Green Synthesis of Silver Nanoparticles by the Cyanobacteria Synechocystis sp.: Characterization, Antimicrobial and Diabetic Wound-Healing Actions

Green nanotechnology is now accepted as an environmentally friendly and cost-effective advance with various biomedical applications. The cyanobacterium Synechocystis sp. is a unicellular spherical cyanobacterium with photo- and hetero-trophic capabilities. This study investigates the ability of this cyanobacterial species to produce silver nanoparticles (AgNPs) and the wound-healing properties of the produced nanoparticles in diabetic animals. Methods: UV–visible and FT-IR spectroscopy and and electron microscopy techniques investigated AgNPs’ producibility by Synechocystis sp. when supplemented with silver ion source. The produced AgNPs were evaluated for their antimicrobial, anti-oxidative, anti-inflammatory, and diabetic wound healing along with their angiogenesis potential. Results: The cyanobacterium biosynthesized spherical AgNPs with a diameter range of 10 to 35 nm. The produced AgNPs exhibited wound-healing properties verified with increased contraction percentage, tensile strength and hydroxyproline level in incision diabetic wounded animals. AgNPs treatment decreased epithelialization period, amplified the wound closure percentage, and elevated collagen, hydroxyproline and hexosamine contents, which improved angiogenesis factors’ contents (HIF-1α, TGF-β1 and VEGF) in excision wound models. AgNPs intensified catalase (CAT), superoxide dismutase (SOD), and glutathione peroxidase (GPx) activities, and glutathione (GSH) and nitric oxide content and reduced malondialdehyde (MDA) level. IL-1β, IL-6, TNF-α, and NF-κB (the inflammatory mediators) were decreased with AgNPs’ topical application. Conclusion: Biosynthesized AgNPs via Synechocystis sp. exhibited antimicrobial, anti-oxidative, anti-inflammatory, and angiogenesis promoting effects in diabetic wounded animals.

Application of ASTER Data for Differentiating Carbonate Minerals and Evaluating MgO Content of Magnesite in the Jiao-Liao-Ji Belt, North China Craton

Numerous reports have successfully detected or differentiated carbonate minerals such as calcite and dolomite by using the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER). However, there is a need to determine whether existing methods can differentiate magnesite from other carbonate minerals. This study proposes optimal band ratio combinations and new thresholds to distinguish magnesite, dolomite, and calcite using ASTER shortwave-infrared (SWIR) data. These were determined based on the spectral and chemical analysis of rock samples collected from Liaoning, China and Danchon, North Korea and the reflectance values from ASTER images. The results demonstrated that the simultaneous use of thresholds 2.13 and 2.015 for relative absorption band depths (RBDs) of (6 + 8)/7 and (7 + 9)/8, respectively, was the most effective for magnesite differentiation. The use of RBDs and band ratios to discriminate between dolomite and calcite was sufficiently effective. However, talc, tremolite, clay, and their mixtures with dolomite and calcite, which are commonly found in the study area, hampered the classification. The assessment of the ASTER band ratios for magnesite grade according to magnesium oxide content indicated that a band ratio of 5/6 was the most effective for this purpose. Therefore, this study proved that ASTER SWIR data can be effectively utilized for the identification and grade assessment of magnesite on a regional scale.

Utilization of hazardous waste of black dross aluminum: processing and application-a review

Aluminum black dross is produced by the secondary smelting process of aluminum. Aluminum black dross is classified as hazardous waste because it is reactive with water and produces substances and gases that are harmful to humans and the environment. Generally, aluminum black dross is managed by landfill method, but because it is produced in large amounts every year, the aluminum black dross needs to be utilized to reduce the impact on the environment. Aluminum black dross consists of large amounts of metal oxide and salts. The amount of metal oxide content in aluminum black dross can be used as raw material. This paper review types of processes for utilizing black dross aluminum as raw material in value-added products. aluminum black dross can be used as alumina, adsorbent, zeolite, composites, geopolymers, refractories, and fillers. By utilizing aluminum black dross waste into various products that have economic value, besides being able to protect the environment, it can also reduce environmental resource use.

Effect of Aggregate Gradation and Filler Content on the Rutting Resistance of Modified Colored Hot Mix Asphalt

Rutting is considered as the most generated distress in Iraqi roads as a result of the high temperature and excessive traffic load. So, it is essential to utilize polymer modified binder to increase the performance of pavements. The objective of this paper is to assess the effect of aggregate gradation and filler content on the rutting formation of Colored Hot Mix Asphalt CHMA. The HMA was colored by using iron oxide as filler to produce red HMA. Two blends were used: fine and coarse with two different types of filler iron oxide for CHMA and limestone for conventional HMA with two filler content 6% and 10%. Neat (AC 40-50) and modified asphalt (AC 40-50 + 4%SBS) were used. Tests are held on adding 4% Styrene Butadiene Styrene )SBS( by the weight of neat asphalt (AC 40-50) to raise the performance grade by two grades from PG (64-16) to PG (76-16) [1] and [2]. The wheel tracking test is used to assess the rut depth of the CHMA. The test results showed that the using iron oxide with neat asphalt increase the rut depth resistance by 200 and 400 failure load cycles than mixtures using limestone (cycles that mix reach 25 mm rut depth) for fine and coarse mix respectively. Also, the effect of gradation shows that the fine mixture fails at 4000 cycles while the coarse mixture fails at 1800 cycles for 6% limestone mixtures. Increasing the iron oxide content from 6% to 10% leads to increase the failure load cycles by 2200 and 1200 cycles for fine and coarse mixture respectively using modified asphalt. The fine mixture with 10% iron oxide using modified asphalt gives the best performance with 7000 cycles than the coarse mixture with 10% filler content and modified asphalt with 4000 cycles. irrespective the filler and type of binder, the dense mixtures using iron oxide as filler exhibit better resistance to rutting formation than coarse mixtures.

Stability and Volumetric Properties of Colored Asphalt Mixtures Containing Iron Oxide

The objective of this paper is find the effect of using iron oxide as a filler on the Marshall stability, flow and the volumetric properties of HMA and compared the results with conventional HMA using limestone dust. Three blends were used: coarse, mid and fine with neat bitumen (AC 40-50). One aggregate type (crushed) with two types of fillers: limestone and iron oxide III (α- ) with three different filler content 6%, 8% and 10%. The Marshall mix design was conducted on the three blends and the optimum binder content is computed for each blend. The Marshall stability test results and the volumetric properties analysis showed that increasing the iron oxide content from 6% to 10% increases the stability about 28%, 17% , 16% for the coarse , mid and fine mixtures respectively. This increment in stability of mixtures using iron oxide related to the increment in specific gravity of the mix (Gmb) by (1.3% to 1.5% about 30 to 50 kg/m3). On the other hand, the flow of mixtures is decreased about (5%) for mixes using iron oxide than the ones that used limestone as filler. The fine blend with 10% iron oxide exhibit the highest stability of 13.3 kN. While the coarse blend stability was 10 kN for the same filler type and content. Generally, the Marshall Test results of HMA using iron oxide as filler showed better resistance to plastic deformation, also produce denser HMA with higher stiffness. On the other hand, the volumetric properties analysis showed lesser values as compared with conventional mixture where the void in mineral aggregates and void filled with asphalt has decreased but within the acceptable limits.

Effect of Ruthenium Oxide Content on the Electrochemical Characteristics of a Supercapacitor With a Carbon Black Electrode Formed by Electrophoretic Deposition

Controlling the ratio of capacitance and power of supercapacitors by changing the composition of the electrodes will allow to create optimal power systems for specific applications. For the formation of such electrodes, a method is required that combines the possibilities of creating a multicomponent composite with a high degree of uniformity of composition and morphology over the layer thickness. An example of such a method can be the eco-friendly method of electrophoretic deposition used in this work, which makes it possible to locally deposit a composite material from multicomponent suspensions at room temperature. We present an approach related to electrophoretic deposition from a suspension of composite material SuperC-RuO 2 , in which the ratio of the components can be changed to vary the proportion of electrochemical and electrical double layer storage. Nanocarbon, which has a large surface area, and ruthenium oxide with a significant electrochemical capacity, in combination, will allow combining high power and capacity in one device, and their ratio will determine the proportion of electrochemical and electrical double layer storage. In this work, approaches are investigated and recommendations are given for increasing the stability of suspensions, the effect of the composition of the suspension on the composition of composite electrodes and their capacitive and power characteristics is determined.

Influence of Aluminum and Molybdenum on the Microstructure and Corrosion Behavior of Thermally Sprayed High-Entropy Alloy Coatings

High-entropy alloys (HEAs) have shown a wide range of promising structural and functional properties. By the application of coating technology, an economical exploitation can be achieved. The high wear and corrosion resistance of HEAs make them particularly interesting for the application as protective coatings. Especially for alloys with a high chromium content, a high corrosion resistance has been revealed. For the current investigations, the equimolar HEA CrFeCoNi with a single-phase face centered cubic structure is considered as a base alloy system. To increase the corrosion resistance as well as the hardness and strength, the influence of the alloying elements aluminum and molybdenum is analyzed. For the current investigations, the high kinetic process high-velocity oxygen fuel thermal spraying (HVOF) has been considered to produce coatings with a low porosity and oxide content. Feedstock is produced by inert gas atomization. The influence of the alloy composition on the microstructure, phase formation and resulting property profile is studied in detail. A detailed analysis of the corrosion resistance and underlying mechanisms is conducted. The pitting and passivation behavior are investigated by potentiodynamic polarization measurements in NaCl and H2SO4 electrolyte. A distinct improvement of the corrosion resistance can be achieved for the alloy Al0.3CrFeCoNiMo0.2.

The Effect of Argon as Atomization Gas on the Microstructure, Machine Hammer Peening Post-Treatment, and Corrosion Behavior of Twin Wire Arc Sprayed (TWAS) ZnAl4 Coatings

In the twin wire arc spraying (TWAS) process, it is common to use compressed air as atomizing gas. Nitrogen or argon also are used to reduce oxidation and improve coating performance. The heat required to melt the feedstock material depends on the electrical conductivity of the wires used and the ionization energy of both the feedstock material and atomization gas. In the case of ZnAl4, no phase changes were recorded in the obtained coatings by using either compressed air or argon as atomization gas. This fact has led to the assumption that the melting behavior of ZnAl4 with its low melting and evaporating temperature is different from materials with a higher melting point, such as Fe and Ni, which also explains the unexpected compressive residual stresses in the as-sprayed conditions. The heavier atomization gas, argon, led to slightly higher compressive stresses and oxide content. Compressed air as atomization gas led to lower porosity, decreased surface roughness, and better corrosion resistance. In the case of argon, Al precipitated in the form of small particles. The post-treatment machine hammer peening (MHP) has induced horizontal cracks in compressed air sprayed coatings. These cracks were mainly initiated in the oxidized Al phase.

Evaluation of the Volume Stability and Resource Benefit of Basic Oxygen Furnace Slag and Its Asphalt Mixture Based on Field Application

Applying basic oxygen furnace (BOF) slag as aggregate in asphalt mixture is continuously investigated due to the increasing shortage of natural aggregate in recent years. However, the negative effect of BOF’s expansion in water greatly limits its further application in pavement construction. To address this problem, this paper studied the volume stability of BOF, and its asphalt mixture relied on actual engineering. The asphalt mixtures contained BOF aggregate was designed by the Marshall method with three different gradation types (AC-16, AC-20, and ATB-25). Besides, both laboratory samples and the core samples from field drilling were investigated in volume expansion rate after curing in a water bath. The economic and resource benefits of BOF replacement of natural aggregates were also analyzed. The results showed that the free calcium oxide content of BOF slag is positively related to the particle sizes. Nevertheless, the expansion rates of both the BOF aggregate and its asphalt mixture were less than 1%, which meant the BOF aggregate applied to the asphalt mixture meets the practical engineering requirements. The maximum allowable free calcium oxide content for large-grain size of steel slag is the smallest; it is also recommended that the expansibility of large-grain steel slag should be the first concern in the application. The resource assessment indicated that the use of steel slag for the construction of a trial section of one kilometer of single lane can save 967 tons of natural aggregates. The economic evaluation showed that the use of steel slag instead of natural aggregates for surface course construction could reduce the investment by 16.87%. The experimental methods and conclusions mentioned in this article provide stable references to enhance the development of sustainable pavement by recycling metallurgical slag in highway construction.