High Temperature Oxidation of TiAl(La)N Coating Deposited on a Steel Substrate by Arc-Ion Plating

2006 ◽  
Vol 510-511 ◽  
pp. 410-413
Author(s):  
Y.A. Shapovalov ◽  
Dong Bok Lee

The high temperature oxidation behavior of the TiAl(La)N coating, which was deposited on a steel substrate by the arc-ion plating method, was investigated at 700, 800 and 900oC in atmospheric air. The oxidation kinetics of the coating were mainly governed by the inward diffusion of oxygen and outward transport of nitrogen. The oxide scale was porous, nonadherent, and prone to cracking, indicating the oxidation resistance above 700oC is poor.

2010 ◽  
Vol 97-101 ◽  
pp. 1479-1483
Author(s):  
Yan Cai ◽  
Chun Hu Tao ◽  
Feng Lu ◽  
Jian Ping Li

Gradient Zr/ZrN/Zr layer was deposited as a diffusion barrier between the NiCrAlYSi The overlay coating and Ni-base superalloy DZ125 by arc ion plating(AIP). The microstructure and high-temperature oxidation behavior of the diffusion barrier were studied. The results show that the gradient diffusion barrier is homogeneous and compact, and has strong bond strength with the substrate. The diffusion barrier is composed of three layers, among which the inner and outer layers are rich in Zr, and the middle layer is rich in ZrN. The main phase structure of the diffusion barrier is ZrN(200). During high temperature oxidation at 1100°C, the Zr/ZrN/Zr/HY3 compound coating system presents excellent oxidation resistance.


2020 ◽  
Vol 20 (7) ◽  
pp. 4394-4397
Author(s):  
Wang Ryeol Kim ◽  
Sungbo Heo ◽  
Hyundong Kim ◽  
Jun-Ho Kim ◽  
In-Wook Park ◽  
...  

High temperature oxidation behavior of nanocomposite films is very important characteristics for application of machining and cutting tools. Quaternary Cr–Al–Si–N nanocomposite films with various compositions were deposited onto WC-Co and Si wafer substrates using a filtered arc ion plating technique. The composition of the films were controlled by different combinations of CrAl2 and Cr4Si composite target power in a reactive gas mixture of high purity Ar and N2 during depositions. The instrumental analyses revealed that the synthesized Cr–Al–Si–N films with Si content of 2.78 at.% were nanocomposites consisting of nano-sized crystallites (3–7 nm in dia.) and a thin layer of amorphous Si3N4 phases. The nanohardness of the Cr–Al–Si–N films exhibited the maximum values of ~42 GPa at a Si content of ~2.78 at.% due to the microstructural change to nanocomposite as well as solid-solution hardening. The Cr–Al–Si–N film shows superior result of oxidation resistance at 1050 °C for 30 min in air. Based on the XRD and GDOES analyses on the oxidized films, it could be revealed that the enrichment of Al (17.94 at.%) and Cr (26.24 at.%) elements in the film leads to form an Al2O3 and Cr2O3 layer on the Cr–Al–Si–N film surface. Therefore, in this study, the microstructural changes on the mechanical properties and oxidation behavior with various compositions in the Cr–Al–Si–N nanocomposite films were discussed and correlated with the deposition parameters.


2011 ◽  
Vol 189-193 ◽  
pp. 441-446
Author(s):  
Xiao Xia Tan ◽  
Zong De Liu

NiAl and Ni3Al intermetallic compound claddings are prepared by argon arc cladding technology on the 16Mn steel substrate. These claddings were oxidized for 100 hours at 850 and the oxide quality of each sample was recorded every 10 hours. The results show that the NiAl and Ni3Al claddings have homogeneous structure and few defects, and form excellent metallurgical bonding with the matrix. The oxidation kinetics results show that, the oxidation weight gain rate of NiAl was more stable than Ni3Al and tended to zero earlier. Oxide layer spallation of Ni3Al cladding was more serious than that of NiAl cladding. Thus, NiAl argon arc cladding has the more excellent high temperature oxidation properties than Ni3Al argon arc cladding.


Author(s):  
Xin Zhang ◽  
Zehua Wang ◽  
Jinran Lin

AbstractFeCrBAlMo coating was deposited on an AISI 20 steel substrate by high velocity arc spraying (HVAS). Compared with FeCrBSiMo coating and pristine AISI 20 steel, the microstructure and high temperature oxidation behavior of FeCrBAlMo coating were investigated by optical microscopy, scanning electron microscopy, energy-dispersive spectroscopy and X-ray diffraction. Meanwhile, the bonding strength of the coatings was also measured. The results indicated that both coatings were composed of α(Fe,Cr) and Fe


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