scholarly journals Study Of The Stability Of Water-In-Oil Emulsion Intended for the Extraction of Heavy Metals Application: Copper Ions

2021 ◽  
Vol 4 (2) ◽  
pp. 62-69
Author(s):  
Saliha Bouranene

This work aims to optimize the parameters that affect the stability of a W/O emulsion to exploit it in the extraction of heavy metals contained in the liquid effluents. The study of the emulsion stability shows that; an emulsification time of 10 minutes, a surfactant concentration of Span80 equal to 3% (w/w), an extractant concentration of Triethylamine N(CH2CH3)3 equal to 5% (w/w), an internal phase concentration of phosphoric acid (H3PO4) of 0.75M, a volume ratio of membrane phase to internal phase of 1, a volume ratio of external phase to the emulsion of 20 and a stirring speed of 180 rpm; lead to the formation of a very stable emulsion with a very low rupture rate of around 1.92% after one hour of contact time. The results of extraction of copper ions revealed that under the best operational conditions, the extraction yield was closed to 93.33% for 20% extractant content, a contact time of 12 minutes, and an initial concentration of copper ions of 400 ppm. The application of this new membrane matrix based on phosphoric acid used as inner phase, sorbitan monooleate as a surfactant, and Triethylamine as extractant has been proven effective for extracting copper ions in water.

2014 ◽  
Vol 67 (2) ◽  
Author(s):  
Norasikin Othman ◽  
Ooi Zing-Yi ◽  
Norlisa Harruddin ◽  
Raja Norimie ◽  
Norela Jusoh ◽  
...  

Nowadays, water pollution has become major issue especially dye contaminated wastewaters from the textile industry. Dye causes serious environmental pollution and health problems. The removal of color from dye-contaminated wastewaters in the related industries becomes a major concern all over the world. In this research, several parameters of dye extraction and recovery in the continuous emulsion liquid membrane (ELM) process were investigated. This process consisted of three phases which are external (feed) phase, membrane phase and internal phase. The membrane phase was prepared by dissolving extractant bis(2-ethylhexyl)phosphoric acid (D2EHPA) and hydrophobic surfactant sorbitan monooleate (Span 80) in kerosene as diluents. The internal phase consisted of an aqueous solution of sulfuric acid (H2SO4). The important parameters governing the extraction process of dye such as stirring speed, initial dye concentration, Span 80 concentration and treat ratio (volume ratio of emulsion to external phase) were studied. The results showed that the optimum condition for 25ppm initial concentration of dye extraction are 250 rpm stirring speed, 5% (w/v) Span 80 and treat ratio 1:5. At this condition, the percentage of dye extraction, stripping and recovery were 98%, 82% and 81% respectively. Hence, continuous ELM technique is proven to be a very promising technique in industrial wastewater treatment and recovery of dye.


Membranes ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 740
Author(s):  
Abdul Latif Ahmad ◽  
Mohd Hazarel Zairy Mohd Harun ◽  
Mohd Khairul Akmal Jasni ◽  
Nur Dina Zaulkiflee

Ibuprofen (IBP) is a pharmaceutical product that is widely prescribed as an over-the-counter painkiller. It has been classified as a contaminant of emerging concern (CEC) that has received global attention in the search for a better wastewater separation technology. The emulsion liquid membrane (ELM) is one of the potential solutions for IBP removal from wastewater owing to its advantages, such as the ability to remove a highly soluble solute, energy efficient and tuneable formulation. To develop this ELM, a series of parameters such as stirring speed, emulsification time, organic to internal phase volume ratio (O/I), internal phase concentration, carrier concentration and surfactant concentration were studied. The extraction was carried out for 15 min stirring time and the concentration of IBP in the feed phase was determined using a UV-Vis spectrophotometer. The optimum formulation for the ELM was found at 300 rpm stirring speed, 20 min emulsification time, 3:1 of O/I, 0.1 M ammonia, NH3 (stripping agent), 6 wt% trioctylamine, TOA (carrier) and 2 wt% sorbitan monooleate, Span 80 (non-ionic surfactant). IBP removal of 89% was achieved at the optimum parameters of ELM. The current research demonstrated that a newly formulated ELM has great potential in removing a low concentration IBP from wastewater.


2018 ◽  
Vol 37 ◽  
pp. 02005
Author(s):  
L. Kadiri ◽  
A. Lebkiri ◽  
E.H. Rifi ◽  
A. Ouass ◽  
Y. Essaadaoui ◽  
...  

The adsorption of copper ions Cu2+ by Coriandrum Sativum seeds (CSS) from aqueous solution was studied in order to highlight the importance of coriander seeds as a potential tool in the treatment of wastewaters containing heavy metals. The kinetic studies of adsorption of Cu (II) were discussed using the spectroscopic technique “Inducting Coupled Plasma” (ICP). The effects of initial copper ion concentration and contact time were determined. All results show that coriander seeds have, over their culinary and medicinal benefits, a significant adsorbent power of copper ions.


2019 ◽  
Vol 14 (3) ◽  
pp. 652-664
Author(s):  
Bayan abdel Fattah ◽  
Mohamed Mossad ◽  
Hisham Kh. El-Etriby

Abstract The removal of lead Pb+2, copper Cu+2 and cadmium Cd+2 from aqueous solutions by alluvial soil (AL) as adsorbent has been investigated in a series of laboratory scale experiments under various operational conditions (solution pH, adsorbent dose, ions concentration and contact time). Characterization of AL has been carried out using infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). The surface of AL beads is irregular with many spaces, channels and holes, which are helpful for mass transfer of metal ions into AL soil. The optimum ions removal can be achieved in alkaline solutions. Ions removal efficiency is directly related to contact time and adsorbant dose and inversely related to the initial ions concentration. Ion selectivity on AL followed the order of Pb+2 > Cu+2 > Cd+2. The results confirm that AL can remove heavy metals from wastewater efficiently, which is a cheap and environmentally friendly adsorbent. Langmuir and Freundlich isotherms fit the experimental data perfectly. The results indicate that the adsorption of pb+2, Cu+2 and Cd+2 ions is well fitted by the pseudo second-order kinetic model.


2021 ◽  
Vol 58 (1) ◽  
pp. 154-166
Author(s):  
Cristina Ileana Covaliu ◽  
Oana Stoian ◽  
Ecaterina Matei ◽  
Gigel Paraschiv ◽  
Eugenia Tanasa ◽  
...  

Wastewater containing Cu (II) ions has become a huge environmental problem worldwide because ingestion of copper ions affects the human body leading to epigastric pain, nausea, vomiting, diarrhea and even death. The researches for new methods of treatment of wastewater polluted with heavy metals more efficient than the conventional ones led us to study Fe3O4 and his corresponding hybrid Fe3O4 -PVP as potential adsorbent nanomaterials for the removal of copper ions from industrial wastewater. First, the two nanomaterials were synthesized by precipitation method and characterized by XRD, FTIR and TEM analyses. Then, the two obtained nanomaterials were tested within the process of copper ions removal from wastewater and factors influencing the process including pH and contact time were investigated. The maximum wastewater treatment capacity reached up to 97 % under the optimal condition using Fe3O4 and 70% for Fe3O4 -PVP.


2017 ◽  
Vol 82 (5) ◽  
pp. 579-592 ◽  
Author(s):  
Xing Li ◽  
Jun Li ◽  
Yang Jin ◽  
Ming Chen ◽  
Dongya Feng ◽  
...  

Solvent extraction is an efficient, economical and widely-used technology for the purification of wet process phosphoric acid (WPA). This present work focused on the development of a solvent extraction system, TC, representing tri-n-butyl phosphate (TBP) and cyclohexanol mixtures. The equilibrium phase diagram of the system H3PO4?H2O?TC at 298.2 K and atmospheric pressure was obtained. The effects of extraction time, phosphoric acid concentration, extractant concentration, temperature and phase volume ratio on extraction efficiency were studied. The extracted complexes were estimated to be 1.8H3PO4 2TC. The extraction process of H3PO4 was exothermic and the enthalpy change, ?H, was obtained. The solvent mixtures had a high efficiency for phosphoric acid purification via multi-stage counter-current extraction from the industrial WPA in a reciprocating plate extraction column with an H3PO4 extraction yield of 85.08 % at 313.2 K. The stability, extraction efficiency and recycling capability of TC for H3PO4 extraction were also estimated.


Author(s):  
Seroor Atalah Khaleefa Alia ◽  
Dr. Mohammed Ibrahimb ◽  
Hussein Ali Hussein

Adsorption is most commonly applied process for the removal of pollutants such as dyes and heavy metals ions from wastewater. The present work talks about preparing graphenic material attached sand grains called graphene sand composite (GSC) by using ordinary sugar as a carbon source. Physical morphology and chemical composition of GSC was examined by using (FTIR, SEM, EDAX and XRD). Efficiency of GSC in the adsorption of organic dyes from water was investigated using reactive green dye with different parameters such as (ph, temperature, contact time and dose). Adsorption isotherm was also studied and the results showed that the maximum adsorption capacity of dye is 28.98 mg/g. This fast, low-cost process can be used to manufacture commercial filters to treat contaminated water using appropriate engineering designs.


2018 ◽  
Vol 69 (3) ◽  
pp. 571-574
Author(s):  
Mihaela Andreea Mitiu ◽  
Maria Iuliana Marcus ◽  
Maria Vlad ◽  
Cristina Mihaela Balaceanu

This paper presents the results of the research activity in order to etablish the stability and leaching potential of ceramic tiles which have been developed using glazes colored with pigments obtained by the extraction of chromium and iron metals from electroplating sludge. All these ceramic tiles contain various amounts of heavy metals in their glazes due to the pigments composition. The ceramic samples have been subjected to leaching tests in order to detect if various elements of relevance such as chromium, lead, cadmium, zinc or iron migrated to any great extent into test solutions. Leaching tests have been performed following the international standard SR ISO 10545-15 method for specific metals leaching into 4% acetic acid solutions at 220C after a 24h period and the international standard SR EN 12457/1-4 method with distilled water as leaching agent at LSR of 10 l/kg, for 24h period. Amounts of heavy metals have been negligible or non-detectable (iron) in the leaching solutions, being well below the limit values established by the legislation in force.


Author(s):  
Joshua O. Ighalo ◽  
Lois T. Arowoyele ◽  
Samuel Ogunniyi ◽  
Comfort A. Adeyanju ◽  
Folasade M. Oladipo-Emmanuel ◽  
...  

Background: The presence of pollutants in polluted water is not singularized hence pollutant species are constantly in competition for active sites during the adsorption process. A key advantage of competitive adsorption studies is that it informs on the adsorbent performance in real water treatment applications. Objective: This study aims to investigate the competitive adsorption of Pb(II), Cu(II), Fe(II) and Zn(II) using elephant grass (Pennisetum purpureum) biochar and hybrid biochar from LDPE. Method: The produced biochar was characterised by Scanning Electron Microscopy (SEM) and Fourier Transform Infrared Spectroscopy (FTIR). The effect of adsorption parameters, equilibrium isotherm modelling and parametric studies were conducted based on data from the batch adsorption experiments. Results: For both adsorbents, the removal efficiency was >99% over the domain of the entire investigation for dosage and contact time suggesting that they are very efficient for removing multiple heavy metals from aqueous media. It was observed that removal efficiency was optimal at 2 g/l dosage and contact time of 20 minutes for both adsorbent types. The Elovich isotherm and the pseudo-second order kinetic models were best-fit for the competitive adsorption process. Conclusion: The study was able to successfully reveal that biomass biochar from elephant grass and hybrid biochar from LDPE can be used as effective adsorbent material for the removal of heavy metals from aqueous media. This study bears a positive implication for environmental protection and solid waste management.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Waheed Ali Khoso ◽  
Noor Haleem ◽  
Muhammad Anwar Baig ◽  
Yousuf Jamal

AbstractThe heavy metals, such as Cr(VI), Pb(II) and Cd(II), in aqueous solutions are toxic even at trace levels and have caused adverse health impacts on human beings. Hence the removal of these heavy metals from the aqueous environment is important to protect biodiversity, hydrosphere ecosystems, and human beings. In this study, magnetic Nickel-Ferrite Nanoparticles (NFNs) were synthesized by co-precipitation method and characterized using X-Ray Diffraction (XRD), Energy Dispersive Spectroscopy (EDS) and Field Emission Scanning Electronic Microscopy (FE-SEM) techniques in order to confirm the crystalline structure, composition and morphology of the NFN’s, these were then used as adsorbent for the removal of Cr(VI), Pb(II) and Cd(II) from wastewater. The adsorption parameters under study were pH, dose and contact time. The values for optimum removal through batch-adsorption were investigated at different parameters (pH 3–7, dose: 10, 20, 30, 40 and 50 mg and contact time: 30, 60, 90, and 120 min). Removal efficiencies of Cr(VI), Pb(II) and Cd(II) were obtained 89%, 79% and 87% respectively under optimal conditions. It was found that the kinetics followed the pseudo second order model for the removal of heavy metals using Nickel ferrite nanoparticles.


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