Enzymatic synthesis of 2-phenethyl acetate in water catalyzed by an immobilized acyltransferase from Mycobacterium smegmatis

Although water is an ideal green solvent for organic synthesis, it is difficult for most biocatalysts to carry out transesterification reactions in water because of the reversible hydrolysis reaction.

Ultrasensitive Room-Temperature Acetone Gas Sensors Employing Green-Solvent-Processed Aligned InNdO Nanofiber Field-Effect Transistors

The development of a high-performance acetone gas sensor for detecting low concentrations of acetone gas is still a key issue. Here, we propose the green-solution-processed electrospinning technique to construct Nd-doped...

Recent Advances in Green-Solvent-Processable Organic Photovoltaics

Over the last four years, tremendous progress has occurred in the field of organic photovoltaics (OPVs) and the champion power conversion efficiency (PCE) under AM1.5G conditions, as certified by the National Renewable Energy Laboratory (NREL), is currently 18.2%. However, these champion state-of-the-art devices were fabricated at lab-scale using highly toxic halogenated solvents which are harmful to human health and to the environment. The transition of OPVs from the lab to large-scale production and commercialization requires the transition from halogenated-solvent-processing to green-solvent-processing without compromising the device’s performance. This review focuses on the most recent research efforts, performed since the year 2018 onwards, in the development of green-solvent-processable OPVs and discusses the three main strategies that are being pursued to achieve the proposed goal, namely, (i) molecular engineering of novel donors and acceptors, (ii) solvent selection, and (iii) nanoparticle ink technology.

Elucidating Charge Generation in Green-Solvent Processed Organic Solar Cells

Organic solar cells have the potential to become the cheapest form of electricity. Rapid increase in the power conversion efficiency of organic solar cells (OSCs) has been achieved with the development of non-fullerene small-molecule acceptors. Next generation photovoltaics based upon environmentally benign “green solvent” processing of organic semiconductors promise a step-change in the adaptability and versatility of solar technologies and promote sustainable development. However, high-performing OSCs are still processed by halogenated (non-environmentally friendly) solvents, so hindering their large-scale manufacture. In this perspective, we discuss the recent progress in developing highly efficient OSCs processed from eco-compatible solvents, and highlight research challenges that should be addressed for the future development of high power conversion efficiencies devices.