Technological Features of the Liquid-Solid State of the Boundary Layer in the Processes of Bimetallic Products

2022 ◽  
Vol 1049 ◽  
pp. 53-61
Author(s):  
Valeriy Lykhoshva ◽  
Dmitry Glushkov ◽  
Elena Reintal ◽  
Valeriy V. Savin ◽  
Ludmila Alexeyevna Savina ◽  
...  
Keyword(s):  
Mathematical Modeling ◽  
Experimental Data ◽  
Boundary Layer ◽  
Solid State ◽  
Liquid Phase ◽  
Contact Zone ◽  
Thermal Field ◽  
Thermal State ◽  
Existence Time ◽  
Modeling Data

The hydrodynamic and thermal state in the contact zone of the layers of a bimetallic product obtained by pouring liquid iron onto a solid steel billet, which changes in time and is responsible for the strength of the diffusion joint and the geometric parameters of the transition layer, has been investigated. Simplified analytical dependences, mathematical modeling data and experimental results of the liquid phase existence time in the contact zone based on research of the melt velocities during pouring and changes in the thermal field are presented. It is shown that simplified calculations data coincide in order and are close in values ​​to the calculations of mathematical modeling and experimental data, which makes it possible to use them for preliminary rough estimates by technologists and metallurgists.

Data Mining and Optimize TCM Prescription Compatibility Based on WDS-PLS

2014 ◽  
Vol 687-691 ◽  
pp. 1385-1388
Author(s):  
Zhuo Wang ◽  
Bin Nie ◽  
Ri Yue Yu
Keyword(s):  
Mathematical Modeling ◽  
Experimental Data ◽  
Data Mining ◽  
Regression Coefficient ◽  
Uniform Design ◽  
Herbal Medicines ◽  
Data Standardization ◽  
Modeling Data ◽  
Pls Method ◽  
Original Formula

Data mining and optimize traditional Chinese medicine (TCM) prescription compatibility based on wavelet denoise spectral and partial least squares (WDS-PLS). Method: First of all, experimental design: with reference to the original formula, the herbal medicines in a prescription designed nine formula based on mixing uniform design; Secondly, obtain experimental data and data standardization; Finally, mathematical modeling, data mining and optimize TCM prescription compatibility base on WDS-PLS.Results: gain the regression coefficient and equation, VIP sorting, loadings Bi plot, and seek out the optimized direction of the prescription. Conclusion: the method data mining and optimize the compatibility of the dachengqi decoction is feasible and effective.

Theoretical analysis of counter-current absorption of a poorly soluble gas based on the PDE-AD model

1986 ◽  
Vol 51 (6) ◽  
pp. 1222-1239 ◽  
Author(s):  
Pavel Moravec ◽  
Vladimír Staněk
Keyword(s):  
Experimental Data ◽  
Liquid Phase ◽  
Gas Phase ◽  
Transfer Functions ◽  
Packed Bed ◽  
Packed Bed Column ◽  
Interfacial Transport ◽  
Gaseous Component ◽  
Poorly Soluble ◽  
Counter Current

Expression have been derived in the paper for all four possible transfer functions between the inlet and the outlet gas and liquid steams under the counter-current absorption of a poorly soluble gas in a packed bed column. The transfer functions have been derived for the axially dispersed model with stagnant zone in the liquid phase and the axially dispersed model for the gas phase with interfacial transport of a gaseous component (PDE - AD). calculations with practical values of parameters suggest that only two of these transfer functions are applicable for experimental data evaluation.

Effect of ionizing radiation on the kinetics of hydrogenation on the Ni-MgO mixed catalyst

1982 ◽  
Vol 47 (7) ◽  
pp. 1780-1786 ◽  
Author(s):  
Rostislav Kudláček ◽  
Jan Lokoč
Keyword(s):  
Experimental Data ◽  
Activation Energy ◽  
Liquid Phase ◽  
Ionizing Radiation ◽  
Oxide Catalyst ◽  
Absorbed Dose ◽  
Hydrogenation Rate ◽  
Solution Composition ◽  
Mixed Catalyst ◽  
Kinetics Of

The effect of gamma pre-irradiation of the mixed nickel-magnesium oxide catalyst on the kinetics of hydrogenation of maleic acid in the liquid phase has been studied. The changes of the hydrogenation rate are compared with the changes of the adsorbed amount of the acid and with the changes of the solution composition, activation energy, and absorbed dose of the ionizing radiation. From this comparison and from the interpretation of the experimental data it can be deduced that two types of centers can be distinguished on the surface of the catalyst under study, namely the sorption centres for the acid and hydrogen and the reaction centres.

scholarly journals Synthesis and Na+ Ion Conductivity of Stoichiometric Na3Zr2Si2PO12 by Liquid-Phase Sintering with NaPO3 Glass

Materials ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 3790
Author(s):  
Yongzheng Ji ◽  
Tsuyoshi Honma ◽  
Takayuki Komatsu
Keyword(s):  
Solid State ◽  
Liquid Phase ◽  
Sintering Temperature ◽  
Liquid Phase Sintering ◽  
Ion Conductivity ◽  
X Ray Diffraction ◽  
Conventional Solid State Reaction ◽  
X Ray ◽  
Sintering Time ◽  
Lower Activation

Sodium super ionic conductor (NASICON)-type Na3Zr2Si2PO12 (NZSP) with the advantages of the high ionic conductivity, stability and safety is one of the most famous solid-state electrolytes. NZSP, however, requires the high sintering temperature about 1200 °C and long sintering time in the conventional solid-state reaction (SSR) method. In this study, the liquid-phase sintering (LPS) method was applied to synthesize NZSP with the use of NaPO3 glass with a low glass transition temperature of 292 °C. The formation of NZSP was confirmed by X-ray diffraction analyses in the samples obtained by the LPS method for the mixture of Na2ZrSi2O7, ZrO2, and NaPO3 glass. The sample sintered at 1000 °C for 10 h exhibited a higher Na+ ion conductivity of 1.81 mS/cm at 100 °C and a lower activation energy of 0.18 eV compared with the samples prepared by the SSR method. It is proposed that a new LPE method is effective for the synthesis of NZSP and the NaPO3 glass has a great contribution to the Na+ diffusion at the grain boundaries.

Separation of phenylenediamine isomers by using decamethylcucurbit[5]uril

2021 ◽  
Author(s):  
Long Cao ◽  
Han-Ling Guo ◽  
Rui Lian Lin ◽  
Li-Fei Tian ◽  
Zhi-Hua Zhang ◽  
...  
Keyword(s):  
Experimental Data ◽  
Aqueous Solution ◽  
Solid State ◽  
Phenylenediamine Isomers

Using multiple techniques, this work studied the binding behaviors of decamethylcucurbit[5]uril (Me10Q[5]) with o-, m- and p-phenylenediamine (PDA) isomers both in solid state and in aqueous solution. Experimental data indicate...

scholarly journals Preparation of Li3PS4–Li3PO4 Solid Electrolytes by Liquid-Phase Shaking for All-Solid-State Batteries

2021 ◽  
Vol 2 (1) ◽  
pp. 39-48
Author(s):  
Nguyen H. H. Phuc ◽  
Takaki Maeda ◽  
Tokoharu Yamamoto ◽  
Hiroyuki Muto ◽  
Atsunori Matsuda
Keyword(s):  
Solid Solution ◽  
Solid State ◽  
Liquid Phase ◽  
Room Temperature ◽  
Reaction Medium ◽  
Magic Angle Spinning ◽  
Resonance Spectroscopy ◽  
Synthesis Methods ◽  
Magic Angle ◽  
Angle Spinning

A solid solution of a 100Li3PS4·xLi3PO4 solid electrolyte was easily prepared by liquid-phase synthesis. Instead of the conventional solid-state synthesis methods, ethyl propionate was used as the reaction medium. The initial stage of the reaction among Li2S, P2S5 and Li3PO4 was proved by ultraviolet-visible spectroscopy. The powder X-ray diffraction (XRD) results showed that the solid solution was formed up to x = 6. At x = 20, XRD peaks of Li3PO4 were detected in the prepared sample after heat treatment at 170 °C. However, the samples obtained at room temperature showed no evidence of Li3PO4 remaining for x = 20. Solid phosphorus-31 magic angle spinning nuclear magnetic resonance spectroscopy results proved the formation of a POS33− unit in the sample with x = 6. Improvements of ionic conductivity at room temperature and activation energy were obtained with the formation of the solid solution. The sample with x = 6 exhibited a better stability against Li metal than that with x = 0. The all-solid-state half-cell employing the sample with x = 6 at the positive electrode exhibited a better charge–discharge capacity than that employing the sample with x = 0.

scholarly journals Effect of Surfactants on Gas Holdup in Shear-Thinning Fluids

2017 ◽  
Vol 2017 ◽  
pp. 1-7 ◽  
Author(s):  
Shaobai Li ◽  
Siyuan Huang ◽  
Jungeng Fan
Keyword(s):  
Experimental Data ◽  
Liquid Phase ◽  
Sodium Dodecyl ◽  
Shear Thinning ◽  
Gas Holdup ◽  
Bubble Columns ◽  
Gas Velocity ◽  
Shear Thinning Fluids ◽  
Liquid Surface Tension ◽  
Superficial Gas Velocity

In this study, the gas holdup of bubble swarms in shear-thinning fluids was experimentally studied at superficial gas velocities ranging from 0.001 to 0.02 m·s−1. Carboxylmethyl cellulose (CMC) solutions of 0.2 wt%, 0.6 wt%, and 1.0 wt% with sodium dodecyl sulfate (SDS) as the surfactant were used as the power-law (liquid phase), and nitrogen was used as the gas phase. Effects of SDS concentration, rheological behavior, and physical properties of the liquid phase and superficial gas velocity on gas holdup were investigated. Results indicated that gas holdup increases with increasing superficial gas velocity and decreasing CMC concentration. Moreover, the addition of SDS in CMC solutions increased gas holdup, and the degree increased with the surfactant concentration. An empirical correlation was proposed for evaluating gas holdup as a function of liquid surface tension, density, effective viscosity, rheological property, superficial gas velocity, and geometric characteristics of bubble columns using the experimental data obtained for the different superficial gas velocities and CMC solution concentrations with different surfactant solutions. These proposed correlations reasonably fitted the experimental data obtained for gas holdup in this system.

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