Analyses of energy transfer of Cr3+ and Nd3+ co-doped Y3Al5O12 ceramic powders at the 4T1 level of Cr3+ ion excitation

The concentration dependence of energy transfer from Cr3+ to Nd3+ at the 4T1 level excitation in Nd/Cr:YAG was investigated by the fluorescence decay curves of Cr3+ and Nd3+ for Nd/Cr:YAG and Cr:YAG ceramic powders in the Cr3+ concentration range of 0.1 to 6.0 mol%. The energy transfer process between Cr3+ and Nd3+ at the 4T1 level excitation is tried to explain using a rate equation that assumes energy transfer from the 2E–4T2 level to Nd3+ on the basis of dipole–dipole interactions, the same as the 4T2 level excitation. In conclusion, the energy excited to the 4T1 level will relax non-radiatively to the 2E–4T2 level and then transfer to Nd3+. It is presumed there will be no direct transfer from the 4T1 level to Nd3+. Our rate equations will be useful when simultaneously exciting the 4T1 and 4T2 levels of Cr3+ in Nd/Cr:YAG using broadband pumping sources.

Modeling the phased implementation of headhunting as a way to fill vacancies

The object of research is a set of stages of processes, used in the application of hunting as a method of closing vacancies. Such stages include: sources of search for candidates, ways of their interest formation, telephone conversation as an interview, negotiations and compilation of statistics with direct transfer of information to the director of the company. In the course of the study, such general scientific and specific research methods as analysis and synthesis, induction, deduction, as well as methods of comparison, observation and a systematic approach, were used. These methods are to determine the results and dynamics when recruiting strategies are changed or when they are combined. With the help of comparison methods and a systematic approach, it was possible to determine the optimal strategy for closing the required number of vacancies in the future. Using the observation method, it was possible to consider the dynamics of indicators from each selection method separately or in different combinations with each other. Among the complex methods, an analysis was used, which allowed to understand the dynamics of indicators and draw conclusions based on them on each of the options for implementing the methods. With the help of induction on the basis of a set of conclusions about each of the options separately, a generalized conclusion was made about the further rationality of the method of hunting as effective for businesses. The simulation allowed us to develop a strategy for the phased implementation of hunting based on direct search and understanding of its difference with the latter. With regard to theoretical methods, in the process of research the transition was made from the definitions and general provisions of the hunt to a specific consideration of the method in the enterprise and its direct implementation. The result of all studies was: – summary of theoretical aspects of headhunting as an effective method of attracting staff; – effective change of dynamics of indicators at the enterprise during introduction of hunting and its combination with direct search; – a developed strategy for the phased implementation of the hunt to increase the effectiveness of the method.

The Impact of Mass Exodus on the Resurgence of COVID19 Cases: Study Case of Regions in Indonesia

The inclusion of the human mobility aspect is essential for understanding the behavior of COVID-19 spread, especially when millions of people travel across borders near Eid Al-Fitr. This study aims at grasping the effect of mass exodus among regions on the active cases of COVID-19 in a mathematical perspective. We construct a multi-region SIQRD (Susceptible-Infected-Quarantined-Recovered-Death) model that accommodates the direct transfer of people from one region to others. The mobility rate is estimated using the proposed Dawson-like function, which requires the Origin-Destination Matrix data. Assuming only susceptible, unapparent infected, and recovered individuals travel near Eid Al-Fitr, the rendered model is well-depicting the actual data at that time, giving either a significant spike or decline in the number of active cases due to the mass exodus. Most agglomerated regions like Jakarta and Depok City experienced the fall of active cases number, both in actual data and the simulated model. However, most rural areas experienced the opposite, like Bandung District and Cimahi City. This study should confirm that most travelers originated from big cities to the rural regions and scientifically justifies that massive mobility affects the COVID-19 transmission among areas.

Direct Transfer to Angiosuite in Acute Stroke

Time to reperfusion is one of the strongest predictors of functional outcome in acute stroke due to a large vessel occlusion (LVO). Direct transfer to angiography suite (DTAS) protocols have shown encouraging results in reducing in-hospital delays. DTAS allows bypassing of conventional imaging in the emergency room by ruling out an intracranial hemorrhage or a large established infarct with imaging performed before transfer to the thrombectomy-capable center in the angiography suite using flat-panel CT (FP-CT). The rate of patients with stroke code primarily admitted to a comprehensive stroke center with a large ischemic established lesion is <10% within 6 hours from onset and remains <20% among patients with LVO or transferred from a primary stroke center. At the same time, stroke severity is an acceptable predictor of LVO. Therefore, ideal DTAS candidates are patients admitted in the early window with severe symptoms. The main difference between protocols adopted in different centers is the inclusion of FP-CT angiography to confirm an LVO before femoral puncture. While some centers advocate for FP-CT angiography, others favor additional time saving by directly assessing the presence of LVO with an angiogram. The latter, however, leads to unnecessary arterial punctures in patients with no LVO (3%–22% depending on selection criteria). Independently of these different imaging protocols, DTAS has been shown to be effective and safe in improving in-hospital workflow, achieving a reduction of door-to-puncture time as low as 16 minutes without safety concerns. The impact of DTAS on long-term functional outcomes varies between published studies, and randomized controlled trials are warranted to examine the benefit of DTAS.

Effect of wall temperature on the kinetic energy transfer in a hypersonic turbulent boundary layer

The effect of wall temperature on the transfer of kinetic energy in a hypersonic turbulent boundary layer for different Mach numbers and wall temperature ratios is studied by direct numerical simulation. A cold wall temperature can enhance the compressibility effect in the near-wall region through increasing the temperature gradient and wall heat flux. It is shown that the cold wall temperature enhances the local reverse transfer of kinetic energy from small scales to large scales, and suppresses the local direct transfer of kinetic energy from large scales to small scales. The average filtered spatial convection and average filtered viscous dissipation are dominant in the near-wall region, while the average subgrid-scale flux of kinetic energy achieves its peak value in the buffer layer. It is found that the wall can suppress the inter-scale transfer of kinetic energy, especially for the situation of a cold wall. A strong local reverse transfer of fluctuating kinetic energy is identified in the buffer layer in the inertial range. Helmholtz decomposition is applied to analyse the compressibility effect on the subgrid-scale flux of kinetic energy. A strong transfer of the solenoidal component of fluctuating kinetic energy is identified in the buffer layer, while a significant transfer of the dilatational component of fluctuating kinetic energy is observed in the near-wall region. It is also shown that compression motions have a major contribution to the direct transfer of fluctuating kinetic energy, while expansion motions play a marked role in the reverse transfer of fluctuating kinetic energy.

Diacetyl and Other Ketones in e-Cigarette Aerosols: Some Important Sources and Contributing Factors

Background: Concerns over the presence of the diketones 2,4 butanedione (DA) and 2,3 pentanedione (AP) in e-cigarettes arise from their potential to cause respiratory diseases. Their presence in e-liquids is a primary source, but they may potentially be generated by glycerol (VG) and propylene glycol (PG) when heated to produce aerosols. Factors leading to the presence of AP, DA and acetoin (AC) in e-cigarette aerosols were investigated. We quantified direct transfer from e-liquids, examined thermal degradation of major e-liquid constituents VG, PG and 1,3 propanediol (1,3 PD) and the potential for AC, AP and DA production from sugars and flavor additives when heated in e-cigarettes.Method: Transfers of AC, AP and DA from e-liquids to e-cigarette aerosols were quantified by comparing aerosol concentrations to e-liquid concentrations. Thermal generation from VG, PG or 1,3 PD e-liquids was investigated by measuring AC, AP and DA emissions as a function of temperature in an e-cigarette. Thermal generation of AC, AP and DA from sugars was examined by aerosolising e-liquids containing sucrose, fructose or glucose in an e-cigarette. Pyrolytic formation of AP and DA from a range of common flavors was assessed using flash pyrolysis techniques.Results: AC transfer efficiency was &gt;90%, while AP and DA were transferred less efficiently (65%) indicating losses during aerosolisation. Quantifiable levels of DA were generated from VG and PG, and to a lesser extent 1,3 PD at coil temperatures &gt;300°C. Above 350°C AP was generated from VG and 1,3 PD but not PG. AC was not generated from major constituents, although low levels were generated by thermal reduction of DA. Aerosols from e-liquids containing sucrose contained quantifiable (&gt;6 ng/puff) levels of DA at all sucrose concentrations tested, with DA emissions increasing with increasing device power and concentration. 1% glucose, fructose or sucrose e-liquids gave comparable DA emissions. Furanose ring compounds also generate DA and AP when heated to 250°C.Conclusions: In addition to less than quantitative direct transfer from the e-liquid, DA and AP can be present in the e-cigarette aerosol due to thermal decomposition reactions of glycols, sugars and furanonse ring flavors under e-cigarette operating conditions.

Hydrogen removal in circulating vacuum degasser under conditions of PJSC “NLMK”

For high­quality steel smelting, stage­by­stage production is required, which has a complex of metallurgical units capable for producing products with high performance properties and low content of harmful impurities. One of the harmful impurities is hydrogen, so it is important to limit its content in the metal. To ensure the specifed hydrogen content, the metal in the steel out­of­furnace treatment at Converter Shop No. 2 (CS­2) of PJSC “Novolipetsk Metallurgical Plant” (“NLMK”) is subjected to vacuum treatment in a circulating vacuum degasser. Despite the prevalence of circulating vacuum derassers, theoretically, mechanism of hydrogen removal in these metallurgical units has been insufciently studied. To increase efciency of hydrogen removal, theoretical calculations were performed to remove it from the metal. There are several mechanisms for hydrogen removing: direct transfer of hydrogen from metal to the surrounding space; formation of gas bubbles in metal and their direct ascent; nucleation of hydrogen bubbles at the border of refractory wall and metal; removal of hydrogen by metal blowing with neutral gas (argon). It is shown that the main ways of hydrogen removal in a circulating vacuum degasser are direct transfer of hydrogen from metal to the surrounding space and blowing of melt with transporting gas. In the CS­2 of PJSC “NLMK”, both ways are implemented at a circulating vacuum degasser. Vacuum pumps provide pressure in a vacuum chamber of less than 101.3 Pa (0.001 atm.). It promotes intensive removal of hydrogen from the metal surface. To ensure circulation of metal, transporting gas argon is supplied to the inlet pipe of the RH degasser, which also takes part in removal of dissolved gases by transferring hydrogen to neutral gas bubbles. Additionally, performed calculations have shown that the main way of degassing in conditions of CS­2 of PJSC “NLMK” is removal of hydrogen into the bubbles of carrier gas.