviov

This paper investigates the creation of high-density impermeable concrete. The effect of the “cement, fly ash, and limestone” composite binders obtained by joint grinding with superplasticizer in the varioplanetary mill on the process of structure formation was studied. Compaction of structure on micro- and nanoscale levels was characterized by different techniques: X-ray diffraction, DTA-TGA, and electron microscopy. Results showed that the grinding of active mineral supplements allows crystallization centers to be created by ash particles as a result of the binding of Ca(OH)2 during hardening alite, which intensifies the clinker minerals hydration process; the presence of fine grains limestone also leads to the hydrocarboaluminates calcium formation. The relation between cement stone neoplasms composition as well as fibrous concrete porosity and permeability of composite at nanoscale level for use of composite binders with polydispersed mineral supplements was revealed. The results are of potential importance in developing the wide range of fine-grained fiber-reinforced concrete with a compressive strength more than 100 MPa, with low permeability under actual operating conditions.


Author(s):  
David A. Ansley

The coherence of the electron flux of a transmission electron microscope (TEM) limits the direct application of deconvolution techniques which have been used successfully on unmanned spacecraft programs. The theory assumes noncoherent illumination. Deconvolution of a TEM micrograph will, therefore, in general produce spurious detail rather than improved resolution.A primary goal of our research is to study the performance of several types of linear spatial filters as a function of specimen contrast, phase, and coherence. We have, therefore, developed a one-dimensional analysis and plotting program to simulate a wide 'range of operating conditions of the TEM, including adjustment of the:(1) Specimen amplitude, phase, and separation(2) Illumination wavelength, half-angle, and tilt(3) Objective lens focal length and aperture width(4) Spherical aberration, defocus, and chromatic aberration focus shift(5) Detector gamma, additive, and multiplicative noise constants(6) Type of spatial filter: linear cosine, linear sine, or deterministic


Author(s):  
Trần Thanh Nhàn

In order to observe the end of primary consolidation (EOP) of cohesive soils with and without subjecting to cyclic loading, reconstituted specimens of clayey soils at various Atterberg’s limits were used for oedometer test at different loading increments and undrained cyclic shear test followed by drainage with various cyclic shear directions and a wide range of shear strain amplitudes. The pore water pressure and settlement of the soils were measured with time and the time to EOP was then determined by different methods. It is shown from observed results that the time to EOP determined by 3-t method agrees well with the time required for full dissipation of the pore water pressure and being considerably larger than those determined by Log Time method. These observations were then further evaluated in connection with effects of the Atterberg’s limit and the cyclic loading history.


2020 ◽  
pp. 39-48
Author(s):  
B. O. Bolshakov ◽  
◽  
R. F. Galiakbarov ◽  
A. M. Smyslov ◽  
◽  
...  

The results of the research of structure and properties of a composite compact from 13 Cr – 2 Мо and BN powders depending on the concentration of boron nitride are provided. It is shown that adding boron nitride in an amount of more than 2% by weight of the charge mixture leads to the formation of extended grain boundary porosity and finely dispersed BN layers in the structure, which provides a high level of wearing properties of the material. The effect of boron nitride concentration on physical and mechanical properties is determined. It was found that the introduction of a small amount of BN (up to 2 % by weight) into the compacts leads to an increase in plasticity, bending strength, and toughness by reducing the friction forces between the metal powder particles during pressing and a more complete grain boundary diffusion process during sintering. The formation of a regulated structure-phase composition of powder compacts of 13 Cr – 2 Mо – BN when the content of boron nitride changes in them allows us to provide the specified physical and mechanical properties in a wide range. The obtained results of studies of the physical and mechanical characteristics of the developed material allow us to reasonably choose the necessary composition of the powder compact for sealing structures of the flow part of steam turbines, depending on their operating conditions.


1984 ◽  
Vol 19 (1) ◽  
pp. 87-100
Author(s):  
D. Prasad ◽  
J.G. Henry ◽  
P. Elefsiniotis

Abstract Laboratory studies were conducted to demonstrate the effectiveness of diffused aeration for the removal of ammonia from the effluent of an anaerobic filter treating leachate. The effects of pH, temperature and air flow on the process were studied. The coefficient of desorption of ammonia, KD for the anaerobic filter effluent (TKN 75 mg/L with NH3-N 88%) was determined at pH values of 9, 10 and 11, temperatures of 10, 15, 20, 30 and 35°C, and air flow rates of 50, 120, and 190 cm3/sec/L. Results indicated that nitrogen removal from the effluent of anaerobic filters by ammonia desorption was feasible. Removals exceeding 90% were obtained with 8 hours aeration at pH of 10, a temperature of 20°C, and an air flow rate of 190 cm3/sec/L. Ammonia desorption coefficients, KD, determined at other temperatures and air flow rates can be used to predict ammonia removals under a wide range of operating conditions.


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