Modification of Irind Mine Pumice Surface

2022 ◽  
Vol 906 ◽  
pp. 25-29
Author(s):  
Marine Kalantaryan ◽  
Nikolay Chilingaryan ◽  
Armine Meymaryan

In the last decade, a continuous increasing research activity is focused on the surface modification of natural porous materials for the efficient removal of oil contaminants from water. A continuous in-situ oil/water separation technique for oil spill cleanup had been designed using surface modified Irind mine pumice as a sorbent. Irind mine pumice is an aluminosilicate rock, with well-developed porosity, mechanical strength, high buoyancy, chemically inert and eco-friendly, therefore it must exhibit certain water-and oil absorption capacities. The modified pumice absorbs a broad variety of oils and organic solvents with high oil absorption capacity and negligible water take-up at both static and dynamic conditions. Irind mine pumice have been used with grain sizes ranging from 2.5 ... 5.0 mm. Oligomethylhydride siloxane is used as a modifier.

Polymers ◽  
2019 ◽  
Vol 11 (1) ◽  
pp. 97 ◽  
Author(s):  
Yu-Ping Zhang ◽  
Jing-Hua Yang ◽  
Ling-Li Li ◽  
Cheng-Xing Cui ◽  
Ying Li ◽  
...  

Membrane-based metal substrates with special surface wettability have been applied widely for oil/water separation. In this work, a series of copper foams with superhydrophobicity and superoleophilicity were chemically etched using 10 mg mL−1 FeCl3/HCl solution with consequent ultrasonication, followed by the subsequent modification of four sulfhydryl compounds. A water contact angle of 158° and a sliding angle lower than 5° were achieved for the copper foam modified using 10 mM n-octadecanethiol solution in ethanol. In addition, the interaction mechanism was initially investigated, indicating the coordination between copper atoms with vacant orbital and sulfur atoms with lone pair electrons. In addition, the polymeric fibers were electrospun through the dissolution of polystyrene in a good solvent of chlorobenzene, and a nonsolvent of dimethyl sulfoxide. Oil absorption and collection over the water surface were carried out by the miniature boat made out of copper foam, a string bag of as-spun PS fibers with high oil absorption capacity, or the porous boat embedded with the as-spun fibers, respectively. The findings might provide a simple and practical combinational method for the solution of oil spill.


Materials ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2431
Author(s):  
Wen Zhang ◽  
Juanjuan Wang ◽  
Xue Han ◽  
Lele Li ◽  
Enping Liu ◽  
...  

In this paper, effective separation of oil from both immiscible oil–water mixtures and oil-in-water (O/W) emulsions are achieved by using poly(dimethylsiloxane)-based (PDMS-based) composite sponges. A modified hard template method using citric acid monohydrate as the hard template and dissolving it in ethanol is proposed to prepare PDMS sponge composited with carbon nanotubes (CNTs) both in the matrix and the surface. The introduction of CNTs endows the composite sponge with enhanced comprehensive properties including hydrophobicity, absorption capacity, and mechanical strength than the pure PDMS. We demonstrate the successful application of CNT-PDMS composite in efficient removal of oil from immiscible oil–water mixtures within not only a bath absorption, but also continuous separation for both static and turbulent flow conditions. This notable characteristic of the CNT-PDMS sponge enables it as a potential candidate for large-scale industrial oil–water separation. Furthermore, a polydopamine (PDA) modified CNT-PDMS is developed here, which firstly realizes the separation of O/W emulsion without continuous squeezing of the sponge. The combined superhydrophilic and superoleophilic property of PDA/CNT-PDMS is assumed to be critical in the spontaneously demulsification process.


Polymers ◽  
2019 ◽  
Vol 11 (10) ◽  
pp. 1593 ◽  
Author(s):  
Hajo Yagoub ◽  
Liping Zhu ◽  
Mahmoud H. M. A. Shibraen ◽  
Ali A. Altam ◽  
Dafaalla M. D. Babiker ◽  
...  

The complex aerogel generated from nano-polysaccharides, chitin nanocrystals (ChiNC) and TEMPO-oxidized cellulose nanofibers (TCNF), and its derivative cationic guar gum (CGG) is successfully prepared via a facile freeze-drying method with glutaraldehyde (GA) as cross-linkers. The complexation of ChiNC, TCNF, and CGG is shown to be helpful in creating a porous structure in the three-dimensional aerogel, which creates within the aerogel with large pore volume and excellent compressive properties. The ChiNC/TCNF/CGG aerogel is then modified with methyltrichlorosilane (MTCS) to obtain superhydrophobicity/superoleophilicity and used for oil–water separation. The successful modification is demonstrated through FTIR, XPS, and surface wettability studies. A water contact angle of 155° on the aerogel surface and 150° on the surface of the inside part of aerogel are obtained for the MTCS-modified ChiNC/TCNF/CGG aerogel, resulting in its effective absorption of corn oil and organic solvents (toluene, n-hexane, and trichloromethane) from both beneath and at the surface of water with excellent absorption capacity (i.e., 21.9 g/g for trichloromethane). More importantly, the modified aerogel can be used to continuously separate oil from water with the assistance of a vacuum setup and maintains a high absorption capacity after being used for 10 cycles. The as-prepared superhydrophobic/superoleophilic ChiNC/TCNF/CGG aerogel can be used as a promising absorbent material for the removal of oil from aqueous media.


2021 ◽  
Author(s):  
Cailin Liu ◽  
Li Yu ◽  
Yue Fan ◽  
Chang Li ◽  
Xianyan Ren ◽  
...  

Abstract In the oil-water separation, the difficulty to recover and low hydrophobicity are key limitation factors for practical applications. In this paper, we design Cobalt ferrite hybird Polystyrene divinylbenzene microspheres (CoFe2O4/SDB), which were conducted through in-situ suspension copolymerization. The CoFe2O4 is prepared by low heat solid phase sol-gel method. It had been found that the CoFe2O4/SDB have a spherical structure, good adsorption behavior, highly hydrophobicity and even superhydrophobicity. The adsorption capacity of CoFe2O4/SDB composites could absorb kerosene up to 6 times of its own weight. Interestingly, kerosene can be easily separated from the surface of CoFe2O4/SDB particles with ultrasonic operation. CoFe2O4/SDB particles can still maintain good hydrophobicity and adsorption capacity of kerosene after 11 cycles after drying. With in situ polymerization of St、DVB and CoFe2O4, CoFe2O4/SDB as a promising absorbent of kerosene which has great potential in application of oil-water separation.


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