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2022 ◽  
Author(s):  
Lihui Ou

Abstract A deeper mechanistic understanding on CH3OH oxidation on Pt-Ru alloys with different Ru surface compositions is provided by DFT-based theoretical studies in this paper. The present results show that alloying and surface compositions of Ru can change CH3OH oxidation pathway and activity. The optimal surface composition of Ru is speculated to be ca. 50% since the higher Ru surface composition can lead to formation of carbonaceous species that can poison surface. Our present calculated Ru surface composition of ca. 50% exhibits excellent consistency with experimental studies. The origin of enhanced catalytic activity of Pt-Ru alloys is determined. The significantly decreased surface work functions after alloying suggest more electrons are transferred into adsorbates. The calculated lower electrode potentials after alloying imply that lower overpotentials are required for CH3OH oxidation. The excellent inconsistency with experimental study on decreased onset potentials after alloying further confirms accuracy of our present calculated results.


Materials ◽  
2021 ◽  
Vol 14 (22) ◽  
pp. 6870
Author(s):  
Dong-Chan Kang ◽  
Jeong-Nyeon Kim ◽  
Ik-Keun Park

In the study, an acoustic sensor for a high-resolution acoustic microscope was fabricated using zinc oxide (ZnO) piezoelectric ceramics. The c-cut sapphire was processed into a lens shape to deposit a ZnO film using radio frequency (RF) magnetron sputtering, and an upper and a lower electrode were deposited using E-beam evaporation. The electrode was a Au thin film, and a Ti thin film was used as an adhesion layer. The surface microstructure of the ZnO film was observed using a scanning electron microscope (SEM), the thickness of the film was measured using a focused ion beam (FIB) for piezoelectric ceramics deposited on the sapphire wafer, and the thickness of ZnO was measured to be 4.87 μm. As a result of analyzing the crystal growth plane using X-ray diffraction (XRD) analysis, it was confirmed that the piezoelectric characteristics were grown to the (0002) plane. The sensor fabricated in this study had a center frequency of 352 MHz. The bandwidth indicates the range of upper (375 MHz) and lower (328 MHz) frequencies at the −6 dB level of the center frequency. As a result of image analysis using the resolution chart, the resolution was about 1 μm.


Nanomaterials ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 2931
Author(s):  
Evgenii Aleksandrovich Kononov ◽  
Mikhail Mikhailovich Vasiliev ◽  
Elena Valeryevna Vasilieva ◽  
Oleg Fedorovich Petrov

The results of a study on particles’ surfaces after being exposed to the near-electrode region of a radio frequency (RF) discharge are presented. It was experimentally displayed that metal starts being deposited on the surface of particles levitating above the lower electrode of the discharge chamber after switching the RF discharge on. For melamine-formaldehyde (MF) particles, the appearance of an island metal coating is observed after 30 min of plasma exposure. Eroded electrodes and elements of the gas discharge chamber may serve as a source of deposited material. In addition, an analysis of the surface and composition of particles placed on the upper electrode after 6 h of plasma exposure is presented. We reveal that the composition and structure of the particle coating changes during the experiment. The MF particles under exposure become eroded, and needle-like structures containing metals are formed on their surface. We also observe the formation of columnar structures from the products of erosion of electrodes on particles with a metal coating.


Actuators ◽  
2021 ◽  
Vol 10 (11) ◽  
pp. 285
Author(s):  
Zhen Lv ◽  
Muhammad Uzair ◽  
Xinjie Wang ◽  
Yafeng Liu

In this paper, a novel photovoltaic-electrostatic hybrid actuator with a slant lower electrode based on the PLZT ceramic is proposed. The mathematical model of photovoltaic-electrostatic hybrid actuator is established. Then, based on the mathematical model of photovoltaic-electrostatic hybrid actuator and the parameters identified, the mathematical simulation of the closed-loop displacement control for the photovoltaic-electrostatic hybrid actuator based on the PLZT ceramic is carried out. The results show that the displacement of the actuator can be controlled successfully at a particular value within the pull-in displacement by the light source. Furthermore, the response speed of the output displacement for photovoltaic-electrostatic hybrid actuator with a slant lower electrode is faster than that with a parallel lower electrode, offering a good potential to advance the current applications on micro-electro-mechanical system.


2021 ◽  
pp. 2141014
Author(s):  
Yue-Peng Zeng ◽  
Chiang-Lung Lin ◽  
Jung-Chou Hung ◽  
Cheng-Fu Yang

Electrical discharge machining (EDM) is one of the importantly non-traditional processing technologies employed for ceramics’ surface processing. Modeling and optimization of the EDM process are essentially applied to find and obtain the optimal values of the responses for materials having smaller surface roughness, higher removing rate of materials, lower electrode wear rate. In this study, the Grey-Taguchi system with AHP weighting was applied in order to optimize the multi-responses of the EDM processing for ceramics. When the EDM processing was used in the ZrO2 ceramics for adhesive metal foils, the multi-response gray relational grade for the optimal level of machining parameter was 0.2685, which was higher than those using the initial experimental conditions. This study has proven that using the Grey-Taguchi system method with AHP weighting to find a model with a highly efficient standard for optimizing differently advanced machining processes is profitable.


2021 ◽  
Vol 4 (1) ◽  
pp. 30
Author(s):  
Marius Pustan ◽  
Corina Birleanu ◽  
Florina Serdean

The influence of the driving electrode positions on the dynamic response of polysilicon MEMS resonators used in biosensing applications is studied as a function of the operating conditions (vacuum versus free-air operating mode). The scope of this research work is orientated towards identifying the effect of driving electrode position on the dynamic response of sensing MEMS used in biomass detection. The mass-deposition detection is based on the change in the resonant frequency of vibrating elements considering a biological detection film deposited on the oscillating structure. The operating conditions, such as medium pressure, change the behavior of the dynamic response including the resonant frequency, the amplitude, and the velocity of oscillations as well as the quality factor and the loss of energy. The change in the dynamic response of the investigated MEMS cantilevers as a function of the lower electrode position and operating conditions is evaluated using a Polytec Laser Vibrometer. The decrease in the amplitude and velocity of the oscillations if the lower electrode is moved from the beam free-end toward the beam anchor is experimentally monitored. The changes in the response of samples in vacuum are slightly influenced by the electrode position compared with the response of the same sample in ambient conditions. Moreover, the effect of oscillating modes (first, second and third modes) is taken into consideration to improve the dynamical detection of the investigated samples. The obtained results indicate that different responses of MEMS resonators can be achieved if the position of the driving electrode is moved from the cantilever free-end toward the anchor. Indeed, the resonator stiffness, velocity and amplitude of oscillations are significantly modified for samples oscillating in ambient conditions for biological detection compared with their response in vacuum.


2021 ◽  
Vol 11 (5) ◽  
pp. 2079
Author(s):  
Cecilia Piferi ◽  
Ruggero Barni ◽  
H. Eduardo Roman ◽  
Claudia Riccardi

In this study, we examine the statistical properties of asymmetric surface dielectric barrier discharges (SDBD) produced by applying a periodic high voltage between two conducting displaced electrodes, located at the opposite sides of a flat dielectric panel. Here, the asymmetry refers to the fact that the lower electrode is fully covered with an insulating material, while the upper one, glued onto the dielectric surface, is otherwise left exposed to the air. Such a configuration allows the formation of a thin layer of plasma above the insulating surface. A single cycle signal consists of two well-separated half-cycle patterns, denoted as forward and backward strokes, corresponding to positive and negative voltages, respectively. They display a quite complex discharge pattern constituted by a sequence of individual peaks (bursts) of varying current and time duration. Specifically, we find that backward stroke bursts carry a positive mean charge Q≃0.3 nC and mean current I≃35 mA, with a mean duration τ≃15 ns, while forward stroke bursts have a negative mean charge Q≃−0.1 nC, a mean current I≃−20 mA, and a mean duration τ≃11 ns. The statistical analysis suggests that power injection can be tailored to produce the active agents in the plasma needed for a particular application. We also determined discharge spatial correlation patterns from measurements of the associated stimulated optical emission. The optical excitations occur as a result of the ionizing effect of the electromagnetic waves which ignite the discharge, followed by the electric current flow. In particular, we point out that one of the phases of the discharge is compatible with a cathode directed streamer phenomenon (backward stroke), while the mechanism acting for a forward stroke has a different structure.


2021 ◽  
Vol 91 (4) ◽  
pp. 657
Author(s):  
С.Д. Полетаев ◽  
А.И. Любимов

This paper presents theoretical and experimental results on reactive ion etching of massive substrates in freon-14 with RF bias at the lower electrode. A hypothesis is proposed according to which a large-sized substrate violates the matching of the lower electrode with the RF generator by adding an additional reactive component to the impedance of the lower electrode. A numerical simulation of reactive ion etching with substrates of various sizes in a CF4 environment is performed . The simulation results showed a significant increase in the reactive component of RF power at the lower electrode if the substrate area exceeds 50% of the area of the lower electrode, which is consistent with the proposed hypothesis. It has been experimentally shown that the etching of massive substrates violates the matching of the lower electrode with the RF generator. A special design of the substrate holder for massive substrates has been developed. It is shown that such a substrate holder significantly improves the matching of the RF generator with the lower electrode, especially when adding 0.3-0.9 l/h argon to the plasma-forming mixture.


Author(s):  
С.Д. Полетаев ◽  
А.И. Любимов

The effect of metal masks on the matching of the lower electrode with a high-frequency bias generator during selective reactive-ion etching through the mask of massive substrates in freon-14 has been studied theoretically and experimentally. It is shown that masks with a substrate coating above 30% lead to an increase in the reactive power component at distances from the center close to the substrate radius. The absence of influence on the specific reactive power of the thickness and material of the masks is established. It is experimentally shown that masks with any practically significant coating coefficient of the substrate, connected to the lower electrode through the substrate holder, improve the matching, reducing the power reflection coefficient.


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