scholarly journals Contribution of combustion Fe in marine aerosols over the northwestern Pacific estimated by Fe stable isotope ratios

2021 ◽  
Vol 21 (20) ◽  
pp. 16027-16050
Author(s):  
Minako Kurisu ◽  
Kohei Sakata ◽  
Mitsuo Uematsu ◽  
Akinori Ito ◽  
Yoshio Takahashi
Keyword(s):  
East Asia ◽  
Fine Particles ◽  
Isotope Ratios ◽  
The Other ◽  
Northwestern Pacific ◽  
Large Contribution ◽  
Coarse Particles ◽  
Marine Aerosols ◽  
Air Masses ◽  
Surface Ocean

Abstract. The source apportionment of aerosol iron (Fe), including natural and combustion Fe, is an important issue because aerosol Fe can enhance oceanic primary production in the surface ocean. Based on our previous finding that combustion Fe emitted by evaporation processes has Fe isotope ratios (δ56Fe) that are approximately 4 ‰ lower than those of natural Fe, this study aimed to distinguish aerosol Fe sources over the northwestern Pacific using two size-fractionated marine aerosols. The δ56Fe values of fine and coarse particles from the eastern or northern Pacific were found to be similar to each other, ranging from 0.0 ‰ to 0.4 ‰. Most of them were close to the crustal average, suggesting the dominance of natural Fe. On the other hand, particles from the direction of East Asia demonstrated lower δ56Fe values in fine particles (−0.5 ‰ to −2.2 ‰) than in coarse particles (on average −0.02 ± 0.12 ‰). The correlations between the δ56Fe values and the enrichment factors of lead and vanadium suggested that the low δ56Fe values obtained were due to the presence of combustion Fe. The δ56Fe values of the soluble component of fine particles in this region were lower than the total, indicating the preferential dissolution of combustion Fe. In addition, we found a negative correlation between the δ56Fe value and the fractional Fe solubility in air masses from the direction of East Asia. These results suggest that the presence of combustion Fe is an important factor in controlling the fractional Fe solubility in air masses from the direction of East Asia, whereas other factors are more important in the other areas. By assuming typical δ56Fe values for combustion and natural Fe, the contribution of combustion Fe to the total (acid-digested) Fe in aerosols was estimated to reach up to 50 % of fine and 21 % of bulk (coarse + fine) particles in air masses from the direction of East Asia, whereas its contribution was small in the other areas. The contribution of combustion Fe to the soluble Fe component estimated for one sample was approximately twice as large as the total, indicating the importance of combustion Fe as a soluble Fe source despite lower emissions than the natural. These isotope-based estimates were compared with those estimated using an atmospheric chemical transport model (IMPACT), in which the fractions of combustion Fe in fine particles, especially in air masses from the direction of East Asia, were consistent with each other. In contrast, the model estimated a relatively large contribution from combustion Fe in coarse particles, probably because of the different characteristics of combustion Fe that are included in the model calculation and the isotope-based estimation. This highlights the importance of observational data on δ56Fe for size-fractionated aerosols to scale the combustion Fe emission by the model. The average deposition fluxes of soluble Fe to the surface ocean were 1.4 and 2.9 nmol m−2 d−1 from combustion and natural aerosols, respectively, in air masses from the direction of East Asia, which suggests that combustion Fe could be an important Fe source to the surface seawater among other Fe sources. Distinguishing Fe sources using the δ56Fe values of marine aerosols and seawater is anticipated to lead to a more quantitative understanding of the Fe cycle in the atmosphere and surface ocean.

scholarly journals Contribution of combustion Fe in marine aerosols over the northwestern Pacific estimated by Fe stable isotope ratios

2021 ◽  
Author(s):  
Minako Kurisu ◽  
Kohei Sakata ◽  
Mitsuo Uematsu ◽  
Akinori Ito ◽  
Yoshio Takahashi
Keyword(s):  
East Asia ◽  
Fine Particles ◽  
Isotope Ratios ◽  
The Other ◽  
Northwestern Pacific ◽  
Large Contribution ◽  
Coarse Particles ◽  
Marine Aerosols ◽  
Air Masses ◽  
Surface Ocean

Abstract. The source apportionment of aerosol iron (Fe), including natural and combustion Fe, is an important issue because aerosol Fe can enhance oceanic primary production in the surface ocean. Based on our previous finding that combustion Fe emitted by evaporation processes has Fe isotope ratios (δ56Fe) that are approximately 4 ‰ lower than those of natural Fe, this study aimed to distinguish aerosol Fe sources over the northwestern Pacific using two size-fractionated marine aerosols. The δ56Fe values of fine and coarse particles from the eastern or northern Pacific were found to be similar to each other, ranging from 0.0 to 0.4 ‰. Most of them were close to the crustal average, suggesting the dominance of natural Fe. On the other hand, particles from East Asia demonstrated lower δ56Fe values in fine particles (−0.5 to −2.2 ‰) than in coarse particles (on average 0.1 ‰). The correlations between the δ56Fe values and the enrichment factors of lead and vanadium suggested that the low δ56Fe values obtained were due to the presence of combustion Fe. The δ56Fe values of the soluble component of fine particles in this region were lower than the total, indicating the preferential dissolution of combustion Fe. In addition, we found a negative correlation between the δ56Fe value and the fractional Fe solubility in air masses from East Asia. These results suggested that the presence of combustion Fe is an important factor in controlling the fractional Fe solubility in air masses from East Asia, whereas other factors were more important in the other areas. By assuming typical δ56Fe values for combustion and natural Fe, the contribution of combustion Fe to the total (acid-digested) Fe in aerosols was estimated to reach up to 50 % of fine and 21 % of bulk (coarse + fine) particles in air masses from East Asia, whereas its contribution was small in the other areas. The contribution of combustion Fe to the soluble Fe component estimated for one sample was approximately twice as large as the total, indicating the importance of combustion Fe as a soluble Fe source, despite lower emissions than the natural. These isotope-based estimates were compared with those estimated using an atmospheric chemical transport model (IMPACT), in which the fractions of combustion Fe in fine particles, especially in air masses from East Asia, were consistent with each other. In contrast, the model estimated a relatively large contribution from combustion Fe in coarse particles, probably because of the different characteristics of combustion Fe that are included in the model calculation and the isotope-based estimation. This highlights the importance of observational data of δ56Fe for size-fractionated aerosols to scale the combustion Fe emission by the model. The average deposition fluxes of soluble Fe to the surface ocean were 1.4 and 2.9 nmol m−2 day−1 from combustion and natural aerosols, respectively, in air masses from East Asia, which suggests combustion Fe could be an important Fe source to the surface seawater among other Fe sources. Distinguishing Fe sources using the δ56Fe values of marine aerosols and seawater is anticipated to lead to a more quantitative understanding of the Fe cycle in the atmosphere and surface ocean.

scholarly journals Seasonal variations and vertical features of aerosol particles in the Antarctic troposphere

2011 ◽  
Vol 11 (3) ◽  
pp. 7555-7591 ◽  
Author(s):  
K. Hara ◽  
K. Osada ◽  
C. Nishita-Hara ◽  
T. Yamanouchi
Keyword(s):  
Seasonal Variations ◽  
Fine Particles ◽  
Austral Summer ◽  
Sea Salt ◽  
Coarse Particles ◽  
Free Troposphere ◽  
Syowa Station ◽  
Air Masses ◽  
Antarctic Expedition ◽  
The Antarctic

Abstract. Tethered balloon-borne aerosol measurements were conducted at Syowa Station, Antarctica during the 46th Japanese Antarctic expedition (2005–2006). The CN concentration reached a maximum in the summer, although the number concentrations of fine particles (Dp > 0.3 μm) and coarse particles (Dp > 2.0 μm) increased during the winter-spring. The CN concentration was 30–2200 cm−3 near the surface (surface – 500 m) and 7–7250 cm−3 in the lower free troposphere (>1500 m). During the austral summer, higher CN concentration was often observed in the lower free troposphere, where the number concentrations in fine and coarse modes were remarkably lower. The frequent appearance of higher CN concentrations in the free troposphere relative to continuous aerosol measurements at the ground strongly suggests that new particle formation is more likely to occur in the lower free troposphere in Antarctic regions. Seasonal variations of size distribution of fine-coarse particles show that the contribution of the coarse mode was greater in the winter-spring than in summer because of the dominance of sea-salt particles in the winter-spring. The number concentrations of fine and coarse particles were high in air masses from the ocean and mid-latitudes. Particularly, aerosol enhancement was observed not only in the boundary layer but also in the lower free troposphere during and immediately after Antarctic haze events occurring in May, July, and September.

scholarly journals Seasonal variations and vertical features of aerosol particles in the Antarctic troposphere

2011 ◽  
Vol 11 (11) ◽  
pp. 5471-5484 ◽  
Author(s):  
K. Hara ◽  
K. Osada ◽  
C. Nishita-Hara ◽  
T. Yamanouchi
Keyword(s):  
Seasonal Variations ◽  
Fine Particles ◽  
Austral Summer ◽  
Sea Salt ◽  
Coarse Particles ◽  
Free Troposphere ◽  
Syowa Station ◽  
Air Masses ◽  
Antarctic Expedition ◽  
The Antarctic

Abstract. Tethered balloon-borne aerosol measurements were conducted at Syowa Station, Antarctica during the 46th Japanese Antarctic expedition (2005–2006). The CN concentration reached a maximum in the summer, although the number concentrations of fine particles (Dp>0.3 μm) and coarse particles (Dp>2.0 μm) increased during the winter–spring. The CN concentration was 30–2200 cm−3 near the surface (surface – 500 m) and 7–7250 cm−3 in the lower free troposphere (>1500 m). During the austral summer, higher CN concentration was often observed in the lower free troposphere, where the number concentrations in fine and coarse modes were remarkably lower. The frequent appearance of higher CN concentrations in the free troposphere relative to continuous aerosol measurements at the ground strongly suggests that new particle formation is more likely to occur in the lower free troposphere in Antarctic regions. Seasonal variations of size distribution of fine-coarse particles show that the contribution of the coarse mode was greater in the winter–spring than in summer because of the dominance of sea-salt particles in the winter–spring. The number concentrations of fine and coarse particles were high in air masses from the ocean and mid-latitudes. Particularly, aerosol enhancement was observed not only in the boundary layer, but also in the lower free troposphere during and immediately after Antarctic haze events occurring in May, July and September.

scholarly journals Contribution of Fine Particles to Air Emission at Different Phases of Biomass Burning

Atmosphere ◽  
2019 ◽  
Vol 10 (5) ◽  
pp. 278 ◽  
Author(s):  
Niloofar Ordou ◽  
Igor E. Agranovski
Keyword(s):  
Particle Size ◽  
Particle Size Distribution ◽  
Fine Particles ◽  
Combustion Process ◽  
Coarse Particles ◽  
Biomass Smoke ◽  
Smoke Particles ◽  
Air Emission ◽  
Entire Duration ◽  
Diffusion Properties

Particle size distribution in biomass smoke was observed for different burning phases, including flaming and smouldering, during the combustion of nine common Australian vegetation representatives. Smoke particles generated during the smouldering phase of combustions were found to be coarser as compared to flaming aerosols for all hard species. In contrast, for leafy species, this trend was inversed. In addition, the combustion process was investigated over the entire duration of burning by acquiring data with one second time resolution for all nine species. Particles were separately characterised in two categories: fine particles with dominating diffusion properties measurable with diffusion-based instruments (Dp < 200 nm), and coarse particles with dominating inertia (Dp > 200 nm). It was found that fine particles contribute to more than 90 percent of the total fresh smoke particles for all investigated species.

scholarly journals Modeling of solid sediment transport in mountain rivers

2020 ◽  
Vol 175 ◽  
pp. 12002 ◽  
Author(s):  
Issam Boukhanef ◽  
Anna Khadzhidi ◽  
Lyudmila Kravchenko ◽  
Zeroual Ayoub ◽  
Kastali Abdennour
Keyword(s):  
Sediment Transport ◽  
Fine Particles ◽  
Agricultural Soils ◽  
Suspended Sediments ◽  
High Water ◽  
The Other ◽  
Concentration Data ◽  
Solid Transport ◽  
One Year ◽  
The One

In Algeria, the problems of erosion and sediment transport are critical, since they have the most dramatic consequences of the degradation of agricultural soils on the one hand and the siltation of the dam on the other .The sediment transport in the Algerian basins is very important especially during the periods of floods, It is in this sense that this study, which consists of estimating the sediment transport in suspension and determining the models of relation linking the liquid discharge and the sediment discharge in order to estimate the solid transport in the absence of suspended sediments concentration data at the Sidi Akkacha station at the outlet of the basin of Oued Allala which is subject to a high water erosion, it degrades from one year to the other under the effect of this phenomenon especially during the floods which drain high amounts of fine particles exceeding in general, the concentration of 150 g/l, the results obtained from the application of the models are very encouraging since the correlation between liquid and solid discharge exceeds 80 %.

scholarly journals Characterization of Bacterial Communities in Bioaerosols over Northern Chinese Marginal Seas and the Northwestern Pacific Ocean in Spring

2019 ◽  
Vol 58 (4) ◽  
pp. 903-917 ◽  
Author(s):  
Manman Ma ◽  
Yu Zhen ◽  
Tiezhu Mi
Keyword(s):  
Pacific Ocean ◽  
Yellow Sea ◽  
Bacterial Communities ◽  
Bohai Sea ◽  
The Yellow Sea ◽  
Northwestern Pacific ◽  
Particle Sizes ◽  
Marine Aerosols ◽  
Northwestern Pacific Ocean ◽  
The Bohai Sea

AbstractStudies of the community structures of bacteria in marine aerosols of different particle sizes have not been reported. Aerosol samples were collected using a six-stage bioaerosol sampler over the Bohai Sea, the Yellow Sea, and northwestern Pacific Ocean in the spring of 2014. The diversity and composition of these samples were investigated by Illumina high-throughput sequencing, and 130 genera were detected in all of the samples; the most abundant bacterial genus was Bacteroides, followed by Prevotella and Megamonas. The Chao1 and Shannon diversity indices ranged from 193 to 1044 and from 5.44 to 8.33, respectively. The bacterial community structure in coarse particles (diameter larger than 2.1 μm) was more complex and diverse than that in fine particles (diameter less than 2.1 μm) in marine bioaerosols from over the Yellow Sea and northwestern Pacific Ocean, while the opposite trend was observed for samples collected over the Bohai Sea. Although we were sampling over marine regions, the sources of the bioaerosols were mostly continental. Temperature and wind speed significantly influenced the bacterial communities in marine aerosols of different particle sizes. There may be a bacterial background in the atmosphere in the form of several dominant taxa, and the bacterial communities are likely mixed constantly during transmission.

THE AGE OF ATTAINING BLADDER CONTROL

PEDIATRICS ◽  
1968 ◽  
Vol 42 (4) ◽  
pp. 614-626
Author(s):  
Wallace C. Oppel ◽  
Paul A. Harper ◽  
Rowland V. Rider
Keyword(s):  
Birth Weight ◽  
Low Birth Weight ◽  
Prospective Study ◽  
Life Table ◽  
Median Duration ◽  
The Other ◽  
Large Contribution ◽  
Median Length ◽  
Bladder Control ◽  
Study Population

Data in life table form are presented from a 12-year prospective study of 859 children on the age of attaining bladder control for waking and sleeping hours by three indices: (1) age of initial dryness, (2) age of final dryness, and (3) the prevalence of dryness. By use of these indices the large contribution of relapsers to enuresis is seen. The prevalence of bedwetting in the study population was greater than that reported in other studies; the validity of this finding is defended. A larger proportion of female than male children attained both day and night dryness during the first 2 years of life. The percentage of Negro boys who first attained dryness was less than that of the other three race-sex groups after 2 years of age and was significantly less than that of Negro girls until 9 years of age. One quarter of the 817 children who attained initial nighttime dryness by age 12 relapsed; these relapsing episodes had a median duration of 2.5 years. One tenth of 855 children who attained initial daytime dryness had relapses, and the median length of these was 1.2 years. Relapsing occurred much more frequently in Negro than Caucasian children; it also was seen more often in Caucasian males than in Caucasian females. Low birth weight children had a higher percentage of children wet for both waking and sleeping hours than did full birth weight children.

scholarly journals Quantifying Asymmetric Wave Breaking and Two-Way Transport

2004 ◽  
Vol 61 (22) ◽  
pp. 2735-2748 ◽  
Author(s):  
Noboru Nakamura
Keyword(s):  
Wave Breaking ◽  
Polar Vortex ◽  
Effective Diffusivity ◽  
The Other ◽  
Stratospheric Polar Vortex ◽  
Air Masses ◽  
Rossby Wave Breaking ◽  
Advection Diffusion Equation ◽  
Extratropical Tropopause ◽  
Asymmetric Wave

Abstract Effective diffusivity calculated from a scalar field that obeys the advection–diffusion equation has proved useful for estimating the permeability of unsteady boundaries of air masses such as the edge of the stratospheric polar vortex and the extratropical tropopause. However, the method does not discriminate the direction of transport—whereas some material crosses the boundary from one side to the other, some material does so in the other direction—yet the extant method concerns only the net transport. In this paper, the diagnostic is extended to allow partitioning of fluxes of mass and tracer into opposing directions. This is accomplished by discriminating the regions of “inward” and “outward” wave breaking with the local curvature of the tracer field. The utility of the new method is demonstrated for nonlinear Kelvin– Helmholtz instability and Rossby wave breaking in the stratosphere using a numerically generated tracer. The method successfully quantifies two-way transport and hence the direction of wave breaking—the predominantly equatorward breaking of Rossby waves in the extratropical middle stratosphere, for example. Isolated episodes of mixing are identified well, particularly by the mass flux that primarily arises from the tracer filaments. Comparison of different transport schemes suggests that the results are reasonably robust under a varying subgrid representation of the model.

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