scholarly journals Mineralogy and genesis of soils developed from ultrabasic and alkaline rocks of Lages Alkaline Complex, Brazil

2021 ◽  
Vol 16 (2) ◽  
pp. 1-12
Author(s):  
Á.E.D.V. Longo ◽  
J.A. Almeida ◽  
G.O.M. Cunha ◽  
C.J.R. Lazzari
Keyword(s):  
Alkaline Complex ◽  
Alkaline Rocks ◽  
Genesis Of Soils

Eocene post-collisional magmatism in Himalaya orogenic belt: evidence from petrography, zircon U-Pb age and Sr-Nd-Hf isotope of the Mayum alkaline complex, southern Lhasa subterrane

2020 ◽  
Author(s):  
Xiaoshuang Chen ◽  
Haijin Xu
Keyword(s):  
Oceanic Lithosphere ◽  
Hf Isotope ◽  
Alkaline Magmatism ◽  
Early Eocene ◽  
Alkaline Complex ◽  
Southern Tibet ◽  
Quartz Syenite ◽  
Alkaline Rocks ◽  
Slab Breakoff ◽  
T Values

<p>Alkaline magmatism is commonly generated in extensional settings, playing an important role in constraining the timing of slab breakoff. Eocene post-collisional magmatism is widely distributed along the Gangdese belt of southern Tibet. However, few Eocene post-collisional alkaline magmatism has been identified. Here, we present a comprehensive study of whole-rock geochemistry, zircon U-Pb ages and Sr-Nd-Hf isotopes of the Mayum alkaline complex from the Southern Lhasa Subterrane, providing an insight into the timing of breakoff of the Neo-Tethyan slab. The alkaline complex is composed of amphibolite syenite, quartz syenite and alkaline granite. The mafic microgranular enclaves are ubiquitous in the syenites. Zircon U-Pb analyses indicates that the alkaline rocks were generated in Early Eocene (ca. 53-50 Ma). These ages suggest that the alkaline rocks emplaced shortly (10-15Ma) after the continental collision between the Indian and Eurasian plates. The alkaline rocks have high SiO<sub>2 </sub>(64.32-77.36 wt.%), Na<sub>2</sub>O + K<sub>2</sub>O (6.63-9.03 wt.%) contents, low MgO (0.14-2.52 wt.%) contents. These rocks show obvious arc-like geochemical features in trace elements, i.e., enrichment in LILEs (e.g., Rb, K), LREEs, Th and U, and depletion in HFSEs (e.g., Nb, Ta, Ti), HREEs with strongly to moderately negative Eu anomalies (δEu=0.28–0.72). These features together with high FeO<sup>T</sup>/MgO, Ga/Al, Ce/Nb and Y/Nb values, and low Ba, Sr contents, suggesting that the Mayum alkaline rocks belong to an A2-type granitoids. Besides, the alkaline rocks have homogeneous initial <sup>87</sup>Sr/<sup>86</sup>Sr ratios (0.7052-0.7059) and negative ε<sub>Nd</sub>(t) values (-2.1 to -0.9) for whole-rock, and positive zircon ε<sub>Hf</sub>(t) values (+0.73 to +11.16). Nd-Hf isotope decoupling suggests that the alkaline was likely produced by mixing of mantle- and crust-derived magmas under a post-collisional extensional setting. Combined with previous published results, we propose that the slab breakoff of the subducting Neo-Tethyan oceanic lithosphere at least prior to Early Eocene (ca. 53Ma). The Eocene Mayum alkaline complex might be related to asthenosphere upwelling trigged by the slab breakoff.</p>

Petrology and Nd-Sr isotopic composition of alkaline lamprophyres from the Early to Late Cretaceous Mundwara alkaline complex, NW India: Evidence of crystal fractionation, accumulation and corrosion in a complex magma chamber plumbing system

2021 ◽  
pp. SP513-2020-175
Author(s):  
Abhinay Sharma ◽  
Samarendra Sahoo ◽  
N. V. Chalapathi Rao ◽  
B. Belyatsky ◽  
P. Dhote ◽  
...  
Keyword(s):  
Late Cretaceous ◽  
Crystal Fractionation ◽  
Large Igneous Province ◽  
Olivine Gabbro ◽  
Plumbing System ◽  
Alkaline Complex ◽  
Content Type ◽  
Alkaline Rocks ◽  
Magmatic Plumbing System ◽  
Supplementary Material

AbstractThe Early to Late Cretaceous Mundwara alkaline complex (comprising the Musala, Mer and Toa plugs) displays a broad spectrum of alkaline rocks closely associated in space and time with the Deccan Large Igneous Province (DLIP) in NW India. Petrology and Nd-Sr isotopic data on two youngest and altogether compositionally different lamprophyre dykes of the Mundwara alkaline complex are presented in this paper to understand their petrogenesis and also to constrain the magmatic processes responsible for generation of the rock spectrum in the complex (pyroxenite, picrite ankaramite, carbonatite, shonkinite, olivine gabbro, feldspathoidal and foid-free syenite). The two lamprophyre dykes occurring in the Mer and the Musala hills are referred to as basaltic camptonite I and camptonite II, respectively. The basaltic camptonite-I is highly porphyritic and contains olivine, clinopyroxene and magnetite macrocrysts embedded within the groundmass of microphenocyrsts composed of clinopyroxene, phlogopite, magnetite and feldspar. Whereas camptonite-II, with more or less similar texture, contains amphibole, biotite, magnetite and clinopyroxene within the microphenocrystic groundmass of amphibole, biotite, apatite and feldspar. Pyroxenes are chemically zoned and display corrosion of the cores revealing that they are antecrysts developed during early stages of magma evolution and later on inherited by more evolved magmas. Mineral chemistry and trace element composition of the lamprophyres reveal that fractional crystallisation was a dominant process. Early segregation of olivine + Cr-rich clinopyroxene + Cr-spinel from a primary hydrous alkali basalt within a magmatic plumbing system is inferred which led to the generation of basaltic camptonitic magma (M1) forming the Mer hill lamprophyre. Subsequently, progressive fractionation of pyroxene and Fe-Ti oxides from the basaltic camptonitic (M1) magma generated camptonitic (M2) magma forming the Musala hill lamprophyre. Both lamprophyre dykes on the Sr-Nd isotopic array reflect plume type asthenospheric derivation which largely corresponds to the Réunion plume and other alkaline rocks of the Deccan LIP. Our study brings out a complex sequence of processes such as crystal fractionation, accumulation and corrosion in the magmatic plumbing system involved in the generation of the Mundwara alkaline complex.Supplementary material at https://doi.org/10.6084/m9.figshare.c.5277073

Potassium–argon geochronology of the Poohbah Lake alkaline complex, northwestern Ontario

1976 ◽  
Vol 13 (10) ◽  
pp. 1456-1459 ◽  
Author(s):  
Roger H. Mitchell
Keyword(s):  
Alkaline Rock ◽  
Strike Slip ◽  
The Other ◽  
Alkaline Complex ◽  
Geological Evidence ◽  
Thermal Event ◽  
Alkaline Rocks ◽  
Northwestern Ontario ◽  
Tight Cluster ◽  
Minimum Age

The Poohbah Lake complex is an Archean undersaturated potassic pluton consisting of porphyritic syenite, malignite, amphibole syenite, and biotite–pyroxenite, intrusive into Couchiching metasediments. Apparent K–Ar ages for biotites from the alkaline rocks fall into two groups, one (2 samples) with ages greater than 2700 m.y., the other (8 samples) forming a tight cluster of ages at 2556 ± 36 m.y. This latter group defines a K–Ar isochron age of 2706 ± 23 m.y. The data are interpreted to imply that the isochron age and the ca. 2700 m.y. apparent ages record the cooling age of the complex and that the majority of samples were subjected to a later thermal event which resulted in loss of equal amounts of Ar from each sample, this event being correlated with epeirogenic strike-slip faulting. Algoman granite and pegmatite (3 samples), which on geological evidence was emplaced later than the alkaline rocks, gives apparent K–Ar ages of 2550–2630 m.y. Algoman mica samples plot on the alkaline rock isochron giving 2702 ± 24 m.y. as a minimum age for plutonism in this area.

Naujakasite from the Ilímaussaq alkaline complex, South Greenland, and the Lovozero alkaline complex, Kola Peninsula, Russia: a comparison

2001 ◽  
pp. 95-104
Author(s):  
Alexander P. Khomyakov ◽  
Henning Sørensen ◽  
Ole V. Petersen ◽  
John C. Bailey
Keyword(s):  
Kola Peninsula ◽  
Atomic Ratio ◽  
New Mineral ◽  
Common Elements ◽  
Alkaline Complex ◽  
Original Series ◽  
Alkaline Rocks ◽  
Highly Evolved

NOTE: This article was published in a former series of GEUS Bulletin. Please use the original series name when citing this article, for example: Khomyakov, A. P., Sørensen, H., Petersen, O. V., & Bailey, J. C. (2001). Naujakasite from the Ilímaussaq alkaline complex, South Greenland, and the Lovozero alkaline complex, Kola Peninsula, Russia: a comparison. Geology of Greenland Survey Bulletin, 190, 95-104. https://doi.org/10.34194/ggub.v190.5178 _______________ Naujakasite, Na6(Fe,Mn)Al4Si8O26, long known from the Ilímaussaq alkaline complex, South Greenland, was not reported until 1999 from other occurrences of alkaline rocks in spite of the fact that the mineral is composed of common elements. In 1999, a variety of naujakasite rich in Mn was found in the Lovozero alkaline complex in the Kola Peninsula, Russia. This variety has been approved by the IMA as a new mineral, manganonaujakasite, Na6(Mn0.53Fe2+ 0.47)Al4Si8O26. At Ilímaussaq naujakasite is a rock-forming mineral in the highly evolved rock naujakasite lujavrite in which it may make up more than 75 vol.%; at Lovozero manganonaujakasite is a very rare constituent in mineralised lovozerite–lomonosovite lujavrite. Naujakasite appears to take the place of nepheline in hyper-agpaitic nepheline syenites characterised by exceptionally high Na/K ratios. The nepheline syenites at Ilímaussaq have an average Na/K (atomic) ratio of 3.08, and the naujakasite lujavrites have the extreme ratio 4.56. The nepheline syenites of the Khibina and Lovozero complexes are characterised by lower Na/K ratios, 1.27 for Khibina and 1.67 for Lovozero, and thus nepheline is stable in the hyper-agpaitic rocks and naujakasite occurs only in pegmatites.

New Findings of Rare Minerals in Alkaline Rocks of Ukrainian Shield

2020 ◽  
Vol 42 (4) ◽  
pp. 3-22
Author(s):  
V.V. SHARYGIN ◽  
S.G. KRYVDIK ◽  
O.V. DUBYNA
Keyword(s):  
Rare Earth ◽  
Chemical Composition ◽  
Ukrainian Shield ◽  
Silicate Mineral ◽  
Alkaline Rocks ◽  
First Finding ◽  
Azov Region ◽  
New Findings ◽  
Oxide Minerals

Over recent years, new rare minerals have been discovered in the alkaline rocks of the Ukrainian Shield. Agpaitic varieties of alkaline magmatic and metasomatic rocks turned out to be especially abundant in rare minerals. Numerous findings are related to alkaline metasomatites which are considered to be fenites and apofenite albitites of the Dmytrivka quarry. It is well known primarily by the presence of various accessory (Nb, REE, and Zr) minerals, as well as silicate and oxide minerals that are rare for Ukraine. The most common albite microcline fenites of this quarry are characterized by rare-earth mineralization, whereas the concentration of REE decreases in apofenite albitites and Zr and Nb increase. New rare minerals were also found in the essentially albite rock with astrophyllite, alkaline pyroxene and amphibole of the Malatersa massif and agpaitic phonolites of the Oktyabrsky massif. In the rocks of the mentioned massifs and occurrences of alkaline rocks the most interesting are the findings of the perraultite — jinshajiangite series. They were found in three points of the Azov area and include 1) perraultite and jinshajiangite in the alkaline metasomatites of the Dmytrivka quarry; 2) only perraultite in agpaitic phonolites of the Oktyabrsky massif (Kam’yana gully); 3) jinshajiangite in a veined albite rock among the gabbro of the Malatersa massif. Baotite and minerals of the hejtmanite — bafertisite series were also found in the metasomatites of the Dmytrivka quarry. The latter belong to intermediate varieties in terms of MnO (10-17 wt.%) and FeO (10-17 wt.%) which distinguishes them from Fe-rich bafertisite from other regions. A silicate mineral with high content of Na, Zr, Mn and elevated Ti and Nb is rarely observed as small inclusions in the kupletskite grains from alkaline metasomatite of the Dmytrivka quarry. According to the chemical composition it was previously diagnosed as janhaugite. Tainiolite was found in some occurrences of alkaline metasomatites in the Azov region. In addition small aggregates of the REE-enriched epidote were found in fenites of the Kaplany village, which is probably the first finding in Ukraine. Two new Zr minerals have been found in the aegirine syenites of the Korsun-Novomyrhorod pluton: elpidite and mineral with a high content of Y2O3 (13-14 wt.%) (Y-hagatalite ?).

A review of the composition and evolution of hydrocarbon gases during solidification of the Ilímaussaq alkaline complex, South Greenland

2001 ◽  
pp. 159-166 ◽  
Author(s):  
Jens Konnerup-Madsen
Keyword(s):  
Nepheline Syenite ◽  
Subsequent Development ◽  
High Water ◽  
Vapour Phase ◽  
Low Carbon ◽  
Low Oxygen ◽  
Alkaline Complex ◽  
Hydrocarbon Gases ◽  
Wide Range ◽  
Water Contents

NOTE: This article was published in a former series of GEUS Bulletin. Please use the original series name when citing this article, for example: Konnerup-Madsen, J. (2001). A review of the composition and evolution of hydrocarbon gases during solidification of the Ilímaussaq alkaline complex, South Greenland. Geology of Greenland Survey Bulletin, 190, 159-166. https://doi.org/10.34194/ggub.v190.5187 _______________ Fluid inclusions in minerals from agpaitic nepheline syenites and hydrothermal veins in the Ilímaussaq complex and in similar agpaitic complexes on the Kola Peninsula, Russia, are dominated by hydrocarbon gases (predominantly methane) and hydrogen. Such volatile compositions differ considerably from those of most other igneous rocks and their formation and entrapment in minerals reflects low oxygen fugacities and a wide range of crystallisation temperatures extending to a low-temperature solidus. Their composition reflects initial low carbon contents and high water contents of the magma resulting in the exsolution of a waterrich CO2–H2O dominated vapour phase. Fractionation of chlorides into the vapour phase results in high salinities and the subsequent development of a heterogeneous vapour phase with a highly saline aqueous-rich fraction and a methane-dominated fraction, with preferential entrapment of the latter, possibly due to different wetting characteristics. The light stable isotope compositions support an abiogenic origin for the hydrocarbons in agpaitic nepheline syenite complexes.

Natrophosphate from the Ilímaussaq alkaline complex, South Greenland

2001 ◽  
pp. 139-141
Author(s):  
Ole V. Petersen ◽  
Alexander P. Khomyakov ◽  
Henning Sørensen
Keyword(s):  
Refractive Index ◽  
Kola Peninsula ◽  
Unit Cell Parameter ◽  
Cell Parameter ◽  
Water Soluble ◽  
Type Locality ◽  
Drill Core ◽  
Alkaline Complex ◽  
First Time ◽  
Alkaline Complexes

NOTE: This article was published in a former series of GEUS Bulletin. Please use the original series name when citing this article, for example: Petersen, O. V., Khomyakov, A. P., & Henning. (2001). Natrophosphate from the Ilímaussaq alkaline complex, South Greenland. Geology of Greenland Survey Bulletin, 190, 139-141. https://doi.org/10.34194/ggub.v190.5184 _______________ The rare mineral natrophosphate has been identified for the first time in the Ilímaussaq alkaline complex in a drill core from the Kvanefjeld area. It occurs sparsely in zoned veinlets with cores of natrophosphate and borders of fibrous trona. The natrophosphate is more or less smoky, transparent and unaltered. The refractive index n = 1.448 ± 0.005 is low compared to that given for the material from the type locality, Khibina alkaline complex, Kola Peninsula; the unit cell parameter a = 27.76 ± 0.05 Å is in excellent agreement with that given for the material from the type locality. The veins occur in hyper-agpaitic naujakasite lujavrite; villiaumite is an associated mineral. Only a few water-soluble minerals have so far been found in the Ilímaussaq alkaline complex compared to the wealth of such minerals in the Khibina and Lovozero alkaline complexes. This is possibly at least partly due to lack of necessary precautions during sampling.

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