Effects of Heat Treatment and Alloying of Spheroidal Graphite Cast Iron on Corrosion Resistance in Aqueous Environment

2004 ◽  
Vol 449-452 ◽  
pp. 533-536
Author(s):  
M. Aoyama ◽  
K. Tahashi ◽  
K. Matsuno

The present study examined the effects of heat treatment and the addition of Cu-Ni alloy on the corrosion resistance of the matrix of spheroidal graphite cast iron in aqueous environments. Test materials of white cast iron and carbon steel were used for comparison with spheroidal graphite cast iron. The alloy spheroidal graphite cast iron that added Cu and Ni was prepared. The spheroidal graphite cast iron was subjected to three kinds of heat treatment to adjust the matrix: annealing, oil quenching, and austemper heat treatment. In electrochemical tests, measurements of corrosion electrode potential and cathode and anode polarization were used. The following was clarified from the relationship between the electrode potential and current density of each of the materials in each of the solution. The alloy spheroidal graphite cast iron had a high corrosion electrode potential owing to the addition of Cu-Ni, and tended to have a low corrosion current density. This demonstrates that in any of the materials having a matrix adjusted by heat treatment, the addition of Cu-Ni increased the corrosion resistance. The corrosion current density was highest in a sulfuric acid environment.

2004 ◽  
Vol 449-452 ◽  
pp. 529-532 ◽  
Author(s):  
Minoru Doi ◽  
Daisuke Sakai ◽  
Toshiyuki Koyama ◽  
Takao Kozakai ◽  
Tomokazu Moritani

The present study examined the effects of heat treatment and the addition of Cu-Ni alloy on the corrosion resistance of the matrix of spheroidal graphite cast iron in aqueous environments. Test materials of white cast iron and carbon steel were used for comparison with spheroidal graphite cast iron. The alloy spheroidal graphite cast iron that added Cu and Ni was prepared. The spheroidal graphite cast iron was subjected to three kinds of heat treatment to adjust the matrix: annealing, oil quenching, and austemper heat treatment. In electrochemical tests, measurements of corrosion electrode potential and cathode and anode polarization were used. The following was clarified from the relationship between the electrode potential and current density of each of the materials in each of the solution. The alloy spheroidal graphite cast iron had a high corrosion electrode potential owing to the addition of Cu-Ni, and tended to have a low corrosion current density. This demonstrates that in any of the materials having a matrix adjusted by heat treatment, the addition of Cu-Ni increased the corrosion resistance. The corrosion current density was highest in a sulfuric acid environment.


2007 ◽  
Vol 561-565 ◽  
pp. 1123-1126
Author(s):  
Akikazu Matsumoto ◽  
Naoyuki Kanetake

The spheroidal graphite cast iron is widely used as a structural material in an industrial field. Possibility to be able to use by improving magnetic characteristic of spheroidal graphite as magnetic circuit material of product related to electromagnetism besides structure material. In this study, the influence that the amount of graphite precipitation , the matrix organization, and the structure gave to a magnetic characteristic was investigated in the spheroidal graphite cast iron that makes matrix ferrite by compounding C element and the Si element and heat-treatment. The graphite was completely precipitated at the heat-treatment temperature of 1173K or more, the organizatiom became a ferrite, and permeability rose. Moreover, Rough making by heat-treatment the size about the particle size of the ferrite and the appearance of the Fe-Si phase have raised permeability.


2018 ◽  
Vol 941 ◽  
pp. 558-561
Author(s):  
Tatsuo Inoue ◽  
Shiro Torizuka

It is well known that austempered spheroidal graphite cast iron shows good tensile and elongation. And, retained austenite include in the austempered spheroidal graphite cast iron structure was known to effect for the mechanical properties when TRIP was occurred. On the other hand, fineness and homogeneity of the structure are considered to influence as a factor to improve mechanical property. In this study, the mechanical properties of spherical graphite cast iron was evaluated that it treatmented fineness prior-structure and austenitized at (α + γ) range followed by isothermal treatment at bainitic transformation temperature range. Compared the heat treatment of this study and typical austempering treatment, the mechanical properties with good balance of strength and ductility were obtained in the heat treatment of this study. But, retained austenite that it determined by x-ray diffraction was slightly changed before and after the tensile test. Therfore, it was considered that not TRIP but complex phase effect on mechanical properties.


Metals ◽  
2019 ◽  
Vol 9 (4) ◽  
pp. 450 ◽  
Author(s):  
Yu Zhang ◽  
Yongzhe Fan ◽  
Xue Zhao ◽  
An Du ◽  
Ruina Ma ◽  
...  

The influence of graphite morphology on the phase, microstructure and properties of hot dipping and diffusion aluminizing (HDDA) coating on flake/spheroidal graphite cast iron (FC/FCD) was investigated. The microstructure and properties of the HDDA coatings on FC/FCD were determined by the graphite morphology. The outer and inner layers of the HDDA coating comprised the Fe2Al5 and FeAl phases, respectively. The outer layer of HDDA on FCD was dense and uniform; however, some pores of different sizes were found in the outer coating on FC, resulting in looser HDDA coating. Hence, the wear resistance of the HDDA coating on FC was worse than that of the coating on FCD. During oxidation, many continuous oxidation channels were formed from the coating surface to the matrix in the HDDA coating on FC, resulting in the oxidation of graphite in the HDDA coating and the matrix. However, only exposed spheroidal graphite was oxidized in the HDDA coating on FCD. Thus, the high-temperature oxidation resistance of the HDDA coating on FC was also worse than that of the coating on FCD.


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