scholarly journals Comparison of metals content in peatlands with different anthropopressure in Welski Landscape Park (Poland)

2021 ◽  
pp. 20-28
Author(s):  
Bartłomiej Igliński ◽  
Anna Iglińska ◽  
Urszula Kiełkowska ◽  
Dariusz Kamiński ◽  
Grzegorz Piechota

The metal content was determined using the WD-XRF method in the peat from the Wąpiersk bog and the Las Nadwelski bog (Welski Landscape Park, Poland). The results of the study show that the concentration of metals, especially heavy metals in peat bogs in Welski Landscape Park is low in general. In both bogs, the concentration of heavy metals was lower in the center than on the border. This shows that heavy metals are absorbed by the peat at the border and their further migration is limited. There are more elements such as iron, calcium and magnesium in the Las Nadwelski bog. There is more light on the border of the forest, which also plays an important role in decomposing plant debris, releasing metals. Heavy metals content was higher in Wąpiersk bog – a bog with higher anthropopressure. To sum up, the peat bog actively captures heavy metals, immobilizing them, and acts as a kind of “filter”. Peat is a good agent for retrospective monitoring of metals migration and accumulation in the environment.

2019 ◽  
Vol 8 (3) ◽  
pp. 63-69
Author(s):  
Elena Sergeevna Novosyolova ◽  
Lyudmila Nikolaevna Shikhova ◽  
Evgeny Mikhailovich Lisitsin

The paper contains the research results on content of total and mobile heavy metals compounds (lead, cadmium, copper, and zinc) in soils of the cutover peat bog Zenginsky located in the central part of the Kirov Region. As a result of the conducted researches it is revealed that the content of elements in different peat layers in control site (zinc - up to 2,60; copper - up to 0,90; lead - up to 5,60; cadmium - up to 0,59 mg/kg of soil) does not exceed the level of their maximum-permissible concentration and background contents in soils of the Kirov Region. For the undeveloped site the increased content of total and mobile compounds of the studied metals in the top layers is noted; it can be caused by biogenous accumulation of these elements by plants. The developed soils (the drained sites) are characterized by considerable fluctuations of elements content both in different profiles, and in the different layers of the same profile. Here the maximum content of elements in separate layers is much higher than control (zinc - up to 126,0; copper - up to 34,0; lead - up to 17,0; cadmium - up to 1,2 mg/kg of soil). Economic use of the peat bogs leads to an active mineralization of the top part of the remained peat mass. As a result of these processes stability of biogeochemical cycles of separate elements is broken. At the same time, the received data allow to consider soils of control sites as indicators of surrounding environment condition. The good safety of peat deposits gives the opportunity to study processes of accumulation and migration of chemical elements.


2017 ◽  
Vol 17 (2) ◽  
pp. 131
Author(s):  
Emas Agus Prastyo Wibowo ◽  
Ika Sri Hardyanti ◽  
Isni Nurani ◽  
Dyan Septyaningsih Hardjono HP ◽  
Aden Dhana Rizkita

STUDI PENURUNAN KADAR LOGAM BESI (Fe) DAN LOGAM TEMBAGA (Cu) PADA AIR EMBUNG MENGGUNAKAN ADSORBEN NANOSILIKAABSTRAKPolusi limbah logam berat dalam air merupakan satu permasalahan lingkungan yang penting. Dalam mengatasi permasalahan tersebut dapat dilakukan purifikasi terhadap air tersebut. Metode yang dapat digunakan untuk purifikasi limbah sangat beragam salah satunya adalah absorpsi. Secara umum metode absorpsi telah banyak digunakan dalam purifikasi air limbah. Metode absorpsi dapat menurunkan kadar logam yang terlarut pada limbah. cair dengan cara menyerap logam-logam tersebut ke dalam permukaan absorbennya. Tujuan dilakukan penelitian ini adalah  untuk menurunkan konsentrasi logam besi (Fe) dan tembaga (Cu) menggunakan adsorben nanosilika. Penelitian ini menggunakan variabel bebas yaitu waktu pengadukan (20 menit, 40 menit, dan 60 menit). Hasil akhir filtrat air embung kemudian diukur absorbansinya menggunakan Spektrofotometer Serapan Atom. Berdasarkan hasil analisa menggunakan instrumen SSA diperoleh hasil bahwa tidak terjadi penurunan logam Fe maupun Cu. Dalam hal ini terjadi peningkatan konsentrasi dalam logam Fe maupun Cu, hal ini dikarenakan kurangnya waktu pengadukan dan pengaruh dari adsorben nanosilika.Kata Kunci: limbah, logam berat, nanosilika STUDY OF DECREASING METALS IRON (Fe) AND COPPER (Cu) ON EMBUNG WATER USE OF NANOSILICA ADSORBEN ABSTRACTHeavy waste pollution of heavy metals in the water is an important environment issue. To solve the problem, its can be purified the water. The methods that can be used for waste purification are very diverse, one of which is absorption. In general, the method of absorption has been widely used in wastewater purification. The absorption method can decrease dissolved metal content in the waste. liquid by absorbing the metals into the absorbent surface. Research has been conducted to reduce the concentration of iron (Fe) and copper (Cu) by using nanosilica adsorbent. This research used to independent variable that is stirring time (20 minutes, 40 minutes, and 60 minutes). The final result of filtrate embung water then measured its absorbance using Atomic Absorption Spectrophotometer (AAS). Based on the result of the analysis using SSA instrument, it is found that there is no decrease of Fe and Cu metals. There are several reasons for those problem such as due to lack of stirring time and the influence of nanosilica adsorbent.Keywords: Waste pollution, heavy metal, nanosilica


2021 ◽  
Author(s):  
Yang Lin ◽  
Kai Luo ◽  
Zilin Su ◽  
Yang Wu ◽  
Wei Xiao ◽  
...  

Abstract The urbanization is regarded as the major factor related to human activities that may interfere with the natural ecosystem. In this study, we have selected the wetland of East Dongting Lake as the research area. We have collected 180 soil samples (within the range of 0–20 cm, and 20cm-40cm), and we have measured the contents of their physicochemical properties (including salinity, pH value, soil particle composition, soil organic carbon, nitrate nitrogen and rapidly available phosphorus) as well as heavy metal elements (including As, Hg, Cd, Pb, Ni and Cr). We have adopted the methods of multivariate statistical analysis and inverse distance weighted (IDW) interpolation, so as to to reveal the sources and distribution characteristics of heavy metal content in soil in the research area. By adopting the potential ecological risk index (PERI) method proposed by Hakanson, we intend to assess the PERI values of heavy metals. Our research findings have shown that: (1) 8 sorts of heavy metals have shown positive correlation with each other. As, Hg and Zn have shown a significantly positive correlation with SOC (P < 0.01); As, Ni, Cr and Zn have shown a significantly positive correlation with AP (P < 0.01); As and Pb have shown a significantly positive correlation with Clay (P < 0.01); whereas Hg and Zn have shown a significantly negative correlation with Silt (P < 0.01); As and Pb have shown a significantly negative correlation with Sand (P < 0.01). (2) During urbanization, the elements of Cd, Ni, As, Hg and Pb might be enriched due to agricultural and industrial activities, whereas the use of fertilizers and pesticides constitute one of the major factors contributing to the increase of Cd and Pb contents in soil. (3) Influenced by the varying land patterns and with exception to Cu, the Fe-normalized concentrations have shown significant variations among different types of land use (P < 0.05). Specifically, there is a significantly higher level of Cd, Zn, Pb and Hg contents in the agricultural land than other types of land use, whereas there is a slightly higher level of heavy metal content in the mudflats than that in the grassland. In addition, the content of heavy metals in woodland remains relatively stable, and with exception to As, the content of heavy metals in woodland is the lowest among the five types of land. (4) The average value of the comprehensive PERI in heavy metals amounts to 555.03, representing a strong degree of ecological risks. Specifically, the proportion of sampling points of Cd that have a high level of ecological risks amounts to 36.51%, which is the primary element contributing to heavy metal pollution in the region, especially in the agricultural land.


2004 ◽  
Vol 4 (2) ◽  
pp. 58
Author(s):  
Lorraine A. Carrillo ◽  
Susan M. Gallardo

Wastewater treatment sludge, which is the largest volume residual waste stream generated by the pulp and paper industry, is generally disposed of in a dedicated landfill. Composting the sludge is an alternative method proposed by the Asian Regional Research Program on Environmental Technology-De La Salle University (ARRPET-DLSU) Minor Issue Group. The Philippine Department of Agriculture's (DA) standards for an organic fertilizer's maximum allowable content of heavy metals provided the legislative regulation for the conversion of sludge to compost. The research was designed to characterize the sludge samples from TIPCO, a Philippine paper-recycling mill, and establish whether the sludge contained the heavy metals cadmium, chromium, lead, mercury, nickel, and zinc using atomic absorption spectrophotometer (MS). Sampling was done for four weeks during newsprint and white paper production. Three discharge terminals were established as sampling points. The samples showed that the metal content of the sludge vary from point to point and was highest throughout the manufacture of white paper. Chromium, mercury, and nickel, however, were nondetectable in all the samples, while cadmium was detectable only in very few samples. Lead and zinc were present at all three points and were highest at the de inking sludge. Comparing the results with Part 503 of the United States EPA and the DA's guidelines for organic fertilizers yield significantly lower parameter values. Composting the sludge was, therefore, found to be a feasible option for recycling paper-mill sludge since the metal content were very low compared to local and international standards.


2021 ◽  
Vol 31 ◽  
pp. 00017
Author(s):  
Natalia Makeeva ◽  
Olga Neverova

The environmental effects of mining and its impact on natural resources are of a holistic nature. One of the modern methods employed for the remediation of technogenically disturbed soils is the application of microorganisms. This paper studies the impact made by soil microorganisms on the accumulation rate of heavy metals in the substrate of waste rock dumps in the process of soil reclamation. Suspensions of soil microorganisms (microorganisms utilising mineral nitrogen forms / MUMN; microorganisms decomposing silicates / MDS; microscopic fungi / MF) were applied to the rock dump surface. Separate groups as well as their combinations were applied. The heavy metal content analysis did not indicate a significant exceedance of the maximum allowable concentration limits (MACL) in the soil of the waste rock. The only metal whose content exceeded the maximum admissible concentration limits was nickel. It has found that the application of microorganisms influences the concentration of several heavy metals due to pH level changes of the rock dump soil.


1987 ◽  
Vol 26 ◽  
pp. 51-58
Author(s):  
Horas Hutagalung ◽  
Suwirma Syamsu

Determination of  heavy  metal  content  (Hg, Pb, Cd, Cu, Cr, Zn) in some seafoods collected from  Muara  Angke  Fish  Auction  Place  were carried out during February to July 1979. The results showed  that Zn  content  in seafoods a nalyzed  was always much higher than the other heavy metals. The concentration levels of  the  six  heavy  metals observed were low. It is almost of the same level as the metal concentration of  other  seafoods  observed  in various parts of the world oceans, but still lower  than the maximum standard set  for human  consumption  as  established  by   Tasmania, Australia and  World Health Organization. The  mean  per capita  consumption of  fish  in Jakarta is only  about 165 g  per week, while  the  Provisional Tolerated Weekly Intake for Hg, set by WHO/FAO at 300 ug level, would be attained by consuming 1500 g Rastrelliger sp., or 698 gPenaeus setiferus, or 545 g Sepia sp., and or 1250 g Pecten sp.  Therefore,  at   present the  level of metal content in fishes sold at TPI  Muara  Angke  can be  considered  as  not  dangerous  to human health as long as these quantities are not surpassed.


2016 ◽  
Vol 11 (1) ◽  
pp. 9 ◽  
Author(s):  
Yani Permanawati ◽  
Rina Zuraida ◽  
Andrian Ibrahim

Penelitian Lingkungan dan Kebencanaan Geologi Kelautan Perairan Teluk Jakarta (Tanjung Kait – Muara Gembong) dilakukan pada bulan Oktober - November 2010. Uji logam berat (Cu, Pb, Zn, Cd, dan Cr) dilakukan terhadap 28 contoh air laut dan 28 contoh sedimen dasar laut menggunakan metoda Atomic Absorption Spectrophotometry (AAS). Tujuan penelitian ini adalah untuk mendapatkan data dan informasi kondisi lingkungan terkini dari kandungan logam berat dalam air laut dan sedimen dasar laut. Kandungan logam berat (air laut dalam mg/l : sedimen dasar laut dalam ppm) terukur sebagai berikut : Cu ( <0.005 : 15.000-169.500 ); Pb (0.005-0.011 : 14.000-58.100); Zn (0.005-0.007 : 95.800-333.000); Cd (0.006-0.015 : 0.012-0.750); Cr (<0.001 : 45.320-139.180). Berdasarkan Metode Storet dapat dilihat nilai status mutu air laut perairan ini adalah -12, berarti bahwa kualitas air laut di perairan termasuk kelas C (tercemar sedang). Sedangkan status mutu sedimen di perairan menunjukkan skor nilai status mutu sedimen adalah 0, yang berarti bahwa kualitas sedimen termasuk kelas A (tidak tercemar/memenuhi baku mutu). Jelas terlihat bahwa nilai ambang batas (NAB) logam berat dalam sedimen jauh lebih tinggi dari NAB logam berat dalam air. Kata kunci: logam berat, sedimen dasar laut, air laut, nilai status mutu Marine Environmental and Geological Hazard Survey In Jakarta Bay Waters (Tanjung Kait - Muara Gembong) conducted in October-November 2010. Testing of heavy metals (Cu, Pb, Zn, Cd, and Cr) performed on 28 samples of sea water and 28 subsurface sediment samples using the method of Atomic Absorption Spectrophotometry (AAS). The purpose of this study was to obtain data and information on current environmental conditions of heavy metal content in seawater and subsurface sediment. Heavy metal content (sea water in mg/l: subsurface sediment in ppm) measured as follows: Cu ( <0.005 : 15.000-169.500 ); Pb (0.005-0.011 : 14.000-58.100); Zn (0.005-0.007 : 95.800-333.000); Cd (0.006-0.015 : 0.012-0.750); Cr (<0.001 : 45.320-139.180). Based on the Storet method shows the value of water quality status of sea waters is -12, which means that the seawater quality in these waters belong to a class C (medium contaminated). While the status of sediment quality in these waters indicate subsurface sediment quality score status value is 0, which means that subsurface sediment quality belongs to the class A (not polluted/correspond to the quality standards). It is clearly seen that the threshold value (NAV) of heavy metals in sediments is much higher than the NAV of heavy metals in water. Keywords: heavy metal, subsurface sediment, seawater, quality score status


2016 ◽  
Vol 23 (2) ◽  
pp. 271-283 ◽  
Author(s):  
Thomas Spanos ◽  
Antoaneta Ene ◽  
Chrysoula Styliani Patronidou ◽  
Christina Xatzixristou

AbstractThe aim of this study was to evaluate the temporal variations of selected heavy metals level in anaerobic fermented and dewatered sewage sludge. Sewage sludge samples were collected in different seasons and years from three municipal wastewater treatment plants (WWTPs) located in Northern Greece, in Kavala (Kavala and Palio localities) and Drama (Drama locality) Prefectures. An investigation of the potential of sludge utilization in agriculture was performed, based on the comparison of average total heavy metal concentrations and of chromium species (hexavalent, trivalent) concentrations with the allowed values according to the Council Directive 86/278/EEC and Greek national legislation (Joint Cabinet Decision 80568/4225/91) guidelines. In this regard, all the investigated heavy metals (Cd, Cr, Cu, Ni, Pb, Zn, Hg) and chromium species Cr(VI) and Cr(III) have average concentrations (dry matter weight) well below the legislated thresholds for soil application, as following: 2.12 mg kg−1Cd; 103.7 mg kg−1Cr; 136.4 mg kg−1Cu; < 0.2 mg kg−1Hg; 29.1 mg kg−1Ni; 62.0 mg kg−1Pb; 1253.2 mg kg−1Zn; 1.56 mg kg−1Cr(VI) and 115.7 mg kg−1Cr(III). Values of relative standard deviation (RSD) indicate a low or moderate temporal variability for domestic-related metals Zn (10.3-14.7%), Pb (27.9-44.5%) and Cu (33.5-34.2%), and high variability for the metals of mixed origin or predominantly resulted from commercial activities, such as Ni (42.4-50.7%), Cd (44.3-85.5%) and Cr (58.2-102.0%). For some elements the seasonal occurrence pattern is the same for Kavala and Palio sludge, as following: a) Cd and Cr: spring>summer>winter; b) Cu, Ni and Pb: winter>spring>summer. On average, in summer months (dry season) metal concentrations are lower than in spring and winter (wet seasons), with the exception of Zn. For Kavala and Palio the results demonstrate that the increased number of inhabitants (almost doubled) in summer time due to tourism does not influence the metal levels in sludge. Comparing the results obtained for similar spring-summer-winter sequences in 2007 and 2010/11 and for the spring season in 2007, 2008 and 2010, it can be noticed that, in general, the average heavy metal contents show an increasing tendency towards the last year. In all the measurement periods, the Palio sludge had the highest metal contents and Kavala sludge the lowest, leading to the conclusion that the WWTP operating process rather than population has a significant effect upon the heavy metal content of sludge. Cr(VI)/Cr(total) concentration ratios are higher for Kavala sludge in the majority of sampling campaigns, followed by Drama and Palio sludge. The metals which present moderate to strong positive correlation have common origin, which could be a domestic-commercial mixed source.


BioResources ◽  
2021 ◽  
Vol 16 (3) ◽  
pp. 5047-5057
Author(s):  
Corneliu Tanase ◽  
Adrian Nisca ◽  
Argeime Lopez

Extracts obtained from the bark of woody plants are used for their high content in polyphenolic compounds with various biological activities. Thus, it is important to evaluate the heavy metals in various tree barks, as these pollutants may end up in the final product, affecting its properties and having potential health implications. This study assessed the heavy metal content in the barks of spruce (Picea abies) and pine (Pinus sylvestris and Pinus nigra) collected from different areas in Romania. After collecting the vegetal material from different sites, the bark samples were appropriately processed and analyzed via inductively coupled plasma optical emission spectroscopy (ICP-OES). The results showed that 6 out of 8 tested samples exceeded the normal values of selenium (Se). Arsenic (As) and cadmium (Cd) were not detected in any sample, while other metals (chromium (Cr); lead (Pb); nickel (Ni)) were detected in variable amounts. Moreover, relatively high levels of heavy metals were recorded in a spruce bark sample collected from the seemingly most unpolluted site. Although further studies are needed to determine the effects of these heavy metals on extraction yields and their transfer into the final extracts, their presence might indicate a potential problem.


2019 ◽  
Vol 17 (2) ◽  
pp. 256
Author(s):  
Rosye H.R. Tanjung ◽  
Suwito Suwito ◽  
Vita Purnamasari ◽  
Suharno Suharno

Kebutuhan bahan pangan sangat tergantung pada ketersediaanya di lingungan. Bahan pangan yang diperlukan untuk memenuhi kebutuhan sehari-hari harus sehat dan bebas dari bahan pencemar, termasuk logam berat. Ikan kakap putih (Lates calcarifer) sering dijumpai pada kawasan muara sungai di hampir seluruh wilayah Indonesia, bahkan di Papua. Tujuan penelitian ini adalah untuk mengkaji kandungan logam berat Pb, Cd, Cu, Fe, As, dan Hg pada ikan kakap putih (L. calcarifer) yang hidup di perairan estuari Mimika Papua. Perairan estuari di Mimika diketahui sebagai salah satu daerah pengendapan pasir sisa tambang (tailing). Metode yang digunakan adalah survei dan analisis laboratorium kandungan logam berat pada tubuh ikan. Analisis Pb, Cd, Cu, Fe, As, dan Hg ditentukan dengan spektroskopi serapan atom (AAS, Atomic Absorpsion Spectroscopy). Penentuan tingkat pencemaran logam berat dilakukan dengan Metode Standar APHA 3113 Cetac Technologies SPR IDA. Analisis data dilakukan dengan membandingkan kandungan logam berat dalam air dengan baku mutu air laut menurut SK MNLH No. 51 tahun 2004. Untuk kandungan logam berat pada organ tubuh ikan dibandingkan dengan kandungan maksimum logam berat berdasarkan SNI 7387: 2009 tentang batas maksimum cemaran logam berat bahan pangan. Kandungan logam berat pada ikan kakap putih masih tergolong aman dikonsumsi karena mengandung logam berat di bawah ambang batas baku mutu. Kondisi ini didukung oleh hasil analisis logam berat pada air yang menunjukkan masih dalam kondisi baik.   Kata kunci: L. calcarifer, logam berat, Sungai Kamora, Sungai Ajkwa, Mimika.   The need for food depends on the availability in the environment. Foods needed to meet daily needs should be healthy and free of pollutants, including heavy metals. White snapper (Lates calcarifer) is often found in the estuary of the river in almost all parts of Indonesia, even in Papua. The purpose of this research is to study the heavy metal content of Pb, Cd, Cu, Fe, As, and Hg on white snapper (L. calcarifer) which live in Mimika Papua estuary waters. The estuary waters of Mimika are known as one of the deposition areas of tailings sand. The method used is survey and laboratory analysis of heavy metal content in fish body. Analysis of Pb, Cd, Cu, Fe, and Hg was determined by Atomic Absorption Spectroscopy (AAS). Determination of the level of heavy metal contamination was done by Standard Method of APHA 3113 Cetac Technologies SPR IDA. Data analysis was done by comparing the heavy metal content in water with sea water quality standard according to SK MNLH No. 51 year 2004. For heavy metal content in fish body organs compared with maximum content of heavy metals based on SNI 7387: 2009 on the maximum limit of heavy metal food contamination. The content of heavy metals in white snapper is still considered safe for consumption because its below the quality standard threshold. This condition is supported by the results of heavy metal analysis on the water which shows still in good condition. Key words: L. calcarifer, heavy metal, Kamora River, Ajkwa River, Mimika.


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