scholarly journals ACE-FTS measurements of trace species in the characterization of biomass burning plumes

2011 ◽  
Vol 11 (6) ◽  
pp. 16611-16637 ◽  
Author(s):  
K. A. Tereszchuk ◽  
G. González Abad ◽  
C. Clerbaux ◽  
D. Hurtmans ◽  
P.-F. Coheur ◽  
...  
Keyword(s):  
Biomass Burning ◽  
Atmospheric Chemistry ◽  
Atmospheric Composition ◽  
Emission Region ◽  
Free Troposphere ◽  
Airborne Measurements ◽  
Convective Processes ◽  
Trace Species ◽  
Chemistry Experiment

Abstract. To further our understanding of the effects of biomass burning emission on atmospheric composition, we report measurements of trace species from biomass burning plumes made by the Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS) instrument on the SCISAT-1 satellite. An extensive set of 15 molecules, C2H2, C2H6, CH3OH, CH4, CO, H2CO, HCN, HCOOH, HNO3, NO, NO2, N2O5, O3, OCS and SF6 are used in our analysis. Even though most biomass burning smoke is typically confined to the boundary layer, much of these emissions are injected directly into the free troposphere via fire-related convective processes and transported away from the emission region. Further knowledge of the aging of biomass burning emission in the free troposphere is needed. Tracer-tracer correlations are made between known pyrogenic species in these plumes in an effort to classify them and follow their chemical evolution. Criteria such as age and type of biomass material burned are considered. Emission factors are derived and compared to airborne measurements of biomass burning from numerous ecosystems to validate the ACE-FTS data.

scholarly journals ACE-FTS measurements of trace species in the characterization of biomass burning plumes

2011 ◽  
Vol 11 (23) ◽  
pp. 12169-12179 ◽  
Author(s):  
K. A. Tereszchuk ◽  
G. González Abad ◽  
C. Clerbaux ◽  
D. Hurtmans ◽  
P.-F. Coheur ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Biomass Burning ◽  
Atmospheric Chemistry ◽  
Atmospheric Composition ◽  
Fourier Transform Spectrometer ◽  
Free Troposphere ◽  
Convective Processes ◽  
Trace Species ◽  
Chemistry Experiment

Abstract. To further our understanding of the effects of biomass burning emissions on atmospheric composition, we report measurements of trace species in biomass burning plumes made by the Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS) instrument on the SCISAT-1 satellite. An extensive set of 15 molecules, C2H2, C2H6, CH3OH, CH4, CO, H2CO, HCN, HCOOH, HNO3, NO, NO2, N2O5, O3, OCS and SF6 are used in our analysis. Even though most biomass burning smoke is typically confined to the boundary layer, some of these emissions are injected directly into the free troposphere via fire-related convective processes and transported away from the emission source. Further knowledge of the aging of biomass burning emissions in the free troposphere is needed. Tracer-tracer correlations are made between known pyrogenic species in these plumes in an effort to characterize them and follow their chemical evolution. Criteria such as age and type of biomass material burned are considered.

scholarly journals ACE-FTS observations of pyrogenic trace species in boreal biomass burning plumes during BORTAS

2013 ◽  
Vol 13 (9) ◽  
pp. 4529-4541 ◽  
Author(s):  
K. A. Tereszchuk ◽  
G. González Abad ◽  
C. Clerbaux ◽  
J. Hadji-Lazaro ◽  
D. Hurtmans ◽  
...  
Keyword(s):  
Boreal Forest ◽  
Biomass Burning ◽  
Atmospheric Chemistry ◽  
Atmospheric Composition ◽  
Fire Season ◽  
Satellite Measurement ◽  
Free Troposphere ◽  
Molar Ratios ◽  
Convective Processes ◽  
Trace Species

Abstract. To further our understanding of the effects of biomass burning emissions on atmospheric composition, the BORTAS campaign (BOReal forest fires on Tropospheric oxidants over the Atlantic using Aircraft and Satellites) was conducted on 12 July to 3 August 2011 during the boreal forest fire season in Canada. The simultaneous aerial, ground and satellite measurement campaign sought to record instances of boreal biomass burning to measure the tropospheric volume mixing ratios (VMRs) of short- and long-lived trace molecular species from biomass burning emissions. The goal was to investigate the connection between the composition and the distribution of these pyrogenic outflows and their resulting perturbation to atmospheric chemistry, with particular focus on oxidant species to determine the overall impact on the oxidizing capacity of the free troposphere. Measurements of pyrogenic trace species in boreal biomass burning plumes were made by the Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS) onboard the Canadian Space Agency (CSA) SCISAT-1 satellite during the BORTAS campaign. Even though biomass burning emissions are typically confined to the boundary layer, outflows are often injected into the upper troposphere by isolated convection and fire-related convective processes, thus allowing space-borne instruments to measure these pyrogenic outflows. An extensive set of 14 molecules – CH3OH, C2H2, C2H6, C3H6O, CO, HCN, HCOOH, HNO3, H2CO, NO, NO2, OCS, O3, and PAN – have been analysed. Included in this analysis is the calculation of age-dependent sets of enhancement ratios for each of the species originating from fires in North America (Canada, Alaska) and Siberia for a period of up to 7 days. Ratio values for the shorter lived primary pyrogenic species decrease over time primarily due to oxidation by the OH radical as the plume ages and values for longer lived species such as HCN and C2H6 remain relatively unchanged. Increasing negative values are observed for the oxidant species, including O3, indicating a destruction process in the plume as it ages such that concentrations of the oxidant species have dropped below their off-plume values. Results from previous campaigns have indicated that values for the molar ratios of ΔO3 /ΔO obtained from the measurements of the pyrogenic outflow from boreal fires are highly variable and range from negative to positive, irrespective of plume age. This variability has been attributed to pollution effects where the pyrogenic outflows have mixed with either local urban NOx emissions or pyrogenic emissions from the long-range transport of older plumes, thus affecting the production of O3 within the plumes. The results from this study have identified another potential cause of the variability in O3 concentrations observed in the measurements of biomass burning emissions, where evidence of stratosphere–troposphere exchange due to the pyroconvective updrafts from fires has been identified. Perturbations caused by the lofted emissions in these fire-aided convective processes may result in the intrusion of stratospheric air masses into the free troposphere and subsequent mixing of stratospheric O3 into the pyrogenic outflows causing fluctuations in observed ΔO3/ΔCO molar ratios.

scholarly journals ACE-FTS observations of pyrogenic trace species in boreal biomass burning plumes during BORTAS

2012 ◽  
Vol 12 (12) ◽  
pp. 31629-31661 ◽  
Author(s):  
K. A. Tereszchuk ◽  
G. González Abad ◽  
C. Clerbaux ◽  
J. Hadji-Lazaro ◽  
D. Hurtmans ◽  
...  
Keyword(s):  
Boreal Forest ◽  
Biomass Burning ◽  
Atmospheric Chemistry ◽  
Forest Fires ◽  
Atmospheric Composition ◽  
Fire Season ◽  
Satellite Measurement ◽  
Mixing Ratios ◽  
Trace Species ◽  
The Impact

Abstract. To further our understanding of the effects of biomass burning emissions on atmospheric composition, the Quantifying the impact of BOReal forest fires on Tropospheric oxidants over the Atlantic using Aircraft and Satellites (BORTAS) campaign was conducted on 12 July to 3 August 2011 during the Boreal forest fire season in Canada. The simultaneous aerial, ground and satellite measurement campaign sought to record instances of Boreal biomass burning to measure the tropospheric volume mixing ratios (VMRs) of short- and long-lived trace molecular species from biomass burning emissions. The goal was to investigate the connection between the composition and the distribution of these pyrogenic outflows and their resulting perturbation to atmospheric chemistry, with particular focus on oxidant species to determine the overall impact on the oxidizing capacity of the free troposphere. Measurements of pyrogenic trace species in Boreal biomass burning plumes were made by the Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS) onboard the Canadian Space Agency (CSA) SCISAT-1 satellite during the BORTAS campaign. Even though most biomass burning smoke is typically confined to the boundary layer, emissions are often injected directly into the upper troposphere via fire-related convective processes, thus allowing space-borne instruments to measure these pyrogenic outflows. An extensive set of 15 molecules, CH3OH, CH4, C2H2, C2H6, C3H6O, CO, HCN, HCOOH, HNO3, H2CO, NO, NO2, OCS, O3 and PAN have been analyzed. Included in this analysis is the calculation of age-dependent sets of enhancement ratios for each of the species.

Characterizing two distinct biomass burning regimes over Southeast Asia and their impacts on regional air quality

2020 ◽  
Author(s):  
Margaret Marvin ◽  
Paul Palmer ◽  
Fei Yao ◽  
Barry Latter ◽  
Richard Siddans ◽  
...  
Keyword(s):  
Air Quality ◽  
Southeast Asia ◽  
Biomass Burning ◽  
Atmospheric Chemistry ◽  
Agricultural Waste ◽  
Critical Evaluation ◽  
Dry Season ◽  
Mitigation Strategies ◽  
Atmospheric Composition ◽  
Regional Air Quality

<p>Mainland and maritime Southeast Asia is home to more than 655 million people, representing nearly 10% of the global population. The dry season in this region is typically associated with intense biomass burning activity, which leads to a significant increase in surface air pollutants that are harmful to human health, including ozone (O<sub>3</sub>) and fine (radii smaller than 2.5 microns) particulate matter (PM<sub>2.5</sub>). Latitude-based differences in dry season timing and land use distinguish two regional biomass burning regimes: (1) agricultural waste burning on the peninsular mainland from February through April and (2) coastal peat burning across the equatorial islands in September and October. The type and amount of material burned determines the chemical composition of emissions and subsequently their impact on regional air quality. Understanding the individual and collective roles of these biomass burning regimes is a crucial step towards developing effective air quality mitigation strategies for Southeast Asia. Here, we use the nested GEOS-Chem atmospheric chemistry transport model (horizontal resolution of 0.25° x 0.3125°) to simulate fire-atmosphere interactions over Southeast Asia during March and September of 2014, when emissions peak from the two regional burning seasons. Based on our analysis of model output, we report how these two distinct biomass burning regimes impact the photochemical environment over Southeast Asia and what the resulting consequences are for surface air quality. We will also present a critical evaluation of our model using ground-based and satellite observations of atmospheric composition across the region.</p>

scholarly journals Overview: oxidant and particle photochemical processes above a south-east Asian tropical rainforest (the OP3 project): introduction, rationale, location characteristics and tools

2010 ◽  
Vol 10 (1) ◽  
pp. 169-199 ◽  
Author(s):  
C. N. Hewitt ◽  
J. D. Lee ◽  
A. R. MacKenzie ◽  
M. P. Barkley ◽  
N. Carslaw ◽  
...  
Keyword(s):  
Atmospheric Chemistry ◽  
Tropical Rainforest ◽  
East Asian ◽  
Anthropogenic Pollution ◽  
Atmospheric Composition ◽  
Airborne Measurements ◽  
Photochemical Processes ◽  
Chemical Models ◽  
Modelling Strategies ◽  
Order Of Magnitude

Abstract. In April–July 2008, intensive measurements were made of atmospheric composition and chemistry in Sabah, Malaysia, as part of the "Oxidant and particle photochemical processes above a South-East Asian tropical rainforest" (OP3) project. Fluxes and concentrations of trace gases and particles were made from and above the rainforest canopy at the Bukit Atur Global Atmosphere Watch station and at the nearby Sabahmas oil palm plantation, using both ground-based and airborne measurements. Here, the measurement and modelling strategies used, the characteristics of the sites and an overview of data obtained are described. Composition measurements show that the rainforest site was not significantly impacted by anthropogenic pollution, and this is confirmed by satellite retrievals of NO2 and HCHO. The dominant modulators of atmospheric chemistry at the rainforest site were therefore emissions of BVOCs and soil emissions of reactive nitrogen oxides. At the observed BVOC:NOx volume mixing ratio (~100 pptv/pptv), current chemical models suggest that daytime maximum OH concentrations should be ca. 105 radicals cm−3, but observed OH concentrations were an order of magnitude greater than this. We confirm, therefore, previous measurements that suggest that an unexplained source of OH must exist above tropical rainforest and we continue to interrogate the data to find explanations for this.

scholarly journals Intercomparison of UV-visible measurements of ozone and NO<sub>2</sub> during the Canadian Arctic ACE validation campaigns: 2004–2006

2008 ◽  
Vol 8 (6) ◽  
pp. 1763-1788 ◽  
Author(s):  
A. Fraser ◽  
F. Goutail ◽  
K. Strong ◽  
P. F. Bernath ◽  
C. Boone ◽  
...  
Keyword(s):  
Atmospheric Chemistry ◽  
Canadian Arctic ◽  
Atmospheric Composition ◽  
The Arctic ◽  
Spatial And Temporal Variability ◽  
Fourier Transform Spectrometer ◽  
Satellite Mission ◽  
Vertical Column ◽  
Uv Visible ◽  
Chemistry Experiment

Abstract. The first three Canadian Arctic ACE validation campaigns were held during polar sunrise at Eureka, Nunavut, Canada (80° N, 86° W) from 2004 to 2006 in support of validation of the ACE (Atmospheric Chemistry Experiment) satellite mission. Three or four zenith-sky viewing UV-visible spectrometers have taken part in each of the three campaigns. The differential slant column densities and vertical column densities of ozone and NO2 from these instruments have been compared following the methods of the UV-visible Working Group of the NDACC (Network for Detection of Atmospheric Composition Change). The instruments are found to partially agree within the required accuracies for both species, although both the vertical and slant column densities are more scattered than required. This might be expected given the spatial and temporal variability of the Arctic stratosphere in spring. The vertical column densities are also compared to integrated total columns from ozonesondes and integrated partial columns from the ACE-FTS (ACE-Fourier Transform Spectrometer) and ACE-MAESTRO (ACE-Measurements of Aerosol Extinction in the Stratosphere and Troposphere Retrieved by Occultation) instruments on board ACE. For both species, the columns from the ground-based instruments and the ozonesondes are found to generally agree within their combined error bars. The ACE-FTS ozone partial columns and the ground-based total columns agree within 4.5%, averaged over the three campaigns. The ACE-MAESTRO ozone partial columns are generally smaller than those of the ground-based instruments, by an average of 9.9%, and are smaller than the ACE-FTS columns by an average of 14.4%. The ACE-FTS NO2 partial columns are an average of 13.4% smaller than the total columns from the ground-based instruments, as expected. The ACE-MAESTRO NO2 partial columns are larger than the total columns of the ground-based instruments by an average of 2.5% and are larger than the partial columns of the ACE-FTS by an average of 15.5%.

scholarly journals ACE-FTS observation of a young biomass burning plume: first reported measurements of C<sub>2</sub>H<sub>4</sub>, C<sub>3</sub>H<sub>6</sub>O, H<sub>2</sub>CO and PAN by infrared occultation from space

2007 ◽  
Vol 7 (3) ◽  
pp. 7907-7932 ◽  
Author(s):  
P.-F. Coheur ◽  
H. Herbin ◽  
C. Clerbaux ◽  
D. Hurtmans ◽  
C. Wespes ◽  
...  
Keyword(s):  
Biomass Burning ◽  
Atmospheric Chemistry ◽  
Signal To Noise Ratio ◽  
Source Region ◽  
High Signal ◽  
Upper Troposphere ◽  
Organic Species ◽  
Specific Biomass ◽  
Chemistry Experiment ◽  
Very High

Abstract. In the course of our study of the upper tropospheric composition with the infrared Atmospheric Chemistry Experiment – Fourier Transform Spectrometer (ACE–FTS), we found an occultation sequence that on 8 October 2005, sampled a remarkable plume near the east coast of Tanzania. Model simulations of the CO distribution in the Southern hemisphere are performed for this period and they demonstrate that the emissions for this event originated from a nearby forest fire, after which the plume was transported from the source region to the upper troposphere. Taking advantage of the very high signal-to-noise ratio of the ACE–FTS spectra over a wide wavenumber range (750–4400 cm−1), we present in-depth analyses of the chemical composition of this plume in the middle and upper troposphere, focusing on the measurements of weakly absorbing pollutants. For this specific biomass burning event, we report simultaneous observations of an unprecedented number of organic species. Measurements of C2H4 (ethene), C3H4 (propyne), H2CO (formaldehyde), C3H6O (acetone) and CH3COO2NO2 (peroxyacetylnitrate, abbreviated as PAN) are the first reported detections using infrared occultation spectroscopy from satellites. Based on the lifetime of the emitted species, we discuss the photochemical age of the plume and also report, whenever possible, the enhancement ratios relative to CO.

scholarly journals An optical transmission spectrum of the ultra-hot Jupiter WASP-33 b

2019 ◽  
Vol 622 ◽  
pp. A71 ◽  
Author(s):  
C. von Essen ◽  
M. Mallonn ◽  
L. Welbanks ◽  
N. Madhusudhan ◽  
A. Pinhas ◽  
...  
Keyword(s):  
Light Curves ◽  
Atmospheric Composition ◽  
Data Sets ◽  
Hot Jupiters ◽  
High Data ◽  
Trace Species ◽  
Exoplanetary Atmospheres ◽  
Combined Data ◽  
Hot Jupiter

There has been increasing progress toward detailed characterization of exoplanetary atmospheres, in both observations and theoretical methods. Improvements in observational facilities and data reduction and analysis techniques are enabling increasingly higher quality spectra, especially from ground-based facilities. The high data quality also necessitates concomitant improvements in models required to interpret such data. In particular, the detection of trace species such as metal oxides has been challenging. Extremely irradiated exoplanets (~3000 K) are expected to show oxides with strong absorption signals in the optical. However, there are only a few hot Jupiters where such signatures have been reported. Here we aim to characterize the atmosphere of the ultra-hot Jupiter WASP-33 b using two primary transits taken 18 orbits apart. Our atmospheric retrieval, performed on the combined data sets, provides initial constraints on the atmospheric composition of WASP-33 b. We report a possible indication of aluminum oxide (AlO) at 3.3-σ significance. The data were obtained with the long slit OSIRIS spectrograph mounted at the 10-m Gran Telescopio Canarias. We cleaned the brightness variations from the light curves produced by stellar pulsations, and we determined the wavelength-dependent variability of the planetary radius caused by the atmospheric absorption of stellar light. A simultaneous fit to the two transit light curves allowed us to refine the transit parameters, and the common wavelength coverage between the two transits served to contrast our results. Future observations with HST as well as other large ground-based facilities will be able to further constrain the atmospheric chemical composition of the planet.

Sign in / Sign up

Export Citation Format

Share Document