Retroarc Jurassic burial and exhumation of Barrovian metamorphic rocks dated by monazite petrochronology, Funeral Mountains, California

ABSTRACT In this study, we determined the timing of burial and subsequent exhumation of Barrovian metamorphic rocks from the Chloride Cliff area of the Funeral Mountains in southeastern California by constraining the ages of different portions of a pressure-temperature (P-T) path. Using a split-stream laser-ablation inductively coupled plasma–mass spectrometry (ICP-MS) system, we analyzed 192 domains from 35 grains of monazite within five samples with a spot size of 8 µm to determine U-Pb ages and trace-element abundances from the same samples (same polished sections) that were analyzed to produce the P-T paths. Changes that took place within individual monazite grains reflect localized equilibrium and captured the changes in heavy rare earth element (HREE) abundances in the matrix reservoir that occurred as garnet grew, resorbed, and then regrew, thus constraining ages on different portions of the P-T path. The results show that garnet began growing ca. 168 Ma, began resorbing ca. 160 Ma, began retrograde regrowth ca. 157 Ma, and continued to regrow at least through ca. 143 Ma. The early garnet growth corresponds to a period of pressure increase along the P-T path. The subsequent partial resorption corresponds to the prograde crossing of a garnet-consuming reaction during decompression, and the retrograde garnet regrowth occurred when this same reaction was recrossed in the retrograde sense during further decompression. These results are consistent with previously determined ages, which include a Lu-Hf garnet age of 167.3 ± 0.72 Ma for the early pressure-increase portion of the P-T path, and 40Ar/39Ar muscovite cooling ages of 153 and 146 Ma in the lower-grade Indian Pass area 10 km southeast of Chloride Cliff. The 40Ar/39Ar muscovite ages document cooling at the same time as retrograde garnet regrowth was taking place at Chloride Cliff. The oldest monazite age obtained in this study, 176 ± 5 Ma, suggests that southeast-directed thrusting within the Jurassic retroarc was ongoing by this time along the California portion of the western North American plate margin, as a consequence of east-dipping subduction and/or arc collision. The Funeral Mountains were likely located on the east side of the northern Sierra Nevada range in the Jurassic, taking into account dextral strike-slip displacement along the Cretaceous Mojave–Snow Lake fault. The Late Jurassic timing of burial in the Funeral Mountains and its Jurassic location suggest burial was associated with the East Sierran thrust system. The timing of prograde garnet resorption during exhumation (160–157 Ma) corresponds to a change from regional dextral transpression to sinistral transtension along the Jurassic plate margin inferred to have occurred ca. 157 Ma. The recorded exhumation was concurrent with intrusion of the 148 Ma Independence dike swarm in the eastern Sierra Nevada and Mojave regions, which developed within a regime of northeast-southwest extension.

Hydrogeochemistry of Hot Springs and the 2018 Mojiang M 5.9 Earthquake-Related Chemical Changes in the Simao Basin, China

The Simao Basin is characterized by strong tectonic activity and frequent seismicity. This study investigated the hydrochemical characteristics of 21 thermal springs in the Simao Basin from 2018 to 2020. In this study period, the 2018 Mojiang M5.9 earthquake caused several hydrochemical changes. The results indicate that the Simao Basin contained saline spring waters, HCO3−-rich spring waters, and SO42−-rich spring waters. In the study area, the water chemistry types were controlled by stratum lithology. Saline springs flowed through red beds and dissolved large amounts of halite, which is a rich source of Cl−and Na+ ions. In the hot spring waters, Ca2+ (Mg2+) and HCO3− were mainly derived from the dissolution of carbonate minerals, gypsum, and anhydrite of Triassic rocks. The higher SO42- content in the hot spring waters was caused by the pyrite present in Ailaoshan metamorphic rocks. The reservoir temperatures (121–289 °C) in the Simao Basin were estimated by the silica-enthalpy mixing model equation and the silica-enthalpy diagram. The hot springs had higher reservoir temperatures (>250 °C) and were mainly located at the edges of the basin. Metamorphic rocks exposed in the region had low permeabilities and these springs was close to nearby deep faults that provided deep heat. In most springs, the concentrations of Ca2+ and HCO3− ions increased obviously before the 2018 Mojiang M5.9 earthquake; however, the concentrations of these ions decreased after the earthquake. The hydrogeochemical variations might be attributed to the vigorous water-rock interactions and the mixing of secondary fluids. The entry of cold shallow groundwater caused changes in the reservoir temperatures of some spring samples.

Diachronous Redistribution of Hf and Nd Isotopes at the Crystal Scale—Consequences for the Isotopic Evolution of a Poly-Metamorphic Crustal Terrane

In metamorphic rocks, mineral species react over a range of pressure–temperature conditions that do not necessarily overlap. Mineral equilibration can occur at varied points along the metamorphic pressure–temperature (PT) path, and thus at different times. The sole or dominant use of zircon isotopic compositions to constrain the evolution of metamorphic rocks might then inadvertently skew geological interpretations towards one aspect or one moment of a rock’s history. Here, we present in-situ U–Pb/Sm–Nd isotope analyses of the apatite crystals extracted from two meta-igneous rocks exposed in the Saglek Block (North Atlantic craton, Canada), an Archean metamorphic terrane, with the aim of examining the various signatures and events that they record. The data are combined with published U–Pb/Hf/O isotope compositions of zircon extracted from the same hand-specimens. We found an offset of nearly ca. 1.5 Gyr between U-Pb ages derived from the oldest zircon cores and apatite U–Pb/Sm–Nd isotopic ages, and an offset of ca. 200 Ma between the youngest zircon metamorphic overgrowths and apatite. These differences in metamorphic ages recorded by zircon and apatite mean that the redistribution of Hf isotopes (largely hosted in zircon) and Nd isotopes (largely hosted in apatite within these rocks), were not synchronous at the hand-specimen scale (≤~0.001 m3). We propose that the diachronous redistribution of Hf and Nd isotopes and their parent isotopes was caused by the different PT conditions of growth equilibration between zircon and apatite during metamorphism. These findings document the latest metamorphic evolution of the Saglek Block, highlighting the role played by intra-crustal reworking during the late-Archean regional metamorphic event.

Intracellular bound chlorophyll residues identify 1 Gyr-old fossils as eukaryotic algae

The acquisition of photosynthesis is a fundamental step in the evolution of eukaryotes. However, few phototrophic organisms are unambiguously recognized in the Precambrian record. The in situ detection of metabolic byproducts in individual microfossils is the key for the direct identification of their metabolisms. Here, we report a new integrative methodology using synchrotron-based X-ray fluorescence and absorption. We evidence bound nickel-geoporphyrins moieties in low-grade metamorphic rocks, preserved in situ within cells of a ~1 Gyr-old multicellular eukaryote, Arctacellularia tetragonala. We identify these moieties as chlorophyll derivatives, indicating that A. tetragonala was a phototrophic eukaryote, one of the first unambiguous algae. This new approach, applicable to overmature rocks, creates a strong new proxy to understand the evolution of phototrophy and diversification of early ecosystems.

On The Supposed Onshore Extension Of The Penyu Basin, Peninsular Malaysia

The Penyu Basin is a Tertiary sedimentary basin located offshore Peninsular Malaysia. The basin is assumed to continue westwards beneath the Pahang River delta where as much as 115 m of Quaternary sediments overlie a bedrock of pre-Tertiary granites and metamorphic rocks. No Pliocene or older sediments beneath the delta have been reported. If the Quaternary sediments are considered as part of the Cenozoic Penyu Basin, the basin’s western limit may be delineated at the foothills of the coastal plain where those sediments onlap onto pre-Tertiary rocks. Therefore, any sedimentary rock of Tertiary age that may occur to the west of that limit most probably represents a separate basin.

Spatial distribution prediction of pre-Sinian volcanic and metamorphic rocks in Xinhenan-Sandaoqiao area, Northern Tarim Basin

The main type of oil and gas reservoir in the Xinhenan-Sandaoqiao area is buried hills. The distribution pattern and scale of reservoirs are obviously controlled by pre-Sinian basement strata. However, the lithologic combination and spatial distribution pattern of pre-Sinian basement in this area are still unclear. In this paper, the spatial distribution of pre-Sinian basement volcanic and metamorphic rocks is studied by using the method of multifactor comprehensive analysis. Firstly, the lithology and lithologic combination of igneous and metamorphic rocks are determined according to cores and thin sections. Guided by the seismic reflection characteristics of different lithologic combinations, different lithologic combinations are identified on the profile by combining the seismic reflection characteristics of single well and multiwell. Secondly, using cluster analysis technology, three seismic attributes sensitive to lithology are selected from 10 attributes, crossplots of three seismic attribute values are constructed, and the distribution range of attribute values corresponding to different lithologic combinations is defined for plane lithologic identification. Finally, the plane lithology distribution of the surface layer of pre-Sinian basement is described by combining plane and profile. Six distribution types were identified: deep metamorphic bedrock area in Kuqu depression, dynamic mixed metamorphic rock and intermediate-acidic intrusive rock area, metamorphic bedrock in thrust napple slopes area, thermal contact metamorphic rock area, intermediate-acidic intrusive rock area, dynamic metamorphic rock area and gneiss area in faulted uplift core.

Supplemental Material: Retroarc Jurassic burial and exhumation of Barrovian metamorphic rocks dated by monazite petrochronology, Funeral Mountains, California

All isotope and elemental data collected and presented in this paper. Table S1 includes monazite isotopic data for U-Th-Pb, element abundances, calculated chondrite normalized REE values, and calculated ages. Table S2 includes xenotime isotopic data for U-Th-Pb, element abundances, calculated chondrite normalized REE values, and calculated ages. Table S3 includes garnet element abundances and chondrite normalized REE data collected along rim-to-rim line traverses.<br>

Supplemental Material: Retroarc Jurassic burial and exhumation of Barrovian metamorphic rocks dated by monazite petrochronology, Funeral Mountains, California

All isotope and elemental data collected and presented in this paper. Table S1 includes monazite isotopic data for U-Th-Pb, element abundances, calculated chondrite normalized REE values, and calculated ages. Table S2 includes xenotime isotopic data for U-Th-Pb, element abundances, calculated chondrite normalized REE values, and calculated ages. Table S3 includes garnet element abundances and chondrite normalized REE data collected along rim-to-rim line traverses.<br>