Influence of the Variability of Limestone and Fly Ash on the Setting and Mechanical Properties of a Moroccan Composite Cement

Author(s):  
Nisrine El Fami ◽  
Hind Agourrame ◽  
Nacer Khachani ◽  
Ali Boukhari ◽  
Adeljebbar Diouri

The Moroccan cement industry is looking for new processes to effectively minimize the high energy costs associated to cement manufacturing. This work presents the effect of three types of limestone with different chemical compositions and different CaCO3 contents on the physical and mechanical properties of resulting composite cements by the addition of fly ash in the proportions by weight of: 5 % and 10 %. The samples are studied in order to evaluate the interaction between different types of limestone and fly ash. Ternary cements based on fly ash-limestone-clinker induce a significant prolongation of the setting time compared to binary cements based on limestone-clinker. The substitution of clinker by limestone induces an improvement in mechanical strength compared to ternary cements in the first days; at 28 days, cements prepared with fly ashes reach significant strength due to their pozzolanic reaction.

Author(s):  
Vu-An Tran

This research investigates the physical and mechanical properties of mortar incorporating fly ash (FA), which is by-product of Duyen Hai thermal power plant. Six mixtures of mortar are produced with FA at level of 0%, 10%, 20%, 30%, 40%, and 50% (by volume) as cement replacement and at water-to-binder (W/B) of 0.5. The flow, density, compressive strength, flexural strength, and water absorption tests are made under relevant standard in this study. The results have shown that the higher FA content increases the flow of mortar but significantly decreases the density of mixtures. The water absorption and setting time increases as the samples incorporating FA. Compressive strength of specimen with 10% FA is approximately equal to control specimen at the 91-day age. The flexural strength of specimen ranges from 7.97 MPa to 8.94 MPa at the 91-day age with the best result for samples containing 10% and 20% FA.


2010 ◽  
Vol 150-151 ◽  
pp. 1655-1661 ◽  
Author(s):  
Dong Xu Li ◽  
Chun Hua Feng

Fly ash can improve the physical and mechanical properties of the magnesium phosphate cement (MPC) paste. The influence of fly ash on the strength, the mortar fluidity, the durability and the setting time of MPC paste were studied in this paper. The results show that: The function of fly ash to the MPC is as followed: physical fill, superplastic and chemical reactions; the optimal content of fly ash is about 30% by weight, and MPC with 30% fly ash has excellent mechanical property and high fluidity; the fineness of magnesia affected the mechanical properties of MPC.


2021 ◽  
Vol 15 (1) ◽  
pp. 51
Author(s):  
Anni Susilowati ◽  
Iqbal Yusra

Abstract One of the world's construction needs is casting in large volumes that require concrete with low hydration heat, and one of the problems is that the concrete has a setting during the casting queue. Therefore, a research was conducted on adding retarder to concrete with a mixture of GGBFS and Fly Ash. The purpose of this research was to analyze the physical and mechanical properties of concrete, the effect of adding retarder and obtain optimal retarder levels. This research used an experimental methods to make concrete specimens of 75% cement mix: GGBFS 15%: Fly Ash 10% with a water cement ratio of 0.5 using mix design SNI-03-2834-2000. Variations of the retarder added to the concrete mixture were 0%, 0.2%, 0.4%, and 0.6% by weight of cement with the Naptha RD 31 type. Analysis of the effect of the retarder used statistical regression test methods on SPSS. The results of research obtained the longest setting time in this researchwas 1890 minutes at a variation of 0.6% with a slump of 168 mm. The compressive strength of the concrete increased by 12.07% - 52.36% by using a retarder added material. Based on the research results, it was obtained that the optimum level of use of retarder in mixed concrete GGBFS and Fly Ash was 0.2% because it has the best physical and mechanical properties. Keywords: Fly Ash, GGBFS, Compressive Strength, Retarder


2019 ◽  
Vol 280 ◽  
pp. 04013
Author(s):  
Irfan Prasetia ◽  
M. Fahmi Rizani

Nowadays, PLTU Asam-Asam produced enormous amounts of combustion waste in the form of coal ash. On the contrary, only a little effort has been made to utilize coal ash from PLTU Asam-Asam, especially from the research side. In fact, due to its siliceous material, when reacting with CH in concrete, will form CSH hence improves concrete strength. In this study, in order to analyze the physical and mechanical properties of concrete using fly ash from PLTU Asam-Asam, 54 concrete samples were prepared according to SNI-03-2834-2000. The examination of concrete samples workability was conducted based on the slump test according to SNI 1972:2008. Moreover, the compressive tests were carried out in accordance with SNI 1974:2011. The slump test results show that the pozzolanic reaction of fly ash contributes to the improvement of concrete workability. Furthermore, the variation in w/b ratio was also affecting the results of the slump test. As for the compressive strength, in general speaking, the replacement ratio of 30% of cement with fly ash in concrete could produce concrete strength up to 30 Mpa. It is also important to note that due to the pozzolanic reactions tends to delayed, it is expected that at later ages (above 28 days) concrete with fly ash will gain much more strength compared to ordinary concrete.


Materials ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1109
Author(s):  
Mati Ullah Shah ◽  
Muhammad Usman ◽  
Muhammad Usman Hanif ◽  
Iqra Naseem ◽  
Sara Farooq

The huge amount of solid waste from the brick manufacturing industry can be used as a cement replacement. However, replacement exceeding 10% causes a reduction in strength due to the slowing of the pozzolanic reaction. Therefore, in this study, the pozzolanic potential of brick waste is enhanced using ultrafine brick powder with hydrated lime (HL). A total of six self-compacting paste mixes were studied. HL 2.5% by weight of binder was added in two formulations: 10% and 20% of waste burnt brick powder (WBBP), to activate the pozzolanic reaction. An increase in the water demand and setting time was observed by increasing the replacement percentage of WBBP. It was found that the mechanical properties of mixes containing 5% and 10% WBBP performed better than the control mix, while the mechanical properties of the mixes containing 20% WBBP were found to be almost equal to the control mix at 90 days. The addition of HL enhanced the early-age strength. Furthermore, WBBP formulations endorsed improvements in both durability and rheological properties, complemented by reduced early-age shrinkage. Overall, it was found that brick waste in ultrafine size has a very high degree of pozzolanic potential and can be effectively utilized as a supplementary cementitious material.


2017 ◽  
Vol 866 ◽  
pp. 199-203
Author(s):  
Chidchanok Chainej ◽  
Suparut Narksitipan ◽  
Nittaya Jaitanong

The aims of this research were study the microstructures and mechanical properties for partial replacement of cement with Fly ash (FA) and kaolin waste (KW). Ordinary Portland cement were partially replaced with FA and KW in the range of 25-35% and 10-25% by weight of cement powder. The kaolin waste was ground for 180 minutes before using. The specimen was packing into an iron mold which sample size of 5×5×5 cm3. Then, the specimens were kept at room temperature for 24 hours and were moist cured in the incubation lime water bath at age of 3 days. After that the specimens were dry cured with plastic wrap at age of 3, 7, 14 and 28 days. After that the compounds were examined by x-ray diffraction patterns (XRD) and the microstructures were examined by scanning electron microscopy (SEM). The compressive strength was then investigated.


2011 ◽  
Vol 2011 ◽  
pp. 1-5 ◽  
Author(s):  
In-Jin Shon ◽  
In-Yong Ko ◽  
Seung-Hoon Jo ◽  
Jung-Mann Doh ◽  
Jin-Kook Yoon ◽  
...  

Nanopowders of 3NiAl and Al2O3were synthesized from 3NiO and 5Al powders by high-energy ball milling. Nanocrystalline Al2O3reinforced composite was consolidated by high-frequency induction-heated sintering within 3 minutes from mechanochemically synthesized powders of Al2O3and 3NiAl. The advantage of this process is that it allows very quick densification to near theoretical density and inhibition grain growth. Nanocrystalline materials have received much attention as advanced engineering materials with improved physical and mechanical properties. The relative density of the composite was 97%. The average Vickers hardness and fracture toughness values obtained were 804 kg/mm2and 7.5 MPa⋅m1/2, respectively.


2020 ◽  
Author(s):  
N. H. Teng ◽  
H. C. Yong ◽  
M. M. A. Abdullah ◽  
N. Yong-Sing ◽  
K. Hussin

2018 ◽  
Vol 2018 ◽  
pp. 1-12 ◽  
Author(s):  
Li Wang ◽  
Hongliang Zhang ◽  
Yang Gao

Low temperature negatively affects the engineering performance of cementitious materials and hinders the construction productivity. Previous studies have already demonstrated that TiO2 nanoparticles can accelerate cement hydration and enhance the strength development of cementitious materials at room temperature. However, the performance of cementitious materials containing TiO2 nanoparticles at low temperatures is still unknown. In this study, specimens were prepared through the replacement of cement with 1 wt.%, 2 wt.%, 3 wt.%, 4 wt.%, and 5 wt.% TiO2 nanoparticles and cured under temperatures of 0°C, 5°C, 10°C, and 20°C for specific ages. Physical and mechanical properties of the specimens were evaluated through the setting time test, compressive strength test, flexural strength test, hydration degree test, mercury intrusion porosimetry (MIP), X-ray diffraction (XRD) analysis, thermal gravimetric analysis (TGA), and scanning electron microscopy (SEM) in order to examine the performance of cementitious materials with and without TiO2 nanoparticles at various curing temperatures. It was found that low temperature delayed the process of cement hydration while TiO2 nanoparticles had a positive effect on accelerating the cement hydration and reducing the setting time in terms of the results of the setting time test, hydration degree test, and strength test, and the specimen with the addition of 2 wt.% TiO2 nanoparticles showed the superior performance. Refined pore structure in the MIP tests, more mass loss of CH in TGA, intense peak appearance associated with the hydration products in XRD analysis, and denser microstructure in SEM demonstrated that the specimen with 2 wt.% TiO2 nanoparticles exhibited preferable physical and mechanical properties compared with that without TiO2 nanoparticles under various curing temperatures.


Materials ◽  
2021 ◽  
Vol 14 (21) ◽  
pp. 6692
Author(s):  
Xianhui Zhao ◽  
Haoyu Wang ◽  
Linlin Jiang ◽  
Lingchao Meng ◽  
Boyu Zhou ◽  
...  

The long-term property development of fly ash (FA)-based geopolymer (FA−GEO) incorporating industrial solid waste carbide slag (CS) for up to 360 d is still unclear. The objective of this study was to investigate the fresh, physical, and mechanical properties and microstructures of FA−GEO composites with CS and to evaluate the effects of CS when the composites were cured for 360 d. FA−GEO composites with CS were manufactured using FA (as an aluminosilicate precursor), CS (as a calcium additive), NaOH solution (as an alkali activator), and standard sand (as a fine aggregate). The fresh property and long-term physical properties were measured, including fluidity, bulk density, porosity, and drying shrinkage. The flexural and compressive strengths at 60 d and 360 d were tested. Furthermore, the microstructures and gel products were characterized by scanning electron microscopy (SEM) with energy dispersive spectroscopy (EDS). The results show that the additional 20.0% CS reduces the fluidity and increases the conductivity of FA−GEO composites. Bulk densities were decreased, porosities were increased, and drying shrinkages were decreased as the CS content was increased from 0.0% to 20.0% at 360 d. Room temperature is a better curing condition to obtain a higher long-term mechanical strength. The addition of 20.0% CS is more beneficial to the improvement of long-term flexural strength and toughness at room temperature. The gel products in CS−FA−GEO with 20.0% CS are mainly determined as the mixtures of sodium aluminosilicate (N−A−S−H) gel and calcium silicate hydration (C−S−H) gel, besides the surficial pan-alkali. The research results provide an experimental basis for the reuse of CS in various scenarios.


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