Mechanical Properties of Bamboo Charcoal (BC)/Poly(Lactic) Acid (PLA) Composites

2019 ◽  
Vol 801 ◽  
pp. 121-126
Author(s):  
Rapeeporn Srisuk ◽  
Laongdaw Techawinyutham ◽  
Wantana Koetniyom ◽  
Rapeephun Dangtungee
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Lactic Acid ◽  
Shear Viscosity ◽  
Tensile Modulus ◽  
Poly Lactic Acid ◽  
Bamboo Charcoal ◽  
Elongation At Break ◽  
The Matrix

The influence of bamboo charcoal (BC) in Poly (lactic) acid (PLA) matrix as masterbatch was studied on mechanical 40:60, 50:50 and 60:40 of masterbatch. BC MBs were diluted at 1 phr, 3 phr, and 5 phr. BC showed even distribution in PLA matrix; however,, it decreased compatibility in the matrix. The infusion of BC in PLA matrix enhanced the tensile modulus; however, there was a reduction in the tensile strength and the elongation at break. It could also be ascertained that there is no signification difference in the hardness of BC/PLA composites compared with neat PLA. The addition of BC slightly decreased shear viscosity of the composites. The optimal BC content in the composites was found to be 2.82wt.% (5 phr 60:40).

PLA-Based Biodegradable Copolyester Nanocomposites: Preparation, Characterization and Mechanical Properties

2011 ◽  
Vol 380 ◽  
pp. 290-293
Author(s):  
Bing Tao Wang ◽  
Ping Zhang ◽  
De Gao
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Lactic Acid ◽  
Interfacial Adhesion ◽  
Polyhedral Oligomeric Silsesquioxanes ◽  
Elongation At Break ◽  
Butylene Terephthalate ◽  
The Matrix ◽  
Different Characteristics

In situ melt copolycondensation was proposed to prepare biodegradable copolyester nanocomposites based on degradable components poly(L-lactic acid) (PLA), rigid segments poly(butylene terephthalate) (PBT), and nanoparticles polyhedral oligomeric silsesquioxanes (POSS). The morphologies and dispersions of two POSS nanoparticles (POSS-NH2 and POSS-PEG) in the copolyester PLABT matrix and their effects on the mechanical properties were investigated. The results demonstrated that the morphologies and dispersions of POSS-NH2 and POSS-PEG showed quite different characteristics. POSS-PEG took better dispersion in the PLABT, while POSS-NH2 had poor dispersions and formed crystalline microaggregates. Due to the good dispersion and strong interfacial adhesion of POSS-PEG with the matrix, the tensile strength and Young’s modulus were greatly improved from 6.4 and 9.6 MPa for neat PLABT up to 11.2 and 70.7 MPa for PLABT/POSS-PEG nanocomposite. Moreover, the incorporation of POSS-PEG could impart macromolecular chains good flexibility and improve the mobility of the chains, so the the elongation at break of PLABT/POSS-PEG nanocomposite dramatically increased from 190 to 350 % compared with neat PLABT.

Mechanical and Morphological Behavior of Blends Obtained from Biopolymers (PLA/PLC)

2014 ◽  
Vol 775-776 ◽  
pp. 24-28
Author(s):  
Taciana Regina de Gouveia Silva ◽  
Bartira Brandão da Cunha ◽  
Pankaj Agrawal ◽  
Edcleide Maria Araújo ◽  
Tomás Jefférson Alves de Mélo
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Lactic Acid ◽  
Elastic Modulus ◽  
Impact Strength ◽  
Polymer Blends ◽  
Poly Lactic Acid ◽  
Elongation At Break ◽  
Morphology Analysis ◽  
Morphological Behavior

In this work, the effect of the PCL content and E-GMA compatibilizer on the mechanical properties and morphology of poly (lactic acid) - PLA/ poly (ε-caprolactone)-PCL blends was investigated. The results of the mechanical properties showed that there was a reduction in the elastic modulus and tensile strength when PCL was added to PLA. The decrease in the modulus was more pronounced when the PCL content was increased from 10 to 20% (wt). The PLA/PCL/E-GMA blend showed the lower modulus and tensile strength. This blend also presented the higher elongation at break and impact strength. The morphology analysis by SEM showed that the PLA/PCL blends where characterized by lack of adhesion between the PLA and PCL phases. The presence of E-GMA in the PLA/PCL/E-GMA blend improved the adhesion between the PLA and PCL phases.Keywords: poly (latic acid); poly (ε-caprolactone); polymer blends; compatibilizer

scholarly journals Mechanical Properties of Poly (lactic acid) Composites Reinforced with CaCO3 Eggshell Based Fillers

MRS Advances ◽  
2017 ◽  
Vol 2 (47) ◽  
pp. 2545-2550 ◽  
Author(s):  
Nicholas G. Betancourt ◽  
Duncan E. Cree
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Lactic Acid ◽  
Water Absorption ◽  
Filler Content ◽  
Tensile Modulus ◽  
Charpy Impact ◽  
Filler Loading ◽  
Poly Lactic Acid ◽  
Particle Sizes

ABSTRACTPoly (lactic acid) (PLA) bioplastics are recyclable and biodegradable thermoplastics. They are derived from environmentally friendly sources such as potatoes, cornstarch and sugarcane. However, PLA is inherently brittle with low impact strength. The goal of this study is to improve mechanical properties of PLA by the addition of calcium carbonate (CaCO3) fillers. PLA composites were prepared by injection molding conventional limestone (LS) and white chicken eggshell (WES) powders with particle sizes of 63 μm and 32 μm in amounts of 5 wt. %, 10 wt. % and 20 wt. %. Mechanical properties such as, tensile strength, tensile modulus, and Charpy impact strengths were investigated. These three properties were evaluated and the results statistically analyzed using ANOVA F-test. For both particle sizes, the tensile strength decreased as the filler content increased, but was highest for a filler loading of 5 wt. %. In general, the 32 μm powder fillers had better tensile strengths than 63 μm sized fillers. The tensile modulus increased with filler content and was highest at 20 wt. % for both particle sizes. The LS/PLA composites had better toughness than the WES/PLA composites. The particle filler morphology and fractured surfaces were observed by scanning electron microscopy (SEM) and determined to have well dispersed particles with smooth fractured surfaces. Water absorption behavior of PLA/CaCO3 composites were studied by immersion in distilled water at room temperature for 56 days. Virgin PLA absorbed the least amount of water while the water absorption of CaCO3 composites were a function of powder type and content.

Effect of Polyethylene Glycol in Nanocellulose/PLA Composites

2019 ◽  
Vol 821 ◽  
pp. 89-95
Author(s):  
Wanasorn Somphol ◽  
Thipjak Na Lampang ◽  
Paweena Prapainainar ◽  
Pongdhorn Sae-Oui ◽  
Surapich Loykulnant ◽  
...  
Keyword(s):  
Tensile Strength ◽  
Lactic Acid ◽  
Polyethylene Glycol ◽  
Aspect Ratio ◽  
Mechanical Performance ◽  
Tensile Modulus ◽  
Poly Lactic Acid ◽  
Solvent Casting ◽  
Casting Method ◽  
Mediated Oxidation

Poly (lactic acid) or PLA was reinforced by nanocellulose and polyethylene glycol (PEG), which were introduced into PLA matrix from 0 to 3 wt.% to enhance compatibility and strength of the PLA. The nanocellulose was prepared by TEMPO-mediated oxidation from microcrystalline cellulose (MCC) powder and characterized by TEM, AFM, and XRD to reveal rod-like shaped nanocellulose with nanosized dimensions, high aspect ratio and high crystallinity. Films of nanocellulose/PEG/PLA nanocomposites were prepared by solvent casting method to evaluate the mechanical performance. It was found that the addition of PEG in nanocellulose-containing PLA films resulted in an increase in tensile modulus with only 1 wt% of PEG, where higher PEG concentrations negatively impacted the tensile strength. Furthermore, the tensile strength and modulus of nanocellulose/PEG/PLA nanocomposites were higher than the PLA/PEG composites due to the existence of nanocellulose chains. Visual traces of crazing were detailed to describe the deformation mechanism.

Mechanical, Thermal, and Morphological Properties of Thermoplastic Starch/Poly(lactic acid/Poly(butylene adipate-co-terephthalate) Blends

2014 ◽  
Vol 970 ◽  
pp. 312-316
Author(s):  
Sujaree Tachaphiboonsap ◽  
Kasama Jarukumjorn
Keyword(s):  
Lactic Acid ◽  
Impact Strength ◽  
Interfacial Adhesion ◽  
Tensile Modulus ◽  
Thermoplastic Starch ◽  
Morphological Properties ◽  
Poly Lactic Acid ◽  
Melt Blending ◽  
Elongation At Break ◽  
Blending Method

Thermoplastic starch (TPS)/poly (lactic acid) (PLA) blend and thermoplastic starch (TPS)/poly (lactic acid) (PLA)/poly (butylene adipate-co-terephthalate) (PBAT) blend were prepared by melt blending method. PLA grafted with maleic anhydride (PLA-g-MA) was used as a compatibilizer to improve the compatibility of the blends. As TPS was incorporated into PLA, elongation at break was increased while tensile strength, tensile modulus, and impact strength were decreased. Tensile properties and impact properties of TPS/PLA blend were improved with adding PLA-g-MA indicating the enhancement of interfacial adhesion between PLA and TPS. With increasing PBAT content, elongation at break and impact strength of TPS/PLA blends were improved. The addition of TPS decreased glass transition temperature (Tg), crystallization temperature (Tc), and melting temperature (Tm) of PLA. Tgand Tcof TPS/PLA blend were decreased by incorporating PLA-g-MA. However, the presence of PBAT reduced Tcof TPS/PLA blend. Thermal properties of TPS/PLA/PBAT blends did not change with increasing PBAT content. SEM micrographs revealed that the compatibilized TPS/PLA blends exhibited finer morphology when compared to the uncompatibilized TPS/PLA blend.

Tensile and water absorption properties of solvent cast biofilms of sugarcane leaves fibre-filled poly(lactic) acid

2018 ◽  
Vol 33 (3) ◽  
pp. 289-304 ◽  
Author(s):  
Kuhananthan Nanthakumar ◽  
Chan Ming Yeng ◽  
Koay Seong Chun
Keyword(s):  
Tensile Strength ◽  
Lactic Acid ◽  
Water Absorption ◽  
Young’S Modulus ◽  
Young's Modulus ◽  
Poly Lactic Acid ◽  
Infrared Analysis ◽  
Absorption Properties ◽  
Elongation At Break ◽  
Bleaching Treatment

This research covers the preparation of poly(lactic acid) (PLA)/sugarcane leaves fibre (SLF) biofilms via a solvent-casting method. The results showed that the tensile strength and Young’s modulus of PLA/SLF biofilms increased with the increasing of SLF content. Nevertheless, the elongation at break showed an opposite trend as compared to tensile strength and Young’s modulus of biofilms. Moreover, water absorption properties of PLA/SLF biofilms increased with the increasing of SLF content. In contrast, the tensile strength and Young’s modulus of biofilms were enhanced after bleaching treatment with hydrogen peroxide on SLF, but the elongation at break and water absorption properties of bleached biofilms were reduced due to the improvement of filler–matrix adhesion in biofilms. The tensile and water properties were further discussed using B-factor and Fick’s law, respectively. Furthermore, the functional groups of unbleached and bleached SLF were characterized by Fourier transform infrared analysis.

Studies on the Mechanical Properties of Foam CB-PVC Composite

2013 ◽  
Vol 681 ◽  
pp. 256-259
Author(s):  
Xiu Qi Liu ◽  
He Qin Xing ◽  
Li Li Zhao ◽  
Dan Wang
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Mechanical Index ◽  
Melt Blending ◽  
Elongation At Break ◽  
Foam Composite ◽  
The Matrix ◽  
System Prototype ◽  
Made In

In our study, a new kind of foam composite was prepared by melt blending with PVC as the matrix and carbon black (CB) as the filler, the standard-spline was made in the dumbbell system prototype. Tensile strength and elongation at break were measured at 25°C。When the CB was added greater than 2.0%, with the increase of CB added, the determination of sample mechanical index began to decline, when the CB content was greater than 9%, tensile strength and elongation at break of the composites remained basically unchanged.

Effects of walnut shell powders on the morphology and the thermal and mechanical properties of poly(lactic acid)

2019 ◽  
Vol 33 (10) ◽  
pp. 1383-1395
Author(s):  
Hongjuan Zheng ◽  
Zhengqian Sun ◽  
Hongjuan Zhang
Keyword(s):  
Mechanical Properties ◽  
Lactic Acid ◽  
Property Testing ◽  
Walnut Shell ◽  
Poly Lactic Acid ◽  
Thermal And Mechanical Properties ◽  
Scanning Calorimetry ◽  
Elongation At Break ◽  
Heat Distortion Temperature ◽  
Testing Techniques

Poly(lactic acid) (PLA) has good environmental compatibility, however, its high brittleness, slow rate of crystallization, and low heat distortion temperature restrict its widespread use. To overcome these limitations, in this study, PLA was mixed with walnut shell (WS) powders. The effects of WS powders on the morphology and the thermal and mechanical properties of PLA were investigated. The products were characterized by differential scanning calorimetry (DSC), infrared (IR) spectroscopy, polarizing optical microscopy (POM), and various mechanical property testing techniques. The results showed that WS powders had a significant effect on the morphology and the thermal and mechanical properties of PLA. The tensile strength, impact strength, and elongation at break of the PLA/WS composites first increased and then decreased with the increasing addition of WS powders. When the addition of WS powders was about 0.5 wt%, they reached maximum values of 51.2 MPa, 23.3 MPa, and 19.0%, respectively. Compared with neat PLA, the spherulite grain size of the composites could be reduced and many irregular polygons were formed during crystallization. The melting, cold crystallization, and glass-transition temperatures of the composites were lower than those of neat PLA.

Mechanical Properties of P34HB/PLA Binary Blendsafter Thermal-Oxidative and Hydrothermal Aging

2013 ◽  
Vol 647 ◽  
pp. 798-801 ◽  
Author(s):  
Wen Can Xi ◽  
Hong Mei Kang ◽  
Hua Li ◽  
He Zhou Liu ◽  
Wei Jie Wang ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Lactic Acid ◽  
Mechanical Behavior ◽  
Poly Lactic Acid ◽  
Hydrothermal Aging ◽  
Weight Percentage ◽  
Lower Ratio

Binary blendscomposed of polyhrdroxyalkanoates (P34HB) and poly(lactic acid) (PLA) with various P34HB weight percentage were preparedby extrusion and compressing molding.Both the thermo-oxidative agingat 80°Cand the hydrothermal aging at 80°C with 80% humidity were performed for 300 h for the P34HB/PLA blends respectively.The mechanical properties of tensile strength and elongation-at-breakrevealed that P34HB/PLA blends possessedthe balanced mechanical properties between P34HB and PLA,theblends with higher ratio of P34HBshowed thedeteriorative mechanical behavior in the aging environment faster than thoseblends with lower ratio of P34HB.

Effects of Graphene Nanopletelets on Poly(Lactic Acid)/Poly(Ethylene Glycol) Polymer Nanocomposites

2014 ◽  
Vol 1024 ◽  
pp. 136-139 ◽  
Author(s):  
Buong Woei Chieng ◽  
Ibrahim Nor Azowa ◽  
Wan Yunus Wan Md Zin ◽  
Mohd Zobir Hussein
Keyword(s):  
Lactic Acid ◽  
Ethylene Glycol ◽  
Tensile Properties ◽  
Tensile Modulus ◽  
Poly Lactic Acid ◽  
Poly Ethylene Glycol ◽  
Elongation At Break ◽  
Sem Image ◽  
Blending Method ◽  
Poly Ethylene

Graphene nanoplatelets (xGnP) were investigated as a novel nanoreinforcement filler in poly (lactic acid)(PLA)/poly (ethylene glycol)(PEG) blends by melt blending method. The prepared nanocomposites exhibited a significant improvement in tensile properties at a low xGnP loading. The tensile properties demonstrated the addition of 0.3wt% of xGnP led to an increase of up to 32.7%, 69.5% and 21.9% in tensile strength, tensile modulus and elongation at break of the nanocomposites respectively, compared to PLA/PEG blend. The nanocomposites also shows enhanced thermal stability compared with PLA/PEG blend in thermogravimetry analysis (TGA). Scanning electron microscopy (SEM) image of PLA/PEG/0.3wt% xGnP displays good uniformity and more homogenous morphology.

Sign in / Sign up

Export Citation Format

Share Document