scholarly journals Contribution of the chemical and mineralogical properties of sandy-loam tropical soils to the cation exchange capacity

Author(s):  
Antonio Carlos Saraiva da Costa ◽  
Ivan Granemann de Souza ◽  
Leila Cristina Canton ◽  
Luciano Grillo Gil ◽  
Rodolfo Figueiredo
2014 ◽  
Vol 2014 ◽  
pp. 1-7
Author(s):  
Tope O. Bolanle-Ojo ◽  
Abiodun D. Joshua ◽  
Opeyemi A. Agbo-Adediran ◽  
Ademola S. Ogundana ◽  
Kayode A. Aiyeyika ◽  
...  

Conducting binary-exchange experiments is a common way to identify cationic preferences of exchangeable phases in soil. Cation exchange reactions and thermodynamic studies of Pb2+/Ca2+, Cd2+/Ca2+, and Zn2+/Ca2+were carried out on three surface (0–30 cm) soil samples from Adamawa and Niger States in Nigeria using the batch method. The physicochemical properties studies of the soils showed that the soils have neutral pH values, low organic matter contents, low exchangeable bases, and low effective cation exchange capacity (mean: 3.27 cmolc kg−1) but relatively high base saturations (≫50%) with an average of 75.9%. The amount of cations sorbed in all cases did not exceed the soils cation exchange capacity (CEC) values, except for Pb sorption in the entisol-AD2 and alfisol-AD3, where the CEC were exceeded at high Pb loading. Calculated selectivity coefficients were greater than unity across a wide range of exchanger phase composition, indicating a preference for these cations over Ca2+. TheKeqvalues obtained in this work were all positive, indicating that the exchange reactions were favoured and equally feasible. These values indicated that the Ca/soil systems were readily converted to the cation/soil system. The thermodynamic parameters calculated for the exchange of these cations were generally low, but values suggest spontaneous reactions.


2005 ◽  
Vol 62 (6) ◽  
pp. 552-558 ◽  
Author(s):  
Adriel Ferreira da Fonseca ◽  
Luís Reynaldo Ferracciú Alleoni ◽  
Adolpho José Melfi ◽  
Célia Regina Montes

The addition of Na-rich anthropogenic residues to tropical soils has stimulated the scientific community to study the role of sodium in both the soil solution and the exchange complex. In this study, several different methods were used to calculate the concentration of exchangeable and soluble cations and this data was then used to establish correlations between the level of these cations and both the accumulation of various elements and the dry weight of maize grown in a greenhouse under different conditions. In the closed environments of the pots, the most suitable method for calculating the effective cation exchange capacity (ECEC) was the cation exchange capacity calculated by cations removed with barium chloride solution (CEC S). Then again, the actual cation exchange capacity (CEC A) should be measured by using Mg adsorption to prevent ionic force from influencing electric charges. A strong positive correlation was obtained between the concentrations of Na in the 1:2 soil:water extracts and the accumulation of Na in the maize plants, indicating saline or double acid extractors are not needed when monitoring the Na concentration only.


1963 ◽  
Vol 43 (2) ◽  
pp. 229-234 ◽  
Author(s):  
A. A. MacLean ◽  
J. J. Doyle

Residual effects of long-term annual applications of fertilizer potassium on the potassium status of an acid sandy loam Podzol were investigated, in a greenhouse experiment. Potassium accumulated in the surface soil in a form readily available to plants.On plots with higher cation exchange capacities, resulting from manurial treatments, there was no evidence to indicate leaching below 15 inches. On plots where cation exchange capacity was not increased by treatment, a higher percentage potassium saturation at greater depths indicates that leaching of potassium had occurred to a depth of 21 inches. An increased concentration of nitric acid-soluble potassium at greater depths suggests that some of the leached potassium has been converted to the non-exchangeable form.Accumulation in the surface soil was sufficient to supply most of the potassium requirement of ladino clover under conditions of intensive cropping. The results suggest that exchangeable and nitric acid-soluble potassium are reliable criteria of available potassium.


1969 ◽  
Vol 36 (2) ◽  
pp. 155-160
Author(s):  
M. A. Lugo López ◽  
F. Abruña ◽  
J. Roldán

The quantity of limestone required to bring the pH of various acid Puerto Rican soils to 6.5 was investigated and found to vary from several hundred to several thousands pounds per acre. To investigate the relation of clay-mineral type, clay content, cation-exchange capacity, organic-matter content, and pH to lime requirement, these properties were determined for several soils. A highly significant regression of lime requirement on pH was obtained which can be expressed by the equation: Y = 18.39 — 3.196 X, where Y is the lime requirement and X is the pH value. Multiple regressions including other factors did not significantly increase the variability which could be explained on terms of the first regression. Further analysis were made by arranging the data according to the predominant clay mineral. For kaolinitic soils highly significant correlations were obtained between lime requirement and either pH or cation exchange capacity. The regressions were: (a) Y = 15.26 — 2.632 pH, and (b) Y = 3.048 + 0.5774 (cation-exchange capacity), where Y is the lime requirement. A regression of lime requirement on both factors did not significantly increase the variability explained by the second equation. No significant regressions were obtained for beidellitic soils.


2004 ◽  
Vol 84 (1) ◽  
pp. 91-102 ◽  
Author(s):  
K. R. Glowa ◽  
J. M. Arocena ◽  
H. B. Massicotte

Soil properties of rhizosphere zones in coniferous forests are influenced by the presence of ectomycorrhizae. To elucidate the role of ectomycorrhizae (ECM) on the alteration of chemical and mineralogical properties of soils, soil pH, total C and N, cation exchange capacity, and the contents of mica, chlorite, and kaolinite, 2:1 type expandable clays, and amorphous minerals were compared in two soils, soils influenced by ectomycorrhizal fungi (ECS) and non-ectomycorrhizosphere soils (N-ECM) of Picea glauca x engelmannii (Moench.) Voss. Specifically, the two ECS soils were dominated by (1) Piloderma spp. (ECS-A) and (2) Inocybe lacera-like and Hebeloma-like morphotypes or where Piloderma spp. colonization was <1% (ECS-B). Our results showed that pH was lower in ECS compared to N-ECM samples. Total C and N were significantly higher in ECS soils than N-ECM samples. Cation exchange capacity as well as exchangeable K+, and Na+ were higher in ECS compared to N-ECM soils. X-ray diffraction analysis showed that the amount of 2:1 expanding clays (vermiculite and smectite) was higher in ECS than N-ECM samples and results suggest that there is an enhanced transformation of mica and chlorite to 2:1 type expandable clays in ECS samples when compared to N-ECM samples. The differences in chemical and mineralogical properties between ECS and N-ECM soils, in our study, support earlier studies that show ectomycorrhizal fungi can alter the properties of soils in the rhizosphere zone. Key words: ectomycorrhizosphere soils, soil properties, Piloderma spp.


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