Analisis Karakteristik Pulp Campuran Tandan Kosong Kelapa Sawit dan Pelepah  Pisang dengan Pelarut NaOH

Tandan kosong kelapa sawit (TKKS) merupakan limbah padatan yang dihasilkan dari proses pembuatan minyak kelapa sawit yang selulosa (45,95%), kadar abu (1,23%), hemiselulosa (22,84%), kadar air (3,74%) dan lignin (16,49%). Pelepah pisang mempunyai kandungan selulosa yang tinggi akan tetapi belum dimanfaatkan secara optimal yang memiliki kandungan densitas ( 1,35 gr/cm3), selulosa (63 -64 %), hemiselulosa (20 %), lignin (5%), kekuatan Tarik rata-rata (600 Mpa), modulus tarik rata-rata (17,85 Gpa), pertambahan panjang (3,36 %), diameter serat (5,8 µm), serta panjang serat (30,9240 cm). Namun bahan-bahan ini mempunyai karakteristik dan sifat fisika kimia yang berbeda-beda. Karakteristik menjadikan perlunya analisa agar menghasilkan pulp yang diinginkan berada pada kondisi optimal. Beberapa parameter yang diukur di antaranya, konsentrasi larutan NaOH dengan variasi 7% dan 9%, dengan variasi bahan baku 40-60% serta waktu pemasakan dengan variasi waktu 75, 90, 105, 120 dan 135 menit. Sehingga pada penelitian ini didapatkan kondisi optimumnya yakni pada rasio 40:60, dengan konsentrasi 9% dan waktu pemasakan selama 120 menit didapatkan nilai kadar lignin 11,21% dan kadar selulosa 68,94%. Oil palm empty fruit bunches or TKKS are solid wastes produced from the process of making palm oil which are cellulose (45.95%), ash content (1.23%), hemicellulose (22.84%), water content (3.74 %) and lignin (16.49%). Banana midrib has a high cellulose content but has not been used optimally which contains density (1.35 g/cm3), cellulose (63 -64 %), hemicellulose (20 %), lignin (5%), average tensile strength. average (600 Mpa), average tensile modulus (17.85 Gpa), increase in length (3.36%), fiber diameter (5.8 m), and fiber length (30,9240 cm). However, these materials have different physicochemical characteristics and properties. The characteristics make the need for analysis in order to produce the desired pulp in optimal conditions. Several parameters were measured including the concentration of NaOH solution with variations of 7% and 9%, with variations of raw materials 40-60% and cooking time with variations of 75, 90, 105, 120 and 135 minutes. So that in this study the optimum conditions were obtained, namely at a ratio of 40:60, with a concentration of 9% and cooking time for 120 minutes, the lignin content was 11.21% and the cellulose content was 68.94%.

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Comparative transcriptome analysis of Pteroceltis tatarinowii Maxim., an endemic fiber tree

Bangladesh Journal of Botany ◽

10.3329/bjb.v48i3.47916 ◽

2019 ◽

Vol 48 (3) ◽

pp. 547-557

Author(s):

Hui-Jin Liu ◽

Li Zhang ◽

Yan-Nian Xu ◽

Xiao-Ping Zhang ◽

Xiao-Hong Li

Keyword(s):

Protein Gene ◽

Raw Materials ◽

Lignin Content ◽

Hierarchical Cluster ◽

Raw Material ◽

Limiting Factor ◽

Cellulose Content ◽

Three Samples ◽

Phenylpropanoid Biosynthesis ◽

Significant Expression

The bark of Pteroceltis tatarinowii Maxim., an endemic tree in Ulmaceae, is the main raw material for manufacturing Xuan Paper which is widely used in calligraphy and painting field. The characteristics of P. tatarinowii bark is the main limiting factor for the quality of Xuan Paper specially the content of cellulose and lignin. The molecular basis related to cellulose and lignin synthesis in P. tatarinowii would be helpful to understand and seek higher quality raw materials for Xuan Paper. RNA-seq was utilized to reveal transcriptome differences in P. tatarinowii from three far isolated localities (AL, JX and XA) under different climate environments. A total of 290 million reads were generated for further analysis in three libraries. In total, 2,850, 2,038 and 1,986 DEGs were identified in XA, JX and AL, respectively. Compared with the sample from XA, there were 822 up-regulated and 1706 down-regulated in AL sample. AL sample has 611 up-regulated genes and 647 down-regulated genes in comparison with JX sample. Comparing XA and JX samples, 443 were up-regulated and 1,783 were down-regulated in XA. Three samples had similar GO enrichment patterns. There were 19 and 9 genes identified as CESA and CSL (E-value less than 1.0E-20), respectively. Although no significant expression differences were found in three samples, KOB1, GPI-anchored protein gene and CTL1 were differently expressed, and KOB1 and GPI-anchored protein gene were up-regulated in JX. A number of the unigenes (474) that were involved in ‘phenylpropanoid biosynthesis’, were mostly not differently expressed. Only a few genes annotated as PAL, 4CL, C4H and CAD were significantly different in expression. In AL, 3 CAD and 1 PAL were up-regulated, whereas 6 CAD, 3 4CL and 1 HCT were up-regulated in XA, and 1 PAL, 2 4CL, 2 C4H in JX. JX sample had the highest cellulose content and XA sample had the highest lignin content, which being consistent with the hierarchical cluster analysis of differently expressed genes. Differences in the expression of these genes might influence the cellulose and lignin content.

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PEMBUATAN PULP DENGAN MEMANFAATKAN LIMBAH KULIT DURIAN (DURIO ZIBETHINUS MURR) DENGAN CAMPURAN (RESINA COLOPHONIUM) GUNA MENCEGAH DEGRADASI LINGKUNGAN

GEMA TEKNOLOGI ◽

10.14710/gt.v17i3.8925 ◽

2015 ◽

Vol 17 (3) ◽

Author(s):

Deddy Kurniawan W Kurniawan W ◽

Fahmi Arifan ◽

M. Dwi Khoirun Adim

Keyword(s):

Lignin Content ◽

Starch Content ◽

Thick Wall ◽

Cellulose Content ◽

Durio Zibethinus ◽

A Value ◽

Yield Value ◽

Term Basis ◽

High Cellulose

Deddy Kurniawan W, Fahmi Arifan, M. Dwi Khoirun Adim, in this article explain that paper is one of the primary needs for humans today . High paper usage is resulting increased in production of paper . On the other hand, paper which are usually made from cellulose and hemi-cellulose in wood can result environmental degradation , due to the use of wood and tree felling leads to long-term basis that can increase the temperature of the earth surface ( global warming) . Durian is relatively abundant in Indonesia , durian shell contains high cellulose ( 50-60 % ) and lignin content ( 5 %), also a low starch content ( 5 % ) . Durian shell wastes containing fibre with dimensions of length and fiber thick wall that be able to bind well when given a synthetic adhesive or an adhesive mineral . Pulp which is produced from durian shell waste in experiments were 1 , 2 , 3 and 4, have a value of α - cellulose content of 35 % , 45 % , 27.7 % , 37.5 % and 57.6 %, respectively. When yield value of 49.2 % , 66.8 % and 48.2 % respectively. Keywords: pulp, durian, gondorukem, digester

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Water Prehydrolysis of Moso Bamboo Dissolving Pulp

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.750-752.1586 ◽

2013 ◽

Vol 750-752 ◽

pp. 1586-1592

Author(s):

Tao Gu ◽

Li Qing Weng ◽

Guo Xin Xue

Keyword(s):

Retention Rate ◽

Dissolving Pulp ◽

Moso Bamboo ◽

Cellulose Content ◽

High Grade ◽

Single Factor ◽

Optimum Conditions ◽

Wood Material ◽

Factor Method ◽

High Cellulose

The chemical comcomposition and water prehydrolysis of moso bamboo were studied to prepare high grade dissolving pulp. The results indicated that the moso bamboo was an appropriate none-wood material for great dissolving pulp goten as its high cellulose content. By single factor method, the optimum prehydrolysis conditions which were 150°C, 120minutes and 1:8 of liquor-to-wood tatio, were obtained. Based on the optimum conditions, the yield was 90.35%, and the retention rate of cellulose, pentosan, acid accumulator insoluble lignin, and ash were respectively 96.30%, 88.22%, 88.13%, and 11.71%.

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Kemampuan jamur pelapuk kayu isolat JPA dan Trichoderma Sp. S2-2 dalam mendegradasi tandan kosong kelapa sawit untuk menghasilkan selulosa The capability of wood rot fungus JPA isolate and Trichoderma sp. S2-2 in degradation of oil palm empty fruit bunches to produce cellulose

E-Journal Menara Perkebunan ◽

10.22302/iribb.jur.mp.v82i2.17 ◽

2016 ◽

Vol 82 (2) ◽

Author(s):

. ALHIDAYATULLAH ◽

Lisdar I SUDIRMAN1 ◽

Okky Setyawati DHARMAPUTRA

Keyword(s):

Palm Oil ◽

Oil Palm ◽

Trichoderma Harzianum ◽

Raw Materials ◽

Value Added ◽

Cellulose Content ◽

Empty Fruit Bunches ◽

Oil Processing ◽

Trichoderma Sp ◽

Value Added Products

Abstract Oil palm empty fruit bunches (OPEFB) are the ligno-cellulosic wastes from palm oil processing. They can be used to produce raw materials for value-added products. The purpose of this study was to determine the degradation capacity of JPA wood rot fungi and Trichoderma sp. S2-2 on OPEFB. The 500 g of substrates consisted of 81% of OPEFB, 15% bran, 1.5% lime and 1.5% gypsum were used for growing. The substrates were inoculated with five treatments i.e without isolate (K); with JPA isolate (JPA); with Trichoderma sp. S2-2 (T); with the two isolates (JPA + T); and with JPA isolate and after four weeks of incubation inoculated with Trichoderma sp. S2-2 [(JPA)+T]. All treatments were incubated for eight weeks. The results showed that JPA+T was the best treatment which the two isolates must be inoculated simultaneously for degradation of OPEFB. Lignin and cellulose content on JPA+T treatment respectively were 20.83% and 33.77%. C/N ratio of OPEFB degraded with JPA+T was lower than the C/N ratio of TKKS degraded with Trichoderma harzianum and TKKS degraded with EM4 in previous study. AbstrakTandan kosong kelapa sawit (TKKS) merupakan limbah lignoselulosa dari pengolahan minyak kelapa sawit. TKKS dapat dimanfaatkan untuk memperoleh bahan baku untuk produk bernilai tambah. Tujuan penelitian ini adalah untuk mengetahui kemampuan degradasi jamur pelapuk kayu isolat JPA dan Trichoderma sp. S2-2 pada TKKS. Sebanyak 500 g substrat terdiri dari 81% TKKS, 15% dedak, 1,5% kapur, dan 1,5% gypsum digunakan untuk per-tumbuhan. Substrat diinokulasi dengan lima perlakuan yaitu tanpa isolat (K); dengan isolat JPA (JPA); dengan Trichoderma sp. S2-2 (T); dengan isolat JPA dan setelah empat minggu inkubasi, diinokulasi dengan Trichoderma sp. S2-2 [(JPA+T)]. Semua perlakuan diinkubasi selama delapan minggu. Hasil percobaan menunjukkan bahwa perlakuan JPA+T adalah perlakuan terbaik yaitu kedua isolat tesebut harus diinokulasi secara bersamaan untuk mendegradasi TKKS. Kandungan lignin dan selulosa TKKS dengan perlakuan JPA+T masing-masing adalah 20,83% dan 33,77%. Rasio C/N TKKS hasil degradasi dengan JPA+T lebih rendah daripada rasio C/N pada TKKS yang didegradasi dengan Trichoderma harzianum dan TKKS yang didegradasi dengan EM4 pada penelitian sebelumnya.

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A Comparative Study of Microcrystalline Cellulose Isolated from the Pod Husk and Stalk of Fluted Pumpkin

Chemical Science International Journal ◽

10.9734/csji/2018/v25i430074 ◽

2019 ◽

pp. 1-11

Author(s):

C. C. Nwajiobi ◽

J. O. E. Otaigbe ◽

O. Oriji

Keyword(s):

Physicochemical Properties ◽

Microcrystalline Cellulose ◽

Lignin Content ◽

Cellulose Derivatives ◽

Cellulose Content ◽

Alternative Source ◽

Fluted Pumpkin ◽

Hydrolysis Of ◽

High Lignin Content ◽

High Cellulose

Microcrystalline celluloses (MCC) were prepared from α-celluloses obtained from fluted pumpkin stalk and pod. The substrates were subjected to treatment with 2% (w/v) NaOH, 3.5% (w/v) NaOCl and 17.5% (w/v) NaOH solutions respectively to obtain alpha celluloses. Acid hydrolysis of the alpha-celluloses using 2.5 N hydrochloric acid were carried out. The study evaluates and compares the physicochemical properties of microcrystalline cellulose obtained from the pod and stalk of fluted pumpkin. Composition of cellulose, hemicellulose and lignin were also determined. Results showed cellulose; hemicellulose and lignin content of the pod husk and stalk were 49%, 26%, 9% and 41%, 24%, 26%, respectively. The morphology of the hydrolyzed MCCs’ were investigated using scanning electron microscopy (SEM) and the results revealed the stalk (FS-MCC) to have an individual rod-like shaped fiber when compared with flat-shaped large aggregated forms of the pod (FP-MCC). The particles sizes were also uneven with FP-MCC (6.689 µm) having larger particle sizes than FS-MCC (5.538 µm). The high cellulose content of the pod husk shows that the applications may be extended in the production of other cellulose derivatives while the high lignin content of the stalk reveals other alternative source of producing lignin in the making of textile dyes, coating and other agricultural chemical. Pod MCC (FP-MCC) had better physicochemical properties than the stalk MCC (FS-MCC).

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Characteristic of Microcrystalline Cellulose from Red Seaweed Eucheuma cottonii

Jurnal Pengolahan Hasil Perikanan Indonesia ◽

10.17844/jphpi.v22i3.28946 ◽

2019 ◽

Vol 22 (3) ◽

pp. 483-489

Author(s):

Edison Edison ◽

Andarini Diharmi ◽

Ela Davera Sari

Keyword(s):

Pharmaceutical Industry ◽

Microcrystalline Cellulose ◽

Raw Materials ◽

Ash Content ◽

Chemical Compositions ◽

Cellulose Content ◽

Red Seaweed ◽

High Cellulose ◽

Hcl Solution ◽

Eucheuma Cottonii

Microcrystalline Cellulose (MCC) is a modified of cellulose widely used as an additive in food and pharmaceutical industry. MCC is used in the pharmaceutical field as an excipient compound in the manufacture of tablets. Raw materials for MCC are of high cellulose content, such as Eucheuma cottonii seaweed. This study was aimed to determine the characteristics of MCC from seaweed E. cottonii. The MCC was obtained by hydrolyzing of α-cellulose from seaweed E. cottonii using HCl solution with three different concentrations: 2, 2.5 and 3 N. The chemical compositions (water, ash, protein, lipid, and carbohydrate) of red seaweed flour were determined. The moisture, ash, sensory, yield, and pH of the MCC were also analysed. The results showed that E. cottonii seaweed flour had moisture, protein, fat, ash, and carbohydrate content 3.88%, 0.85%, 2.4%, 3.44%, and 89.4% respectively. HCl concentrations had a significant effect on the moisture and ash content. The MCC had a yield of 35.8-38.00%, pH 5.73-6.82, moisture content 4.09.6, ash 0.94-4.90%. The characteristics of the MCC was in accordance with the standards of the British Pharmacopeia except the ash content.

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Pengaruh Penggunaan Effective Microorganism 4 (EM4) Pada Budidaya Jamur Merang (Volvariella volvaceae) Menggunakan Media Tandan Kosong Kelapa Sawit.

JURNAL BIOLOGI UNAND ◽

10.25077/jbioua.7.1.59-68.2019 ◽

2019 ◽

Vol 7 (1) ◽

pp. 59 ◽

Cited By ~ 1

Author(s):

Andriyanto Andriyanto ◽

Retni S Budiarti ◽

Agus Subagyo

Keyword(s):

Palm Oil ◽

Cellulose Content ◽

Processing Industry ◽

Mushroom Production ◽

Empty Fruit Bunches ◽

Oil Processing ◽

The World ◽

High Cellulose ◽

Effective Microorganism

Indonesia is the biggest producer of palm oil in the world. Palm oil empty fruit bunches is the biggest waste generated by the palm oil processing industry. However, utilization of the palm oil empty bunches has been not optimal. The palm oil empty fruit bunches have potential to be developed into a medium for growing mushroom because it has a high cellulose content. However, the high content of cellulose and lignin in palm oil empty fruit bunches is difficult to decompose into organic material that need for mushroom growth. The composting processes of empty fruit bunches can be increased by using Effective Microorganism (EM4). This study aims to understanding the role of Effective Microorganism 4 (EM4) on Volvariella volvaceae cultivation processes that used Empty Fruit Bunches compost. This research was conducted by composted the empty fruit bunch with different concentration of EM-4 there are 0%, 10%, 15%, 20% and 25%. Parameters observed were number of mushrooms, weight of mushrooms and C / N ratio of compost. The results showed that EM-4 had reduce C/N ratio of empty bunch palm oil compost, C/N ratio was not affected mushroom production and EM4 was affected mushroom production, the highest production reached by concentration of 15% that had not significant with concentration of 5%, 10% and 20%. At concentration of 25% mushroom production was decreased. It is probably there are several mechanisms by EM4 microorganisms containing that affected mushrooms production.

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HIDROLISIS HASIL DELIGNIFIKASI TANDAN KOSONG KELAPA SAWIT DALAM SISTEM CAIRAN IONIK CHOLINE CHLORIDE

Jurnal Teknik Kimia USU ◽

10.32734/jtk.v5i1.1521 ◽

2016 ◽

Vol 5 (1) ◽

pp. 27-33

Author(s):

Gendish Yoricya ◽

Shinta Aisyah Putri Dalimunthe ◽

Renita Manurung ◽

Nimpan Bangun

Keyword(s):

Ionic Liquid ◽

Ionic Liquids ◽

Reaction Time ◽

Choline Chloride ◽

Liquid System ◽

Cooking Time ◽

Raw Material ◽

Cellulose Content ◽

Empty Fruit Bunches ◽

Hydrolysis Conditions

Palm Empty Fruit Bunches (TKKS) was the waste which has a fairly high content of lignocelluloses. Meanwhile, TKKS has not been utilize optimally. With a cellulose content of 45%-50%, TKKS then potentially be used as raw material for bioethanol. In the process of production bioethanol, delignification of lignocellulose the first phase was conducted to dissolve ligament between cellulose, hemicellulose and lignin. In this research, delignification process was carried out using NaOH in the ionic liquid system and without ionic liquids. The purpose of this research was to find out the highest content of cellulose which contained in the TKKS and to determine the hydrolysis of delignification results on palm empty fruit bunches and the best hydrolysis conditions was obtained at the hydrolysis process in the choline chloride ionic liquid system. Delignification process were performed using ionic liquids choline chloride (ChCl) in variety of cooking time with amount different ChCl. This research used TKKS powder cooked at a temperature 130 °C with a variety of cooking time 30, 60, and 90 minutes and the variation of ChCl 10%, 15% and 20% weight of TKKS. Delignification research results used ChCl obtained highest content of cellulose was 40,33%, hemicellulose 20,28%, and lignin 3,62% in cooking treatment 90 minutes and 15% ChCl. While delignification without ChCl obtained highest content of cellulose is 24,98%, hemicellulose 8,25%, and lignin 18,99% in cooking treatment 90 minutes. Delignification process using ChCl be able increase the degree of delignification as big as 61,45%. In the hydrolisis process, the main raw material used cellulose of delignification TKKS result, choline chloride, sulfatl acid, and distilled water. The hydrolysis stage in this research was carried out at temperature 105 0C, catalyst (H2SO4) 10% (w / w) cellulose, ChCl 10%, 15%, and 20% (w / w) cellulose and it was stirred at constant speed 120 rpm with reaction time of 30, 60 and 90 minutes. The result in the hydrolysis stage using ionic liquid obtained glucose. LUFF method analysis showed the maximum result of glucose 37.96% with the best conditions in reaction time 90 minutes and the amount of choline chloride 20%.

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Optimization of synthesis conditions for carboxymethyl cellulose from pineapple leaf waste using microwave-assisted heating and its application as a food thickener

BioResources ◽

10.15376/16.4.7684-7701 ◽

2021 ◽

Vol 16 (4) ◽

pp. 7684-7701

Author(s):

Noppadol Panchan ◽

Pattra Wattanapan ◽

Sirada Sungsinchai ◽

Supacharee Roddecha ◽

Peerapan Dittanet ◽

...

Keyword(s):

Optimal Condition ◽

Carboxymethyl Cellulose ◽

Cellulose Content ◽

Box Behnken Design ◽

Synthesis Conditions ◽

Naoh Solution ◽

Food Thickener ◽

High Degree ◽

Pineapple Leaves ◽

High Cellulose

Pineapple leaf waste, with its high cellulose content, can serve as alternative starting material for the production of carboxymethyl cellulose (CMC). In this study, synthesis conditions of CMC from pineapple leaves via the use of microwave heating were optimized. Box-Behnken design and response surface methodology were applied to schedule the experiments and to optimize the synthesis condition, respectively. Preparation of CMC was investigated by varying three factors, namely, sodium hydroxide (NaOH) concentration, monochloroacetic acid (MCA) dose, and etherification time. The process of carboxymethylation was optimized to produce CMC with high degree of substitution (DS). Optimal condition for CMC synthesis was noted to be 50% (w/v) NaOH solution, 8 g of MCA/g cellulose, and etherification time of 16 min; such optimal condition resulted in the maximum DS of 0.78. Synthesized CMC was utilized as a thickener for liquid foods (water, orange juice, milk, and mushroom cream soup) where 2% (w/v) as-synthesized CMC increased the viscosity of the foods and changed their characteristics from thin to nectar-like liquids.

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Combined Pretreatment as an Effective Technology in Breaking of Phenolic Polymer Lignin from Sustainable Biomass: Bambusa balcooa

10.20944/preprints202105.0656.v1 ◽

2021 ◽

Author(s):

heena Parveen ◽

Lakshmi Tewari ◽

Diwas Pradhan ◽

Parul Chaudhary

Keyword(s):

Structural Changes ◽

Lignin Content ◽

Biomass Conversion ◽

Cellulose Content ◽

Fungal Culture ◽

Biomass Structure ◽

Hydrolysis Process ◽

Combined Pretreatment ◽

Phenolic Polymer ◽

High Cellulose

Bamboo biomass is a potential source for the production of monomeric sugars containing high cellulose content with low amount of lignin. However, for efficient hydrolysis, the biomass treatment by effective pretreatment technique is required to minimize lignin content and other barrier components. During present study, the bamboo biomass was treated with different physical, chemical, biological and combined treatments to reduce the lignin content. Among all the pretreatments, the maximum lignin removal (14.5%) was obtained with the combined chemical and biological treatment under 2% NaOH+1% H2O2 +WDP2 fungal culture (5 plugs) conditions. In addition, lignolytic fungus and NaOH pretreatment was mainly effective in removing lignin, whereas the H2O2 pretreatment efficiently minimize cellulose crystallinity. To analyze structural changes of raw and treated biomass, we used scanning electron microscopy and fourier transform infrared spectroscopy. The structural analysis indicated that all treatments causes disruption in the biomass structure and loses the compactness of the biomass which facilitates the biomass conversion during hydrolysis process. The findings of the present study indicate effective pretreatment methods in breaching the recalcitrancy of the potential lignocellulosic biomass for maximum hydrolysis.

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