Micro-Structural Design of Soft Solid Composite Electrolytes with Enhanced Ionic Conductivity

Electrolyte in a rechargeable Li-ion battery plays a critical role in determining its capacity and efficiency. While the typically used electrolytes in Li-ion batteries are liquid, soft solid electrolytes are being increasingly explored as an alternative due to their advantages in terms of increased stability, safety and potential applications in the context of flexible and stretchable electronics. However, ionic conductivity of solid polymer electrolytes is significantly lower compared to liquid electrolytes. In a recent work, we developed a theoretical framework to model the coupled deformation, electrostatics and diffusion in heterogeneous electrolytes and also established a simple homogenization approach for the design of microstructures to enhance ionic conductivity of composite solid electrolytes. Guided by the insights from the theoretical framework, in this paper, we ex- amine specific microstructures that can potentially yield significant improvement in the effective ionic conductivity. We numerically implement our theory in the open source general purpose finite element package FEniCS to solve the governing equations and present numerical solutions and insights on the effect of microstructure on the enhancement of ionic conductivity. Specifically, we investigate the effect of shape by considering ellipsoidal inclusions. We also propose an easily manufacturable microstructure that increases the ionic conductivity of the composite electrolyte by forty times, simply by the addition of dielectric columns parallel to the solid electrolyte phase.

Flexible and Stretchable Memristive Arrays for in-Memory Computing

With the tremendous progress of Internet of Things (IoT) and artificial intelligence (AI) technologies, the demand for flexible and stretchable electronic systems is rapidly increasing. As the vital component of a system, existing computing units are usually rigid and brittle, which are incompatible with flexible and stretchable electronics. Emerging memristive devices with flexibility and stretchability as well as direct processing-in-memory ability are promising candidates to perform data computing in flexible and stretchable electronics. To execute the in-memory computing paradigm including digital and analogue computing, the array configuration of memristive devices is usually required. Herein, the recent progress on flexible and stretchable memristive arrays for in-memory computing is reviewed. The common materials used for flexible memristive arrays, including inorganic, organic and two-dimensional (2D) materials, will be highlighted, and effective strategies used for stretchable memristive arrays, including material innovation and structural design, will be discussed in detail. The current challenges and future perspectives of the in-memory computing utilizing flexible and stretchable memristive arrays are presented. These efforts aim to accelerate the development of flexible and stretchable memristive arrays for data computing in advanced intelligent systems, such as electronic skin, soft robotics, and wearable devices.

Postbuckling analysis of ultra-low rigidity serpentine structures

Serpentine structures are of growing interest due to its unique mechanical and physical properties for applications in stretchable electronics, mechanical sensing, biomedical devices. Mechanics-guided, deterministic three-dimensional (3D) assembly provide routes to form remarkable 3D structures, which in turn significantly improve its potential for applications. Therefore, an accurate postbuckling analysis is essential to the complex 3D serpentine structures with arbitrary geometry/material parameters. Here, simple, analytical expressions are obtained for the displacement and effective rigidity of serpentine structures during postbuckling. By tuning geometry parameters, the amplitude of assembled 3D serpentine structures can span a very broad range from zero to that of a straight ribbon. The analytical model can be used in design, fabrication, and application of versatile 3D serpentine structures to ensure their compatibility with the ultra-low rigidity biological tissues. A hierarchical 3D serpentine structure with ultra-low rigidity is presented to demonstrate the application of the analytical model.