Effect of compatibilisers on the cure characteristics and mechanical properties of ternary rubber blend composites

Purpose This paper aims to study the effects of various compatibilisers (maleic anhydride (MAH), methyl methacrylate/butyl acrylate emulsion lattice, and adhesion system (HRH)) on properties of carbon black (CB) filled with natural rubber (NR)/styrene-butadiene rubber (SBR)/ nitrile butadiene rubber (NBR) blends). A series of NR/SBR/NBR blends at a 30/30/40 blend ratio reinforced with 45 phr of CB was prepared using the master-batch method. Design/methodology/approach The tensile properties such as the tensile strength, stress at 100, 200 and 300% elongations, and elongation at break (EB)% were studied. Additionally, the morphological properties of compatibilised and uncompatibilised composites were compared to determine the optimal compatibiliser content. Findings The influence of compatibilisers appeared on all the properties studied. The properties of the blends compatibilised with prepared emulsion are very distinct from those of blends compatibilised with MAH and adhesion systems. Research limitations/implications Interactions among the different components of blends at the interfaces have a high impact on the interfacial properties of the rubber blend. Practical implications Compatibilisers significantly improve the physicomechanical properties of the resulting composites with the loading of investigated compatibilisers because of the uniform dispersion of CB in the rubber matrix. Social implications Using blends in the rubber industry leads to high-efficiency production of low-cost products. Originality/value The rubber blending has a significant positive effect on a wide range of applications such as structural applications, aerospace, military, packaging, tires and biomedical. Hence, improving the compatibility of blends will make new materials suitable for new applications.

ELID Mirror Surface Grinding for Concave Molds by Conductive Elastic Wheel Containing Carbon Black

Elastic grinding wheels have previously been adopted for the development of the mirror surface finishing method for concave spheres. In this study, new conductive elastic grinding wheels, to which electrolytic in-process dressing (ELID) can be applied, are developed; the aim of the study is to address the challenge of maintaining a constant removal rate for rubber bond wheels. When ELID grinding is performed using a non-diene (isobutane isoprene rubber, IIR)-based wheel, a larger removal amount is achieved, and a higher-quality surface is also achieved compared to a diene (acrylonitrile-butadiene rubber, NBR)-based wheel. In addition, to investigate the effect of grinding wheel bond hardness on the removal amount and ground shape accuracy, grinding wheels with various levels of hardness are prepared by controlling the amount of carbon black contained in them, and grinding experiments are conducted. Thus, a larger removal amount is achieved using a harder grinding wheel, but the roughness of the ground surfaces deteriorates. Therefore, in practice, it is necessary to select an appropriate grinding wheel that can achieve both productivity and surface quality. Finally, to obtain a high-quality mirror finish on a concave spherical surface, ELID grinding is performed on the workpieces as is done for spherical lens molds. Thus, high-quality mirror surfaces with roughness Ra < 10 nm were generated. When the work pieces are ground using a grinding wheel of the same radius, excessive removal occurs at the edge of the concave spherical profile, decreasing the form accuracy. Numerical simulation demonstrates that chamfering of the grinding wheel is effective for improving the shape accuracy. The results of this study are expected to contribute to automation and cost reduction in the mirror-finishing process for concave molds.