The Watershed Tungsten Deposit, Northeast Queensland, Australia: Permian Metamorphic Tungsten Mineralization Overprinting Carboniferous Magmatic Tungsten

2020 ◽  
Author(s):  
Jaime A. Poblete ◽  
Paul H.G.M. Dirks ◽  
Zhaoshan Chang ◽  
Jan Marten Huizenga ◽  
Martin Griessmann ◽  
...  

Abstract The Watershed tungsten deposit (49.2 Mt avg 0.14% WO3) lies within the Mossman orogen, which comprises deformed Silurian-Ordovician metasedimentary rocks of the Hodgkinson Formation intruded by Carboniferous-Permian granites of the Kennedy Igneous Association. The Hodgkinson Formation in the Watershed area comprises skarn-altered conglomerate, psammite, and slate units that record four deformation events evolving from ductile, isoclinal, colinear folding with transposition (D1–D3) to brittle ductile shear zones (D4). Multiple felsic to intermediate dikes cut across the metasedimentary rocks at Watershed including: (1) Carboniferous, monzonite dikes (zircon U/Pb age of 350 ± 7 Ma) emplaced during D1–2; and (2) Permian granite plutons and dikes (zircon U/Pb ages of 291 ± 6, 277 ± 6, and 274 ± 6 Ma) and diorite (zircon U/Pb age of 281 ± 5 Ma) emplaced during D4. Tungsten mineralization is largely restricted to skarn-altered conglomerate, which preserves a peak metamorphic mineralogy formed during ductile deformation and comprises garnet (Grt40–87 Alm0–35Sps1–25Adr0–16), actinolite, quartz, clinopyroxene (Di36–59Hd39–61Jhn1–5), and titanite. A first mineralization event corresponds to the crystallization of disseminated scheelite in monzonite dikes (pre-D3) and adjacent units, with scheelite grains aligned in the S1–2 fabric and affected by D3 folding. This event enriched the Hodgkinson Formation in tungsten. The bulk of the scheelite mineralization formed during a second event and is concentrated in multistaged, shear-related, quartz-oligoclase-bearing veins and vein halos (muscovite 40Ar-39Ar weighted average age of 276 ± 6 Ma), which were emplaced during D4. The multistage veins developed preferentially in competent, skarn-altered conglomerate units and formed synchronous with four retrograde alteration stages. The retrograde skarn minerals include clinozoisite after garnet, quartz, plagioclase, scheelite, and phlogopite with minor sodium-rich amphibole, which formed during retrograde stages 1 and 2, accompanied by later muscovite, calcite, and chlorite formed during retrograde stage 3. Retrograde stage 4 was a late-tectonic, noneconomic sulfide stage. The principal controls on scheelite mineralization at Watershed were the following: (1) early monzonite dikes enriched in scheelite; (2) D4 shear zones that acted as fluid conduits transporting tungsten from source areas to traps; (3) skarn-altered conglomerate lenses that provide a competent host to facilitate vein formation and a source for calcium to form scheelite; and (4) an extensional depositional environment characterized by vein formation and normal faulting, which provide trapping structures for tungsten-bearing fluids, with decompression being a likely control on scheelite deposition. The coexistence of scheelite with oligoclase in monzonite dikes and veins suggests that tungsten was transported as NaHWO40. Exploration in the area should target Carboniferous monzonite, associated with later syn-D4 shear zones cutting skarn-altered conglomerate.

2018 ◽  
Vol 14 (18) ◽  
pp. 305
Author(s):  
Daï Bi Seydou Mathurin ◽  
Ouattara Gbele ◽  
Koffi Gnammytchet Barthélémy ◽  
Gnanzou Allou ◽  
Coulibaly Inza

The lithological and structural observations of the region of Brobo (Central Côte d'Ivoire) indicate a succession of metasedimentary rocks (micaschists with cordierite, silstones, graphitic sediments, sandstones with amphibole-garnet, etc.) intermixed with volcanic rocks (rhyolite, dacite, andesite, basalt and the volcanoclastics). The whole is intruded by granites with one or two micas, sometimes porphyries, granodiorites, gabbros, and granite gneisses. Interpretations of Landsat ETM+ , RadarSat-1 and SRTM remote sensing imageries, as well as field data, revealed several lineament directions which, after field control, correspond to major faults and shear zones. These large structures show the N-S, NE-SW, NNE-SSW, E-W, NWSE, and NNW-SSE orientations. The field data also made it possible to describe several structures and to propose a preliminary geodynamic model for the setting and structuring of the formations of this region. This model suggests that the geodynamic took place in three stages: distension with a deformation of basement formations generating a gneissocity (D1), as well as deposits of sediments in the basins; followed by a NW-SE to E-W convergence generating a cleavage in the volcanogenic series (D2). This phase of deformation continues while creating, locally, a strain slip cleavage or a transposed schistosity. The third cleavage affects the volcanogenic series (fractures cleavages, D3) and ends in large corridors of ductile shear zones and associated faults.


2021 ◽  
Author(s):  
Carolyn Tewksbury-Christle ◽  
Alissa Kotowski ◽  
Whitney Behr

<p>The strength, or viscosity, of the subduction interface is a key parameter in subduction dynamics, influencing both long-term subduction plate speeds and short-term transient deformation styles. Fossil subduction interfaces exhumed from downdip of the megathrust record ductile deformation accommodated by diverse lithologies, including metasedimentary and metamafic rocks. Existing flow laws for quartz-rich rocks predict relatively low viscosities, in contrast to high viscosities predicted for basalt and eclogite, but the rheological properties of blueschists representative of metamorphosed oceanic crust of the down-going slab are poorly constrained. Two key questions remain: 1) are there significant viscosity contrasts between blueschists and quartz- or mica-rich metasedimentary rocks, and 2) what are the microscale mechanisms for creep in naturally deformed blueschists and how do they vary with pressure and temperature? To address these questions, we characterized deformation in natural samples from the Condrey Mountain Schist (CMS) in northern California, USA, and the Cycladic Blueschist Unit (CBU) on Syros Island, Cyclades, Greece, using outcrop-scale structural observations, optical microscopy, and Electron Backscatter Diffraction. The CMS and CBU record pressure-temperature conditions of 0.8-1.1 GPa, 350-450°C and 1.4-1.8 GPa, 450-550°C, respectively. </p><p>In the field, blueschists form m- to km-scale lenses that are interfolded with quartz schists, ultramafics, and, in the CBU, eclogites and marbles. At the outcrop scale in both localities, quartz-rich schists and blueschists each exhibit strong foliations and lineations and planar contacts at lithological boundaries. At the thin section scale, the prograde foliation and mineral lineation in blueschists are commonly defined by Na-amphiboles elongated in the lineation direction. Crystallographic preferred orientations in Na-amphibole in all samples have c-axes parallel to lineation and a-axes predominantly defining point-maxima perpendicular to the foliation, suggesting some component of dislocation activity for all temperature conditions in our sample suite. Microtextures in lower temperature CMS samples suggest strain accommodation primarily by dislocation glide and kinking in Na-amphibole, with extremely high-aspect-ratio grains and limited evidence for climb-controlled dynamic recrystallization. Some higher temperature CBU samples show large porphyroclasts with apparent ‘core-and-mantle’-type recrystallization textures and subgrain orientation analyses consistent with the (hk0)[001] slip systems. In contrast, epidote grains accommodate less strain than Na-amphibole, via some combination of rigid rotation, brittle boudinage, and minor intracrystalline plasticity.</p><p>Observations of evenly-distributed strain, despite lithological heterogeneity, suggest low viscosity contrasts and comparable bulk strengths of quartz schists and blueschists. Our microstructural observations suggest that Na-amphibole was the weakest phase and accommodated the majority of strain in mafic blueschists. Dislocation activity, and not just rigid-body-rotation or diffusional processes, accommodated some component of strain and possibly transitioned with increasing temperature from glide- to climb-controlled. Although effective viscosities appear to be similar, subduction interface shear zones dominated by blueschists may exhibit a power-law rheology consistent with dislocation activity, in contrast to the common inference of Newtonian creep in metasediments. Complementary experimental work on CMS and CBU rocks will also be presented at this meeting (see Tokle et al. and Hufford et al.).</p>


2020 ◽  
Vol 50 (1) ◽  
pp. 27-81 ◽  
Author(s):  
Stefan Bergman ◽  
Pär Weihed

AbstractTwo lithotectonic units (the Norrbotten and Överkalix units) occur inside the Paleoproterozoic (2.0–1.8 Ga) Svecokarelian orogen in northernmost Sweden. Archean (2.8–2.6 Ga and possibly older) basement, affected by a relict Neoarchean tectonometamorphic event, and early Paleoproterozoic (2.5–2.0 Ga) cover rocks constitute the pre-orogenic components in the orogen that are unique in Sweden. Siliciclastic sedimentary rocks, predominantly felsic volcanic rocks, and both spatially and temporally linked intrusive rock suites, deposited and emplaced at 1.9–1.8 Ga, form the syn-orogenic component. These magmatic suites evolved from magnesian and calc-alkaline to alkali–calcic compositions to ferroan and alkali–calcic varieties in a subduction-related tectonic setting. Apatite–Fe oxide, including the world's two largest underground Fe ore mines (Kiruna and Malmberget), skarn-related Fe oxide, base metal sulphide, and epigenetic Cu–Au and Au deposits occur in the Norrbotten lithotectonic unit. Low- to medium-pressure and variable temperature metamorphic conditions and polyphase Svecokarelian ductile deformation prevailed. The general northwesterly or north-northeasterly structural grain is controlled by ductile shear zones. The Paleotectonic evolution after the Neoarchean involved three stages: (1) intracratonic rifting prior to 2.0 Ga; (2) tectonic juxtaposition of the lithotectonic units during crustal shortening prior to 1.89 Ga; and (3) accretionary tectonic evolution along an active continental margin at 1.9–1.8 Ga.


2020 ◽  
Author(s):  
Christoph Schrank

<p>About 50 years ago, John Ramsay and colleagues established the thorough foundation for the field-scale observational and mathematical description of the structures, deformation, and kinematics in ductile shear zones. Since then, these probably most important instabilities of the ductile lithosphere enjoyed an almost explosive growth in scientific attention. It is perhaps fair to say that this tremendous research effort featured four main themes:</p><p> </p><p>[1] The historic scientific nucleus – quantification of shear-zone geometry, strain and associated kinematic history from field observations</p><p> </p><p>[2] Qualitative and quantitative analysis of microphysical deformation mechanisms in the field and the laboratory</p><p> </p><p>[3] Shear-zone rheology</p><p> </p><p>[4] The development of physically consistent mathematical models for shear zones, mainly using continuum mechanics.</p><p> </p><p>In concert, these four cornerstones of shear-zone research enabled tremendous progress in our understanding of why and how ductile shear zones form. So, what are some of the outstanding problems?</p><p> </p><p>A truly comprehensive model for ductile shear zones must account for the vast range of length and time scales involved, each easily covering ten orders of magnitude, as well as the associated intimate coupling between thermal, hydraulic, mechanical, and chemical processes. The multi-scale and multi-physics nature of ductile shear zones generates scientific challenges for all four research themes named above. This presentation is dedicated to highlighting exciting challenges in themes 2, and 3 and 4.</p><p> </p><p>In the microanalytical arena [2], the nano-scale is an exciting new frontier, especially when it comes to the interplay between metamorphism and ductile deformation. The nano-frontier can be tackled with new synchrotron methods. I showcase some applications to fossil shear-zone samples and discuss opportunities for in-situ experiments. In the domain of rheology [3], I present some simple experiments with strain-softening materials and field observations that support the notion: transient rheological behaviour is very important for shear localisation. In the modelling domain [4], some recent examples for the intriguing physical consequences predicted by new multi-physics and cross-scale coupling terms in ductile localisation problems are illustrated.</p>


1994 ◽  
Vol 162 ◽  
pp. 53-70
Author(s):  
B Chadwick ◽  
C.R.L Friend

Mid-crustal deformation of an Early Proterozoic high-grade gneiss complex in western Dove Bugt gave rise to at least two sets of nappes. Structures in mylonites in low-angle ductile shear zones associated with the younger nappes indicate north-easterly-directed displacements. The nappes and mylonites are folded by upright to inclined folds that verge north-west and which appear to be associated with decollements that dip south-east. Hornblende, sillimanite and anatectic partial melts that developed with the nappes, mylonites and younger folds show that deformation took place under amphibolite facies conditions. Several lines of evidence suggest that the younger nappes, the mylonites and the upright to inclined folds formed during the Caledonian orogeny. Some pre-Caledonian deformation may be represented by the oldest isoclinal folds. Numerous, small-scale, ductile extensional shear zones and more brittIe fractures that were superimposed across the Caledonian structures are believed to have formed during orogen-parallel collapse which may be related IO Devonian basin development farther south in central East Greenland. Younger fauIts and major joints are correlated with Carboniferous, Mesozoic and Tertiary basin development in North-East Greenland.


2021 ◽  
Author(s):  
Richard Spiess ◽  
Antonio Langone ◽  
Alfredo Caggianelli ◽  
Finlay M. Stuart ◽  
Martina Zucchi ◽  
...  

<p>Exhumation and cooling of upper crustal plutons is generally assumed to develop in the brittle domain, thus determining an abrupt passage from crystallization to faulting. To challenge this general statement, we have applied an integrated approach involving meso- and micro-structural studies, thermochronology, geochronology and rheological modeling. We have analyzed the Miocene syn-tectonic Porto Azzurro pluton on Elba (Tuscan archipelago – Italy), emplaced in an extensional setting, and have realized that its fast exhumation is accompanied by localized ductile shear zones, developing along dykes and veins, later affected by brittle deformation. This is unequivocally highlighted by field studies and the analysis of microstructures with EBSD. In order to constrain the emplacement and exhumation rate of the Porto Azzurro pluton we performed U-Pb zircon dating and (U+Th)/He apatite thermochronology. It results in a magma emplacement age of 6.4 ± 0.4 Ma and an exhumation rate of 3.4 to 3.9 mm/yr. By thermo-rheological modeling we were able to establish that localized ductile deformation occurred at two different time steps: within felsic dykes when the pluton first entered into the brittle field at 380 kyr, and along quartz-rich hydrothermal veins at c. 550 kyr after pluton emplacement. Hence, the major conclusion of our data is that ductile deformation can affect a granitic intrusion even when it is entered into the brittle domain in a fast exhuming extensional regime.</p>


2020 ◽  
Vol 50 (1) ◽  
pp. 131-153 ◽  
Author(s):  
Karin Högdahl ◽  
Stefan Bergman

AbstractDuctile shear zones with dextral transpressive deformation separate the Ljusdal lithotectonic unit from the neighbouring units (Bothnia–Skellefteå and Bergslagen) in the 2.0–1.8 Ga Svecokarelian orogen. Sedimentation steered by regional crustal extension at c. 1.86–1.83 Ga was sandwiched between two separate phases of ductile strain with crustal shortening and predominantly high-grade metamorphism with plutonic activity. Metamorphism occurred under low-pressure, medium- to high-temperature conditions that locally reached granulite facies. The earlier shortening event resulted in the accretion of outboard sedimentary and c. 1.89 Ga volcanic rocks (formed in back- or inter-arc basin and volcanic arc settings, respectively) to a continental margin. Fabric development (D1), the earlier phase of low-pressure and variable temperature metamorphism (M1) and the intrusion of a predominantly granitic to granodioritic batholith with rather high εNd values (the Ljusdal batholith) occurred along this active margin at 1.87–1.84 Ga. Thrusting with westerly vergence, regional folding and ductile shearing (D2–3), the later phase of low-pressure and variable temperature metamorphism (M2), and the subsequent minor shear-related intrusion of granite, again with relatively high εNd values, prevailed at 1.83–1.80 Ga. Mineral deposits include epithermal Au–Cu deposits hosted by supracrustal rocks, V–Fe–Ti mineralization in subordinate gabbro and norite bodies inside the Ljusdal batholith, and graphite in metasedimentary rocks.


2001 ◽  
Vol 38 (5) ◽  
pp. 787-802
Author(s):  
L B Harris ◽  
B Rivard ◽  
L Corriveau

The Lac Nominingue – Mont-Laurier region of the Central Metasedimentary Belt, Grenville Province of Quebec, comprises the granulite-facies Bondy gneiss complex (core of the Bondy gneiss dome) and overlying Sourd group metasedimentary rocks. A metamorphic foliation – transposed compositional layering (S1; host to peak-pressure parageneses) has been folded by isoclinal folds (F2 and F3) crosscut by leucosomes that host peak-temperature assemblages. The orthopyroxene isograd cuts obliquely across F3 folds, indicating that 1.20–1.18 Ga granulite-facies metamorphism post-dated D3. D3 structures are cut by ductile shear zones and boudinaged in D4 and are folded by regional-scale, open, upright north–south folds (F5). Folds with shallowly dipping axial surfaces (F6) are subsequently developed in the Sourd group. F5 (and probably F6) developed prior to intrusion of the ca. 1165 Ma Chevreuil suite. In the Nominingue–Chénéville deformation zone (NCDZ) east of the Bondy gneiss dome, Chevreuil intrusions contain north-striking magmatic and tectonic foliations. These, along with host gneisses and metasedimentary rocks, are displaced by conjugate ductile shear zones (northeast dextral and south-southeast sinistral) and north-northeast-striking thrusts. Late open folds (F8) with east-northeast-striking axial surfaces produce dome and basin interference patterns. F2 to F5 folds may have formed during either subhorizontal, east–west contraction or east–west extension resulting from orogenic collapse or convective lithospheric thinning following crustal thickening during terrane assembly in the Elzevirian orogeny. Structures in the NCDZ imply ESE–WNW contraction and NNE–SSW (orogen-parallel) extension in D7 syn- to post-intrusion of the Chevreuil suite. F8 folds imply a late, Grenvillian SSE–NNW contraction.


2019 ◽  
Author(s):  
William O. Nachlas ◽  
◽  
Christian Teyssier ◽  
Donna L. Whitney ◽  
Greg Hirth

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