Geobiological features of storage hydrogen-methane mixtures in underground reservoirs
Taking into account the world and domestic experience of studying the ontogenesis of lithospheric hydrogen a combination of coupled hydrochemical, geochemical and microbiological factors of the accumulation of this natural gas together with methane in the terrigenous formations of the sedimentary cover is justified. It is predicted that various hydrochemical and microbiological processes that cause the development of carbon dioxide and sulfate corrosion of engineering structures, as well as cement of reservoir rocks and tires, can occur together with methane at industrial facilities of underground storage of hydrogen. The risks of reducing the volume of injected hydrogen in underground storage in addition to diffusion losses can be associated with geobiological factors, including the conversion of hydrogen into CH4 and H2S due to microbial activity, chemical interaction of hydrogen with minerals of reservoirs and tires, accompanied by changes in filtration-capacity and geomechanical properties, hydrogen embrittlement of metal structures of ground and underground well equipment. Keywords: geobiology; hydrogen; methane; underground storage; methanogenesis; acetogenesis; sulfate reduction.