Similar and Different: Effect of Substitution Pattern on the Aggregation-Induced Emission Property of [4'-(bisphenylamino)[1,1']biphenyl]methylene Fluorenes

2013 ◽  
Vol 859 ◽  
pp. 329-332
Author(s):  
Zhi Chen ◽  
Yi Long Xie ◽  
Jin Xing Qiu ◽  
Zhong He Chen
Keyword(s):  
Solid State ◽  
Optical Property ◽  
Quantum Yield ◽  
Suzuki Coupling ◽  
Emission Property ◽  
Aggregate State ◽  
Substitution Pattern ◽  
Aggregation Induced Emission ◽  
Emission Behavior ◽  
Fluorescent Quantum Yield

Three isomers, [4'-(bisphenylamino)[1,1']biphen-2-yl]methylenefluorene (BAB2MF), [4'-(bisphenylamino)[1,1']biphen-3-yl]methylenefluorene (BAB3MF) and [4'-(bisphenylamino)[1,1']biphen-4-yl]methylenefluorene (BAB4MF), were synthesized through Suzuki coupling. The substitution pattern exerts a dramatic influence on the optical property. BAB3MF and BAB4MF are hardly emissive either in the solution or as solid state. On the contrary, BAB2MF emits strongly, especially in the aggregate state with a high fluorescent quantum yield of 69%. Furthermore, BAB2MF shows an aggregation-induced enhanced emission behavior. BAB2MF solid emits at 488 nm, about 60 nm blue-shifted from its solution.

Aggregation-induced emission in precursors to porous molecular crystals

2017 ◽  
Vol 53 (72) ◽  
pp. 10022-10025 ◽  
Author(s):  
Zhenglin Zhang ◽  
Mohamed I. Hashim ◽  
Ognjen Š. Miljanić
Keyword(s):  
Solid State ◽  
Molecular Crystals ◽  
Aggregation Induced Emission ◽  
Emission Behavior ◽  
Solid State Fluorescence

Trigonal fluorinated pyrazoles assemble into porous molecular crystals and show solid-state fluorescence. However, their emission behavior in solution is dramatically different.

Synthesis and Spectroscopic Characteristics of Ligands Based on Quinolin-8-Ol as Useful Precursors for Alq3 Type Complexes

2021 ◽  
Vol 903 ◽  
pp. 168-173
Author(s):  
Elmārs Zariņš ◽  
Deins Alksnis ◽  
Patricija Paulsone ◽  
Karlis Balodis ◽  
Aivars Vembris ◽  
...  
Keyword(s):  
Solid State ◽  
Light Emission ◽  
Emission Property ◽  
Blue Luminescence ◽  
Reaction Conditions ◽  
Aggregation Induced Emission ◽  
Chemical Structures ◽  
Emission Enhancement ◽  
Spectroscopic Characteristics ◽  
Reliable Methods

In order to develop reliable methods for the synthesis of various 5-substituted-8-oxyquinoline derivatives for the preparation of Alq3-type complexes, we have improved the reaction conditions on some syntheses described in the literature, successfully synthesized new ligands based on quinolin-8-ol and characterized their chemical structures by NMR. Some of the synthesized quinolin-8-ol derivatives containing incorporated bulky triphenyl or tert-butyl groups showed blue luminescence in the solid state due to the possible aggregation induced emission enhancement (AIEE) with a maximum wavelength around 510 nm. More detailed light-emission property investigation of the mentioned bulky group containing compounds is currently underway.

Solid-state thiolate-stabilized copper nanoclusters with ultrahigh photoluminescence quantum yield for white light-emitting devices

Nanoscale ◽  
2020 ◽  
Vol 12 (29) ◽  
pp. 15791-15799 ◽  
Author(s):  
Hao-Hua Deng ◽  
Qiong-Qiong Zhuang ◽  
Kai-Yuan Huang ◽  
Paramasivam Balasubramanian ◽  
Zhen Lin ◽  
...  
Keyword(s):  
Solid State ◽  
Quantum Yield ◽  
White Light ◽  
Copper Nanoclusters ◽  
Light Emitting ◽  
Aggregation Induced Emission ◽  
Emission Properties ◽  
Light Emitting Devices ◽  
Photoluminescence Quantum Yield

White-light-emitting devices are successfully fabricated by using solid-state copper nanoclusters as the sole phosphors with aggregation-induced emission properties.

scholarly journals The Solid-State Emission of Bilirubin

2020 ◽  
Author(s):  
Ahmed El-Zohry ◽  
Taha Ahmed ◽  
Burkhard Zietz
Keyword(s):  
Solid State ◽  
Quantum Yield ◽  
Room Temperature ◽  
Crystal Quality ◽  
Biological Sensors ◽  
Frenkel Exciton ◽  
Aggregation Induced Emission ◽  
Isomerization Process ◽  
Emission Lifetime

<p>Bilirubin (BR) is a human-biological compound formed during the haem metabolism that is insoluble in most solvents. BR has shown short emission lifetime with low quantum yield in limited number of solvents, due to the non-radiative ultrafast isomerization process. However, in solid-state, red-shifted emission of long-lived species of BR are detected at room temperature, due to the aggregation-induced emission formed by Frenkel exciton of J-system. This solid-state emission of BR depends on the crystal quality of BR as shown by SEM and XRD. This study allows for better understandings of the photophysics of BR in solid-state, opening opportunities for its applications in luminescent biological sensors. </p>

scholarly journals Solid-State Highly Efficient DR Mono and Poly-Dicyano-Phenylenevinylene Fluorophores

2018 ◽  
Author(s):  
Barbara Panunzi ◽  
Rosita Diana ◽  
Simona Concilio ◽  
Lucia Sessa ◽  
Rafi Shikler ◽  
...  
Keyword(s):  
Solid State ◽  
Quantum Yield ◽  
Fluorescence Quantum Yield ◽  
Spectroscopic Properties ◽  
Crystallographic Data ◽  
Time Dependent ◽  
Aggregation Induced Emission ◽  
Solid Films ◽  
Highly Efficient ◽  
Organic Solid

A highly efficient deep red (DR) emitting organic solid based on a dicyano-phenylenevinylene derivative was reported. The structural and spectroscopic properties of the solid have been described in terms of crystallographic data and time dependent DFT analysis. A noteworthy fluorescence quantum yield of 53% was observed for the brightest emitter cast into solid films. This result can be explained in terms of aggregation-induced emission (AIE) effect.

scholarly journals Aggregation induced emission of chalcones

2021 ◽  
Author(s):  
Sneha Kagatikar ◽  
Dhanya Sunil
Keyword(s):  
Solid State ◽  
Hydrogen Atom ◽  
Functional Group ◽  
Evidence Based ◽  
Luminescent Materials ◽  
Biological Applications ◽  
Optical Performance ◽  
Aggregate State ◽  
Aggregation Induced Emission ◽  
Quenching Effect

AbstractThere is always a need for efficient luminescent materials with simple synthesis and possible ease of hydrogen atom or functional group manipulation for use in different optoelectronic and biological applications. However, for certain real-world uses aggregation caused quenching effect of luminophores in their solid/aggregate state is undesirable, and is a cause of concern in areas, wherein the solid-state optical performance is more crucial. In this regard, chalcones have been explored for their ability to display aggregation-induced emission (AIE) or aggregation-induced enhanced emission (AIEE), which can be of practical use. This article is thus focused on an integrated evidence-based report on the AIE/AIEE-active chalcone systems for potential technological and biological applications. Graphic abstract

scholarly journals The Solid-State Emission of Bilirubin

2020 ◽  
Author(s):  
Ahmed El-Zohry ◽  
Taha Ahmed ◽  
Burkhard Zietz
Keyword(s):  
Solid State ◽  
Quantum Yield ◽  
Room Temperature ◽  
Crystal Quality ◽  
Biological Sensors ◽  
Frenkel Exciton ◽  
Aggregation Induced Emission ◽  
Isomerization Process ◽  
Emission Lifetime

<p>Bilirubin (BR) is a human-biological compound formed during the haem metabolism that is insoluble in most solvents. BR has shown short emission lifetime with low quantum yield in limited number of solvents, due to the non-radiative ultrafast isomerization process. However, in solid-state, red-shifted emission of long-lived species of BR are detected at room temperature, due to the aggregation-induced emission formed by Frenkel exciton of J-system. This solid-state emission of BR depends on the crystal quality of BR as shown by SEM and XRD. This study allows for better understandings of the photophysics of BR in solid-state, opening opportunities for its applications in luminescent biological sensors. </p>

scholarly journals A series of 4,5,9,10-tetrahydropyrene-based tetraarylethenes: synthesis, structures and solid-state emission behavior

RSC Advances ◽  
2018 ◽  
Vol 8 (27) ◽  
pp. 15173-15180 ◽  
Author(s):  
Zhao-Ming Zhang ◽  
Bao-Xi Miao ◽  
Xin-Xue Tang ◽  
Zhong-Hai Ni
Keyword(s):  
Solid State ◽  
Quantum Yield ◽  
Fluorescence Quantum Yield ◽  
Emission Behavior

Tetraarylethenes with different π-conjugation degrees can be realized by controlling the number of 4,5,9,10-tetrahydropyrene segments. However, the fluorescence quantum yield of these compounds in films doesn't increase with the π-conjugation degree.

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