Abstract
This paper examines the controls on global precipitation that are evident in the transient experiments conducted using coupled climate models collected for the Intergovernmental Panel on Climate Change (IPCC) Fourth Assessment Report (AR4). The change in precipitation, water vapor, clouds, and radiative heating of the atmosphere evident in the 1% increase in carbon dioxide until doubled (1pctto2x) scenario is examined. As noted in other studies, the ensemble-mean changes in water vapor as carbon dioxide is doubled occur at a rate similar to that predicted by the Clausius–Clapeyron relationship. The ratio of global changes in precipitation to global changes in water vapor offers some insight on how readily increased water vapor is converted into precipitation in modeled climate change. This ratio ɛ is introduced in this paper as a gross indicator of the global precipitation efficiency under global warming.
The main findings of this paper are threefold. First, increases in the global precipitation track increase atmospheric radiative energy loss and the ratio of precipitation sensitivity to water vapor sensitivity is primarily determined by changes to this atmospheric column energy loss. A reference limit to this ratio is introduced as the rate at which the emission of radiation from the clear-sky atmosphere increases as water vapor increases. It is shown that the derived efficiency based on the simple ratio of precipitation to water vapor sensitivities of models in fact closely matches the sensitivity derived from simple energy balance arguments involving changes to water vapor emission alone. Second, although the rate of increase of clear-sky emission is the dominant factor in the change to the energy balance of the atmosphere, there are two important and offsetting processes that contribute to ɛ in the model simulations studied: One involves a negative feedback through cloud radiative heating that acts to reduce the efficiency; the other is the global reduction in sensible heating that counteracts the effects of the cloud feedback and increases the efficiency. These counteracting feedbacks only apply on the global scale. Third, the negative cloud radiative heating feedback occurs through reductions of cloud amount in the middle troposphere, defined as the layer between 680 and 440 hPa, and by slight global cloud decreases in the lower troposphere. These changes act in a manner to expose the warmer atmosphere below to high clouds, thus resulting in a net warming of the atmospheric column by clouds and a negative feedback on the precipitation.
Characterization of Alkanolamine Blends for Carbon Dioxide Absorption. Corrosion and Regeneration Studies
