Colorimetric Measurement of Deltamethrin Pesticide Using a Paper Sensor Based on Aggregation of Gold Nanoparticles

Deltamethrin (DEL) is one of the most commonly used pyrethroid pesticides that can cause serious harms to the ecological environment and human health. Herein, we have developed a paper-based colorimetric sensor impregnated with gold nanoparticles (AuNPs) for on-site determination of DEL pesticide. AuNPs show obvious color change on paper device with the presence of DEL. Measuring the gray intensity of the AuNPs on the reaction zone of the paper sensor allows accurate quantitative analysis. The detection mechanism of DEL on paper sensor was confirmed by UV-Vis spectrophotometry (UV-Vis), Fourier transform infrared spectroscopy (FT-IR), and transmission electron microscope (TEM). Under optimal conditions, the colorimetric sensor exhibited high sensitivity, rapid detection, and low detection limit within the values stipulated by Chinese detection standards (LOD = 0.584 mg/L). Besides, detecting DEL in vegetable and fruit samples also gave satisfying results, which were much consistent with those obtained by spectrophotometry. Overall, this work provided a user-friendly, cost-effective and visualized detection platform, which could be applied to rapidly detect DEL pesticides in the food safety field.

Paper Sensors Based on Fluorescence Changes of Carbon Nanodots for Optical Detection of Nanomaterials

A paper sensor was designed in order to detect the presence of nanomaterials, such as ZnO and silica nanoparticles, as well as graphene nanoplatelets (GnP), based on fluorescence changes of carbon nanodots. Paper strips were functionalized with carbon nanodots using polyvinyl alcohol (PVA) as binder. The carbon nanodots were highly fluorescent and, hence, rendered the (cellulosic) paper stripes emissive. In the presence of silica and ZnO nanoparticles, the fluorescence emission of the carbon nanodots was quenched and the emission decay was shortened, whereas in the presence of GnP only emission quenching occurred. These different photoluminescence (PL) quenching mechanisms, which are evident from lifetime measurements, convey selectivity to the sensor. The change in fluorescence of the carbon dot-functionalized paper is also evident to the naked eye under illumination with a UV lamp, which enables easy detection of the nanomaterials. The sensor was able to detect the nanomaterials upon direct contact, either by dipping it in their aqueous dispersions, or by sweeping it over their powders. The use of the proposed optical sensor permits the detection of nanomaterials in a straightforward manner, opening new ways for the development of optical sensors for practical applications.