Study on Microstructure Characteristics of Clay Rock of Xigeda Formation in Xichang City Based on Softening Test and Image Recognition

Based on the Xigeda clay rock exposed in the back mountain of Nanshan Villa in Xichang City, the microstructure changes of Xigeda clay rock before and after water softening were studied by scanning electron microscope and image recognition of PCAS software. The results show that: (1) the clay rock of Xigeda group has flake and layered micro structural characteristics, and the surface of aggregates in natural state has honeycomb characteristics. After water softening, the aggregate particles decompose, the average size of particles becomes smaller, the honeycomb characteristics disappear, and the surface contours of particles become smooth and round. (2) With the increase of water saturation time, the number of aggregate particles and pores increases, the porosity decreases in advance and increases in the later stage. (3) Micro structural changes of the clay rock in Xigeda formation have two stages, in the first stage, the aggregates decompose and the produced fine granular clays fill the original pores, resulting in the decrease of porosity.In the second stage, the fine clay particles further soften, decompose and lose in the water, the porosity increases suddenly.

An Impedance Study of the Membrane Polarisation Effect in Simulated Rock Systems

<p>Work is reported on the development of a high precision, low frequency impedance bridge, and the use of impedance measurement in characterising the induced polarisation effect of unmineralised material. Impedance spectra for a variety of laboratory model clay/rock/electrolyte systems are analysed in terms of an equivalent circuit. By measuring the dependence of the parameters of this circuit, on such variables as electrolyte type and concentration, temperature and pore geometry, an electrochemical model for membrane polarisation has been developed. Polarisation is considered to arise from diffusional limitation of cations at the membrane/electrolyte interface of clay aggregations in rock pores, and this is found to be amenable to a Warburg diffusional impedance analysis.</p>

An Impedance Study of the Membrane Polarisation Effect in Simulated Rock Systems

<p>Work is reported on the development of a high precision, low frequency impedance bridge, and the use of impedance measurement in characterising the induced polarisation effect of unmineralised material. Impedance spectra for a variety of laboratory model clay/rock/electrolyte systems are analysed in terms of an equivalent circuit. By measuring the dependence of the parameters of this circuit, on such variables as electrolyte type and concentration, temperature and pore geometry, an electrochemical model for membrane polarisation has been developed. Polarisation is considered to arise from diffusional limitation of cations at the membrane/electrolyte interface of clay aggregations in rock pores, and this is found to be amenable to a Warburg diffusional impedance analysis.</p>

Identification and evaluation of processes for joint disposal of high level radioactive waste and low to intermediate level radioactive waste

The on-going research project „Identification and evaluation of processes that can arise by disposing of both high level radioactive waste (HAW) and low to intermediate level radioactive waste (LAW/MAW) at the same site“ (GemEnd, FKZ 4719F10401), commissioned by the Federal Office for the Safety of Nuclear Waste Management (BASE), is concerned with the question which thermal, hydraulic, mechanical, chemical and biological (THMCB) processes could be of importance for the long-term safety of the geological repository for high level radioactive waste. The focus of the project is on mutual influences between the HAW and LAW/MAW repositories, which should be constructed separately according to the Safety Regulations (Federal Ministry for the Environment, Nature Conservation and Nuclear Safety, BMU, 2020). A second point of emphasis is on processes that could result from the disposal of small amounts of LAW/MAW within the HAW repository. The analyses carried out for each of the potential host rocks clay rock, rock salt and crystalline rock as well as for a combination of clay rock above crystalline rock at a generic site are divided into a qualitative and a quantitative part. As for the qualitative analyses, all potentially relevant processes are identified and evaluated as to whether they are negligible or principally relevant for the exemplary repository configurations considered and according to the current state of knowledge. With regard to the quantitative analyses, the possible extent of potentially safety-relevant processes is illustrated by means of coupled numerical simulations. Of special interest are the effects of particularly sensitive model approaches and/or parameters and notably of the distances between the HAW and LAW/MAW repositories in the different exemplary repository configurations considered. From the results of the quantitative and qualitative analyses, knowledge gaps will be identified and the possibility of their reduction by research and development activities will be discussed. Furthermore, aspects of the transferability of the results to the German site selection procedure will be illuminated. At the interdisciplinary research symposium safeND selected preliminary results of both the qualitative and quantitative analyses will be presented.

An interdisciplinary view of the long-term evolution of repository systems across scales: the iCROSS project

The interdisciplinary project “Integrity of nuclear waste repository systems – Cross-scale system understanding and analysis (iCROSS)” combines research competencies of Helmholtz scientists related to the topics of nuclear, geosciences, biosciences and environmental simulations in collaborations overarching the research fields energy and earth and environment. The focus is to understand and analyze close-to-real long-term evolutionary pathways of radioactive waste repositories across nanoscales to repository scales. The project is subdivided into work packages dealing with laboratory studies, field experiments in underground research laboratories (URLs), advanced modelling studies and the integration and alignment of data and information using virtual reality methods. In this sense, the project structure aims at a holistic view on relevant processes across scales in order to comprehensively simulate potential repository evolutions. Within the multi-barrier system of a repository for heat-generating radioactive waste, a number of complex reactions proceed, including dissolution, redox processes, biochemical reactions, gas evolution and solid/liquid interface and (co)precipitation reactions. At the same time, thermal and external mechanical stress has an impact on the conditions in a deep geological repository. All those processes are highly coupled, with multiple interdependencies on various scales and have a strong impact on radionuclide mobility and retention. In recent years, substantial progress was achieved in describing coupled thermal-hydro-mechanical-chemical-biological (THM/CB) processes in numerical simulations. A realistic and concise description of these coupled processes on different time and spatial scales is, at present, a largely unresolved scientific and computational challenge. The close interaction of experimental and simulation teams aims at a more accurate quantification and assessment of processes and thus, the reduction of uncertainties and of conservative assumptions and eventually to a close-to-real perception of the repository evolution. One focus of iCROSS is directed to relevant processes in a clay rock repository. In this context, the iCROSS team became a full member of the international Mont Terri consortium and worked in close collaboration with international and German institutions in URL projects. Respective experiments specifically deal with coupled processes at the reactive interfaces in a repository near field (e.g. the steel/bentonite and bentonite/concrete interfaces). Within iCROSS, the impact of secondary phase formation on radionuclide transport is investigated. At Mont Terri, experiments are in preparation to study radionuclide transport phenomena in clay rock formations within temperature gradients and in facies exhibiting significant heterogeneities on different scales (nm to cm). Beside those studies, high resolution exploration methods for rock characterization are developed and tested and the effect of temperature and other boundary conditions on the strength, creep properties and healing of faults within Opalinus clay are quantified. Multiphysics models coupled to reactive transport simulation have been further developed and applied to laboratory and field experiments. Results are digitally analyzed and illustrated in a visualization center, in order to enhance the comprehension of coupled processes in repository systems across scales. The present contribution provides an overview on the project and reports selected results. The impact of considering complex coupled processes in repository subsystems for the assessment of the integrity of a given (generic) repository arrangement is discussed.

Diffusive transport of uranium and americium through clay rock down to ultra-trace levels

Clay rock is a potential host rock for the final disposal of nuclear waste in deep geological formations. In the scenario of ground water intrusion into the nuclear waste repository and subsequent corrosion of canisters and waste, possibly released actinides, such as uranium (U) and americium (Am), would be transported through the engineered barrier and clay host rock mainly by diffusion. Actinides are known to exhibit low solubility and are strongly sorbing under the reducing conditions of deep geological formations. Diffusion experiments are therefore difficult to perform due to analytical constraints. To our knowledge, the diffusion of U in clay rock has not been investigated below concentrations of 10-7molkg-1 clay (e.g., Joseph et al., 2013) and for Am, no diffusion experiments have been performed in a clay rock, considered suitable as host rock, such as Opalinus clay (OPA). This work aimed at the investigation of the diffusive behavior of U and Am down to ultra-trace concentrations (≪10-7molkg-1) in OPA. Laboratory-scale diffusion experiments were conducted with samples of OPA, obtained from the Mont Terri underground laboratory, Switzerland for up to 240 d. The OPA samples were placed in contact with synthetic pore water (I=0.22molL-1, pH=7.24), spiked with 5×10-9molL-1 of 233U and 243Am, respectively. After termination of the experiment, the OPA samples were segmented into thin layers of 20–400 µm. The obtained clay segments were analyzed for the 233U and 243Am content with accelerator mass spectrometry. Concentration profiles were determined down to 10-12molkg-1 clay for 233U and 5×10-10molkg-1 clay for 243Am. U showed a typical diffusion profile which can be interpreted by applying Fick's laws, while the Am profile was more complex, requiring further investigation of transport modes. These results will provide relevant insights into the transport behavior of U and Am in OPA over a wide range of concentrations down to ultra-trace levels.

Stability Analysis of Host Claystone under T-M Coupling of HLW Disposal Repository in China: Experiments and Numerical Simulation

This paper focuses on the stability of the high-level radioactive waste (HLW) in the proposed clay rock in Tamusu area of China. The in-situ stress as well as the variational characteristics of ambient temperature caused by nuclide decay during HLW storage should be noticeable. A series of thermal property tests and thermo-mechanical coupled strength (T-M) tests of rock samples in the target formation are carried out. Then the stability of surrounding rock of an HLW under the combination of heat release from HLW and in-situ stress is simulated and analyzed by numerical method. Thermal properties of Tamusu clay rock samples are obtained by testing their thermal conductivity. In order to obtain the characteristics and the failure modes of rock samples at different temperatures, the T-M coupling experiments in the temperature range of 100°C are conducted. Numerical model for simulating the state of operation of the nuclear waste tank buried in the tunnel within 100 years is constructed. A thermal boundary by the heat release equation of HLW and the real in-situ stress level in Tamusu area are considered in the model. While, the variation law of surrounding rock’s temperature, stress, and deformation corresponding to the embedding time is obtained from the numerical calculation. Finally, the stability of the deep geological repository is comprehensively evaluated. The results show that the temperature has a significant impact on the T-M coupling characteristics of Tamusu clay rock, and the proposed repository numerical model has no large deformation and failure problems in 100 years. However, the temperature of the surrounding rock of the repository may exceed the safety standard value during the operation period.

Molecule Diffusion Behavior of Tritium and Selenium in Mongolia Clay Rock by Numerical Analysis of the Spatial and Temporal Variation

Clay rock in the Tamusu (TMS) area in the Inner Mongolia province is one candidate as a geological disposal site for highly radioactive waste in China. The diffusion behavior of HTO and Se(IV) in Tamusu clay rock was studied by through-diffusion (TD) experiments and numerical analysis to determine the spatial and temporal variation. A minimum error analysis was conducted to determine the HTO and Se(IV) diffusion coefficients in compacted TMS clay. The TD experimental results and numerical analysis showed that the diffusion of HTO and Se reached a steady state within 7 and 50 days, respectively, and the apparent diffusion coefficients (Da) decreased with the increases in the compacted density. In fact, there was retardation of Se diffusion in intact TMS clay rock. A two-site sorption model for Se was applied to simulate fast and slow sorption behavior quantitatively.