scholarly journals A Review on Synthesis and Characterization of Activated Carbon from Natural Fibers for Supercapacitor Application

2022 ◽  
Vol 30 (1) ◽  
pp. 351-376
Author(s):  
Thilageshwaran Subramaniam ◽  
Mohamed Ansari Mohamed Nainar ◽  
Noor Afeefah Nordin

Supercapacitors have gained much attention in recent years due to their promising characteristics, such as high specific capacitance, high power density, long cycle life, and environment-friendly nature. Usage of natural sources for activated carbon synthesis is a major focus by many researchers worldwide for discovering a replacement of existing supercapacitors. This review summarizes the methods used to synthesize activated carbon (AC) from various natural fiber, their physical and electrochemical characteristics, and the improvement of supercapacitor electrode performance. Previous research studies indicate the practicability of activated carbon derived from various natural fibers with superior electrochemical properties. The effect of activating reagents and temperature on the electrochemical performance for supercapacitor applications are also highlighted in this paper. Since the nature of activated carbon from fibers and its synthesizing methods would result in different properties, the Cyclic Voltammetry (CV) study is also thoroughly discussed on the specific capacitance together with charge/discharge test to observe the capacitance retention after several cycles. Finally, a detailed approach of converting biowaste materials to activated carbon for energy storage applications with environmental concerns is explored.

Author(s):  
Nurul Infaza Talalah Ramli ◽  
Hartini Ahmad Rafaie ◽  
Muhd Firdaus Kasim ◽  
Hanifa Binti Ibno

Objective: An efficient and facile preparation route has been developed to prepare activated carbon (AC)/zinc oxide (ZnO) nanocomposite electrodes for the supercapacitor electrode. Methods: The zinc oxide nanostructure was synthesized via the sol-gel method by using conventional hexamethylenetetramine (HMTA) reagent as the reducing agent. Results: The physicochemical and electrochemical properties of the nanocomposites were characterized by X-ray diffraction analysis (XRD) and cyclic voltammetry (CV) analysis, respectively. 10 wt% of ZnO loading shows an optimum specific capacitance of 398 F/g at a scan rate of 50 mV/s. The optimum sample retained 96% of its initial specific capacitance upon 100 consecutive cycles. Conclusion: The enhanced specific capacitance can be ascribed to the synergistic effect of the individual properties of AC and ZnO.


2014 ◽  
Vol 1678 ◽  
Author(s):  
Shiang Teng ◽  
Ashutosh Tiwari

ABSTRACTThe electrochemical effects of embedding Cu nanoparticles in carbonized wood supercapacitor electrodes have been investigated. The nanoparticles were embedded using a solution method. Subsequent X-ray diffraction (XRD) and scanning electron microscopy (SEM) results showed that the Cu nanoparticles were anchored uniformly on the surface and deep within the pores of the electrode. Cyclic voltammetry measurements showed that the electrode has typical pseudocapacitive behavior, with two pairs of redox reaction peaks. The charge-discharge cycling also indicated that the redox charge transformation was a reversible process. An ultra-high specific capacitance of 888 F/g and an energy density of 123 Wh/kg were observed for the Cu loaded electrodes, as compared to the pure carbonized wood electrodes, which had a specific capacitance of 282 F/g and an energy density of 39 Wh/kg. Furthermore, both the carbonized wood and Cu loaded electrodes exhibited excellent long cycle abilities with at least 95% of the specific capacitance retained after 2000 cycles. These remarkable results demonstrate the potential for using Cu nanoparticle loaded carbonized wood as a high performance and environmentally friendly supercapacitor electrode material.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Taslima Ahmed Tamanna ◽  
Shah Alimuzzaman Belal ◽  
Mohammad Abul Hasan Shibly ◽  
Ayub Nabi Khan

AbstractThis study deals with the determination of new natural fibers extracted from the Corypha taliera fruit (CTF) and its characteristics were reported for the potential alternative of harmful synthetic fiber. The physical, chemical, mechanical, thermal, and morphological characteristics were investigated for CTF fibers. X-ray diffraction and chemical composition characterization ensured a higher amount of cellulose (55.1 wt%) content and crystallinity (62.5%) in the CTF fiber. The FTIR analysis ensured the different functional groups of cellulose, hemicellulose, and lignin present in the fiber. The Scherrer’s equation was used to determine crystallite size 1.45 nm. The mean diameter, specific density, and linear density of the CTF fiber were found (average) 131 μm, 0.86 g/cc, and 43 Tex, respectively. The maximum tensile strength was obtained 53.55 MPa for GL 20 mm and Young’s modulus 572.21 MPa for GL 30 mm. The required energy at break was recorded during the tensile strength experiment from the tensile strength tester and the average values for GL 20 mm and GL 30 mm are 0.05381 J and 0.08968 J, respectively. The thermal analysis ensured the thermal sustainability of CTF fiber up to 230 °C. Entirely the aforementioned outcomes ensured that the new CTF fiber is the expected reinforcement to the fiber-reinforced composite materials.


2016 ◽  
Vol 42 (4) ◽  
pp. 5195-5202 ◽  
Author(s):  
Hongtao Guan ◽  
Wenhui Dang ◽  
Gang Chen ◽  
Chengjun Dong ◽  
Yude Wang

2022 ◽  
Author(s):  
Chong-Huan Wang ◽  
Da-Wei Zhang ◽  
Shude Liu ◽  
Yusuke Yamauchi ◽  
Fei-Bao Zhang ◽  
...  

Herein, we propose a solvent-assisted approach for preparing Ni-MOF microflowers with high specific capacitance and excellent rate capability as an electrode material for supercapacitors. Such high electrochemical performance is attributed...


2016 ◽  
Vol 45 (3) ◽  
pp. 164-171 ◽  
Author(s):  
Linjie Su ◽  
Bohong Li ◽  
Dongyu Zhao ◽  
Chuanli Qin ◽  
Zheng Jin

Purpose The purpose of this paper is to prepare a new modified activated carbon fibers (ACFs) of high specific capacitance used for electrode material of supercapacitor. Design/methodology/approach In this study, the specific capacitance of ACF was significantly increased by using the phenolic resin microspheres and melamine as modifiers to prepare modified PAN-based activated carbon fibers (MACFs) via electrospinning, pre-oxidation and carbonization. The symmetrical supercapacitor (using MACF as electrode) and hybrid supercapacitor (using MACF and activated carbon as electrodes) were tested in term of electrochemical properties by cyclic voltammetry, AC impedance and cycle stability test. Findings It was found that the specific capacitance value of the modified fibers were increased to 167 Fg-1 by adding modifiers (i.e. 20 wt.% microspheres and 15 wt.% melamine) compared to that of unmodified fibers (86.17 Fg-1). Specific capacitance of modified electrode material had little degradation over 10,000 cycles. This result can be attributed to that the modifiers embedded into the fibers changed the original morphology and enhanced the specific surface area of the fibers. Originality/value The modified ACFs in our study had high specific surface area and significantly high specific capacitance, which can be applied as efficient and environmental absorbent, and advanced electrode material of supercapacitor.


2018 ◽  
Vol 281 ◽  
pp. 854-858
Author(s):  
Xi Cheng Gao ◽  
Jian Qiang Bi ◽  
Wei Li Wang ◽  
Guo Xun Sun ◽  
Xu Xia Hao ◽  
...  

NiFe2O4 powders were synthesized by a facile hydrothermal method at 180°C followed by a thermal treatment at 300°C. The phase composition and morphology were analyzed by X-ray diffraction (XRD) and scanning electron microscope (SEM). The results showed that the NiFe2O4 powders were well-crystallized, and they possessed a particle size in the range of 50-100 nm. The electrochemical property was characterized via cyclic voltammetry (CV) and constant current charge-discharge method. Encouragingly, the NiFe2O4 powders had an excellent electrochemical property, whose specific capacitance reached 266.84 F/g at the electric current density of 1 A/g due to the small particle size. Compared with other Fe-based metal compound oxides, NiFe2O4 has a better electrochemical performance, which can be widely used in the supercapacitor electrode materials.


Polymers ◽  
2020 ◽  
Vol 12 (12) ◽  
pp. 2841 ◽  
Author(s):  
Mauricio Torres-Arellano ◽  
Victoria Renteria-Rodríguez ◽  
Edgar Franco-Urquiza

This work deals with the manufacture and mechanical characterization of natural-fiber-reinforced biobased epoxy resins. Biolaminates are attractive to various industries because they are low-density, biodegradable, and lightweight materials. Natural fibers such as Ixtle, Henequen, and Jute were used as reinforcing fabrics for two biobased epoxy resins from Sicomin®. The manufacture of the biolaminates was carried out through the vacuum-assisted resin infusion process. The mechanical characterization revealed the Jute biolaminates present the highest stiffness and strength, whereas the Henequen biolaminates show high strain values. The rigid and semirigid biolaminates obtained in this work could drive new applications targeting industries that require lightweight and low-cost sustainable composites.


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