scholarly journals Growth, optical, spectral, thermal and mechanical investigations of organic NLO crystal cis-2, 6-bis(4-chlorophenyl)-3, 3-dimethylpiperidin-4-one

2021 ◽  
Vol 3 (1) ◽  
pp. 13-20
Author(s):  
Mohanraj V ◽  
Ilango S.S. ◽  
Ponnuswamy S
Keyword(s):  
Spectral Studies ◽  
Slow Evaporation ◽  
Optical Studies ◽  
Orthorhombic System ◽  
Slow Evaporation Technique ◽  
Evaporation Technique ◽  
Ft Ir ◽  
Solubility Studies ◽  
Thermal Stability Of ◽  
Mechanical Studies

The single crystal of cis-2,6-bis(4-chlorophenyl)-3,3-dimethylpiperidin-4-one (4C3DMPO) has been grown using a slow evaporation technique. 4C3DMPO is a non-centrosymmetric crystal which crystallizes in the orthorhombic system with space group Pna21. Benzene is used as a solvent for the crystal growth based on solubility studies. The mechanical studies, using microhardness methods, have also been carried out. The compound is characterised using UV, FT-IR and NMR spectral studies. Furthermore, the thermal stability of the crystal is established by TG/DTA. The nonlinear optical studies (SHG) of the crystal have been determined using the Kurtz and Perry powder technique and the activity observed is 2.5 times greater than that of KDP.

Spectral Investigation on the Growth and Characterization of NLO Crystals of Thiourea Succinic Acid Single Crystal.

2015 ◽  
Vol 2 (2) ◽  
pp. 70-73
Author(s):  
Kannan.P ◽  
Thambidurai.S ◽  
Suresh.N
Keyword(s):  
Single Crystal ◽  
Succinic Acid ◽  
Slow Evaporation Technique ◽  
Absorption Studies ◽  
Dta Analysis ◽  
Evaporation Technique ◽  
Ft Ir ◽  
Ir Spectroscopic ◽  
Thermal Stability Of

Growth of optically transparent single crystals of thiourea succinic acid (TUSA) was grown successfully from aqueous solution by slow evaporation technique. The crystal structure was elucidated using the single crystal XRD. The various functional groups and the modes of vibrations were identified by FT-IR spectroscopic analysis. The optical absorption studies indicate that the optical transparency window is quite wide making its suitable for NLO applications. Thermal stability of the crown crystal carried out by TGA-DTA analysis.

Investigation on the growth, structural, HOMO–LUMO and optical studies of 1-ethyl-2-[2-(4-hydroxy-phenyl)-vinyl]-pyridinium iodide (HSPI) – a new stilbazolium derivative for third-order NLO applications

RSC Advances ◽  
2016 ◽  
Vol 6 (42) ◽  
pp. 35977-35990 ◽  
Author(s):  
K. Nivetha ◽  
S. Kalainathan ◽  
Manabu Yamada ◽  
Yoshihiko Kondo ◽  
Fumio Hamada
Keyword(s):  
Optical Quality ◽  
Slow Evaporation ◽  
Optical Studies ◽  
Third Order ◽  
Slow Evaporation Technique ◽  
Evaporation Technique ◽  
Optical Crystal ◽  
First Time ◽  
Homo Lumo ◽  
Phenyl Vinyl

The organic third-order non-linear optical crystal HSPI, a new derivative of the stilbazolium family, was successfully synthesized and the optical quality single crystal was grown by a slow evaporation technique for the first time.

scholarly journals Influence studies of doping on FTIR Spectra and Thermogravimetric Analysis of Barium Nitrate Crystals

2018 ◽  
Vol 15 (1) ◽  
pp. 83-90 ◽  
Author(s):  
Vanish H. Tandel ◽  
I. B. Patel ◽  
S.A. Suthar ◽  
A.M. Shah
Keyword(s):  
Magnesium Nitrate ◽  
Barium Nitrate ◽  
Ftir Spectra ◽  
Spectral Studies ◽  
Nitrate Hexahydrate ◽  
Slow Evaporation ◽  
Magnesium Nitrate Hexahydrate ◽  
Slow Evaporation Technique ◽  
Ionic Bonds ◽  
Evaporation Technique

Pure and Magnesium Nitrate hexahydrate (MgN) doped Barium Nitrate (BaN) crystals were grown by slow evaporation technique. FTIR spectral studies have been carried to identify the presence various functional groups. An FTIR spectrum of grown crystals confirms the presence of ionic bonds in the structure of pure and doped BaN crystals. The influence of MgN doping on FTIR spectra was absorbing frequencies by pure and doped BaN crystals were studied. Thermogravimetric of pure and doped BaN crystals were analysed to characterise thermal stability. Thermal parameters are evaluated using thermogram. The results are presented and discussed in this paper.

scholarly journals Enhancement of yttrium ion on the properties of L-histidine nitrate single crystal for frequency conversion applications

2019 ◽  
Vol 37 (4) ◽  
pp. 615-621 ◽  
Author(s):  
S. Sathiyanathan ◽  
M. Selvapandiyan
Keyword(s):  
Room Temperature ◽  
Frequency Conversion ◽  
Cutoff Wavelength ◽  
Slow Evaporation ◽  
Edax Analysis ◽  
Slow Evaporation Technique ◽  
Evaporation Technique ◽  
Ft Ir ◽  
Yttrium Ion ◽  
Lower Cutoff

AbstractNonlinear optical single crystals of L-histidine nitrate (LHN) as well as 0.05 mol % Y2+ doped LHN and 0.10 mol % Y2+ doped LHN were successfully grown by slow evaporation technique at room temperature. The lower cutoff wavelength and transmittance were 339 nm, 343 nm, 347 nm and 84 %, 86 % and 87 % for LHN, 0.05 mol % and 0.10 mol % yttrium doped LHN, respectively. Powder XRD studies revealed that the grown materials belong to an orthorhombic system with the space group P212121. FT-IR peak at 534 cm−1 due to yttrium coordinated with oxygen was observed. The EDAX analysis confirmed the presence of such elements as C, N, O and Y in the grown materials. High intensity PL emission peak was obtained at 420 nm.

scholarly journals Growth, Optical and Microhardness Studies of 2-Aminothiazole- 3, 5-Dinitrobenzoic Acid Complex

2019 ◽  
Vol 1 (1) ◽  
pp. 42-45
Author(s):  
Tamiloli Devendhiran ◽  
Keerthika Kumarasamy ◽  
Mei–Ching Lin
Keyword(s):  
Room Temperature ◽  
Grown Crystal ◽  
Optical Transmittance ◽  
Dielectric Measurements ◽  
Slow Evaporation ◽  
X Ray Diffraction ◽  
Acid Complex ◽  
X Ray ◽  
Slow Evaporation Technique ◽  
Evaporation Technique

Single crystals of 2-Aminothiazole 3,5-Dinitrobenzoic acid has been synthesized and good quality optical crystals were grown by slow evaporation technique at room temperature. The crystallinity nature of the grown crystal was confirmed from X-ray diffraction technique. An optical transmittance study was also carried out by UV – Vis spectra. FTIR spectra confirm the presence of functional groups in the grown crystal. The dielectric measurements were carried out in the range of 50Hz to 2MHz. The dielectric constant was seen to increase exponentially at lower frequencies. The microhardness studies were carried out using Vickers hardness indenter. Photoluminescence study shows that maximum emission occurs at 435nm.

scholarly journals Synthesis, Spectral, Structural and Thermal Characterization of Inorganic Crystal: Phenyl Trimethylammonium Tetrachlorocobaltate

2019 ◽  
Vol 31 (8) ◽  
pp. 1779-1784
Author(s):  
V. Mohanraj ◽  
R. Pavithra ◽  
M. Thenmozhi ◽  
R. Umarani
Keyword(s):  
Three Dimensional ◽  
Thermal Characterization ◽  
Dimensional Structure ◽  
X Ray Diffraction ◽  
Monoclinic Crystal ◽  
Evaporation Technique ◽  
Ft Ir ◽  
Thermal Stability Of ◽  
Ft Ir Spectroscopy

Phenyl trimethylammonium tetrachlorocobaltate, crystals were grown by slow evaporation technique. The crystal was bright, transparent. The three dimensional structure of the phenyl trimethylammonium tetrachlorocobaltate was obtained from single crystal X-ray diffraction studies. The molecule belongs to monoclinic crystal system with C2/c space group. The presence of functional groups and modes of vibrations were identified by FT-IR spectroscopy. 1H NMR spectroscopy was also used to characterise the compound and the thermal stability of the crystal was established by TGA/DT analysis. This work undergoes phase transition which makes the study interesting.

Growth and analysis of NSH and KMNSH crystals by slow evaporation technique

2014 ◽  
Vol 59 (7) ◽  
pp. 1114-1117 ◽  
Author(s):  
V. Masilamani ◽  
J. Shanthi ◽  
V. Sheelarani
Keyword(s):  
Slow Evaporation ◽  
Slow Evaporation Technique ◽  
Evaporation Technique
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