In any industry, attrition is a big problem, whether it is about employee attrition of an organization or customer attrition of an e-commerce site. If we can accurately predict which customer or employee will leave their current company or organization, then it will save much time, effort, and cost of the employer and help them to hire or acquire substitutes in advance, and it would not create a problem in the ongoing progress of an organization. In this chapter, a comparative analysis between various machine learning approaches such as Naïve Bayes, SVM, decision tree, random forest, and logistic regression is presented. The presented result will help us in identifying the behavior of employees who can be attired over the next time. Experimental results reveal that the logistic regression approach can reach up to 86% accuracy over other machine learning approaches.