Design and Fabrication of Modified SMA-Connector Sensor for Detecting Water Adulteration in Honey and Natural Latex

A detection system for water adulteration in honey is proposed. It consists of a modified SMA-connector sensor and a vector network analyzer. A modified SMA-connector sensor is applied to measure complex relative permittivity, electrical conductivity, and phase constant of honey samples with the open-ended method. The system is tested in the frequency range of 0.5–4.0 GHz at the sample temperature of 25 °C. The relationships between the complex relative permittivity, electrical conductivity, the phase constant, and the honey samples with different concentrations (0–30%w/w) are determined. The experimental results show that the real part of the complex relative permittivity is significantly proportional in honey samples with adulteration of water in the range of 0–30%w/w. The frequency of 0.6 GHz is a suitable frequency for detection with a real part of complex relative permittivity as an indicator. The frequency of 3.74 GHz is an appropriate frequency for detection with electrical conductivity as in indicator while the frequency of 4.0 GHz is suitable for detection with phase constant as an indicator. In addition, the data are analyzed with regression analysis. This technique is also performed on natural latex samples to determine the dry rubber content. The frequency of 0.5 GHz is a suitable frequency with a real part of complex relative permittivity as an indicator while the frequency of 4.0 GHz is a suitable frequency with an imaginary part of complex relative permittivity, electrical conductivity, and phase constant as the indicators. The results demonstrate that it is possible to apply this technique to determine the dry rubber content in the natural latex samples as well.

Effect of Ground Tire Rubber on Mechanical Properties of Low Density Polyethylene

This research explores the effect of ground tire rubber (GTR) on the mechanical properties of LDPE. This thermoplastic-elastomer blend sets the composition of ground tire rubber and low-density polyethylene (LDPE/GTR). The blend was prepared in different proportions and was processed in a compression molding machine. The optimum operating conditions of the blend set to be 220℃ temperature and pressure varied from 150-200 bars. Different parts per hundred rubber (phr) samples were obtained under these conditions, including 1 phr, 2 phr, 3 phr, 4 phr, and 5 phr. After that, the mechanical properties of the blend were examined concerning various compositions. Different testing methods were used to determine the mechanical properties of the thermoplastic-elastomer blend, which include tensile strength, flexural strength, and Izod impact. The results obtained from these tests show that tensile strength and modulus decreases by increasing the rubber content. However, impact strength and percentage elongation increase by increasing the rubber content. This enhancement in impact and percentage elongation may be suitable for the applications in gymnasium mat and automobile industry.

Studies on reinforcing effect of industrial nano silica in chloroprene vulcanizates containing carboxy-terminated liquid natural rubber

Maleic anhydride was chemically attached to depolymerized natural rubber, and the product was named as carboxy-terminated liquid natural rubber (CTNR). The CTNR can act as a potential plasticizer in chloroprene (CR) vulcanizates. This paper describes the use of commercial nano silica (NS) as a promising cost-effective filler, which can enhance the tensile properties and ageing resistance of the CR vulcanizates incorporated with CTNR (CR-CTNR). The enhancement in properties may be attributed to the increased bound-rubber content owing to the large surface area of the nano-sized filler. The characteristics of the NS-filled CR vulcanizates containing CTNR (NS CR-CTNR) were compared with those containing amorphous silica. The NS CR-CTNR vulcanizates showed superior ageing and oil resistance due to the finer rubber filler interaction modified by ionic cross linking.

Sand–Tire Shred Mixture Performance in Controlling Surface Explosion Hazards That Affect Underground Structures

Blasting is an unavoidable activity in geotechnical engineering, road and tunnel construction, and mining and quarrying. However, this activity can expose the environment to various hazards that are challenging to control and, at the same time, critical for the safety of site workers, equipment, and surrounding structures. This research aims to evaluate the ability of sand–tire shred mixtures to reduce peak blast pressure, which is the leading cause of damage to underground structures under surface explosion. ABAQUS software is used to model the material behavior under explosion and is validated using the results of previous studies and an empirical equation. Different scenarios are created by using mixture layers with different thicknesses (2, 4, and 6 m) and tire shred contents (10%, 20%, and 30%) that are subjected to various surface explosion charges (100, 500, 1000, and 5000 kg). The thickness of the mixture layer is found to be directly related to the dissipation of explosion energy. However, the percentage of the rubber content in the mixture is only significant in reducing peak blast pressure when a thick enough mixture layer is used. The results confirm the adequate performance of the correctly chosen sand–tire shred mixtures in reducing peak blast pressure and protecting the underground structure from surface explosion hazards.

Mechanical Behaviour of Completely Decomposed Granite Soil with Tire Rubber Granules and Fibres

Mixing soil with waste tire rubber granules or fibres is a practical and promising solution to the problem of global scrap tire pollution. Before successful applications, the mechanical behaviour of the soil–rubber mixture must be thoroughly investigated. Comprehensive laboratory studies (compaction, permeability, oedometer and triaxial tests) were conducted on the completely decomposed granite (CDG)–rubber mixtures, considering the effects of rubber type (rubber granules GR1 and rubber fibre FR2) and rubber content (0–30%). Results show that, for the CDG–rubber mixture, as the rubber content increases, the compaction curves become more rubber-like with less obvious optimum moisture content. The effect on permeability becomes clearer only when the rubber content is greater than 30%. The shape effect of rubber particles in compression is minimal. In triaxial shearing, the inclusion of rubber particles tends to reduce the stiffness of the mixtures. After adding GR1, the peak stress decreases with the increasing rubber content due to the participation of soft rubber particles in the force transmission, while the FR2 results in higher peak stress especially at higher rubber contents because of the reinforcement effect. For the CDG–GR1 mixture, the friction angle at the critical state (φ’cs) decreases with the increasing rubber content, mainly due to the lower inter-particle friction of the CDG–rubber interface compared to the pure CDG interface, while for the CDG–FR2 mixture, the φ’cs increases with the increasing rubber content, again mainly due to the reinforcement effect.

Raman Tweezers for Tire and Road Wear Micro- and Nanoparticles analysis

Tire and Road Wear Particles (TRWP) are non-exhaust particulate matter generated by road transport means during the mechanical abrasion of tires, brakes and roads. TRWP accumulate on the roadsides and are transported into the aquatic ecosystem during stormwater runoffs. Due to their size (sub-millimetric) and rubber content (elastomers), TRWP are considered microplastics (MPs). While the amount of the MPs polluting the water ecosystem with sizes from ~ 5 μm to more than 100 μm is known, the fraction of smaller particles is unknown due to the technological gap in the detection and analysis of < 5 μm MPs. Here we show that Raman Tweezers, a combination of optical tweezers and Raman spectroscopy, can be used to trap and chemically analyze individual TWRPs in a liquid environment, down to the sub-micrometric scale. Using tire particles mechanically grinded from aged car tires in water solutions, we show that it is possible to optically trap individual sub-micron particles, in a so-called 2D trapping configuration, and acquire their Raman spectrum in few tens of seconds. The analysis is then extended to samples collected from a brake test platform, where we highlight the presence of sub-micrometric agglomerates of rubber and brake debris, thanks to the presence of additional spectral features other than carbon. Our results show the potential of Raman Tweezers in environmental pollution analysis and highlight the formation of nanosized TRWP during wear.