Transport Reagents through the Pore Structure of a Membrane Catalyst under Isothermal and Non-Isothermal Conditions

The article presents the results of an experimental comparison of methane transport in the pore structure of a membrane catalyst under isothermal and non-isothermal Knudsen diffusion conditions. It is shown that under the conditions of non-isothermal Knudsen diffusion in the pore structure of the membrane catalyst, there is a coupling of dry reforming of the methane (DRM) and gas transport, which leads to the intensification of this process. The reasons for the intensification are changes in the mechanism of gas transport, an increase in the rate of mass transfer, and changes in the mechanism of some stages of the DRM. The specific rate constant of the methane dissociation reaction on a membrane catalyst turned out to be an order of magnitude (40 times) higher than this value on a traditional (powder) catalyst.

DFT Study on Mechanisms of the N2O Direct Catalytic Decomposition over Cu-ZSM-5: The Detailed Investigation on NO Formation Mechanism

Nitrous oxide (N2O) is an industrial emission that causes the greenhouse effect and damages the ozone layer. Density functional theory study on the N2O direct catalytic decomposition over Cu–ZSM-5 has been performed in this paper. Two possible reaction mechanisms for N2O direct catalytic decomposition over Cu-ZSM-5 were proposed (O2 formation mechanism and Nitric oxide (NO) formation mechanism). The geometrical parameters, vibration frequency and thermodynamic data of the intermediate states in each step have been examined. The results indicate that N2O can be adsorbed on active site Cu in two ways (O-terminal or N-terminal), and N2O decomposition reactions can occur in both cases. The NO formation mechanism exhibits higher N2O dissociation reaction due to lower energy barrier.

VACUUM CVD COATINGS TA ON TARGET W PLATE OF NEUTRONS SOURCE

The paper presents data on the creation of a tungsten target, protected from corrosion under irradiation with a power of up to 100 kW. A protective coating of tantalum with a thickness of 250 μm was deposited on the surface of tungsten plates 66x66 mm, thickness 10; 6; 4; 3 mm. The coating has a solid-phase compound over the entire surface of tungsten and is hermetic. This was achieved by CVD (chemical vapor deposition) tantalum deposition in a vacuum of 2.66•10-2 Pa on a plate surface heated to ~ 1700 K using the thermal dissociation reaction of tantalum pentachloride vapor. Such tungsten plates, equipped with tantalum coatings with desired properties, were used in the Neutron Source installation of the NSC KIPT.

Decreased conformational stability in the oncogenic N92I mutant of Ras-related C3 botulinum toxin substrate 1

Ras-related C3 botulinum toxin substrate 1 (Rac1) functions as a molecular switch by cycling between an inactive guanosine diphosphate (GDP)–bound state and an active guanosine triphosphate (GTP)–bound state. An oncogenic mutant of Rac1, an N92I mutant, strongly promotes cell proliferation and subsequent oncogenic activities by facilitating the intrinsic GDP dissociation in the inactive GDP-bound state. Here, we used solution nuclear magnetic resonance spectroscopy to investigate the activation mechanism of the N92I mutant. We found that the static structure of the GDP binding site is not markedly perturbed by the mutation, but the overall conformational stability decreases in the N92I mutant, which then facilitates GDP dissociation by lowering the activation energy for the dissociation reaction. On the basis of these results, we proposed the activation mechanism of the N92I mutant, in which the decreased conformational stability plays important roles in its activation process.