Diamond and methane formation from the chemical decomposition of polyethylene at high pressures and temperatures

Polyethylene (C2H4)n was compressed to pressures between 10 and 30 GPa in a diamond anvil cell (DAC) and laser heated above 2500 K for approximately one second. This resulted in the chemical decomposition of the polymer into carbon and hydrocarbon reaction products. After quenching to ambient temperature, the decomposition products were measured in the DAC at pressures ranging from ambient to 29 GPa using a combination of x-ray diffraction (XRD) and small angle x-ray scattering (SAXS). XRD identified cubic diamond and methane as the predominant product species with their pressure–volume relationships exhibiting strong correlations to the diamond and methane equations of state. Length scales associated with the diamond products, obtained from SAXS measurements, indicate the formation of nanodiamonds with a radius of gyration between 12 and 35 nm consistent with 32–90 nm diameter spherical particles. These results are in good agreement with the predicted product composition under thermodynamic and chemical equilibrium.

Investigation of Laser Treatment as a Method for Fatigue Crack Growth Retardation in Aluminum Alloy 2198-T851

Among the third-generation Al-Li alloys, AA2198 stands out for its lower density, formability and increased stiffness, being suitable for use in aircraft fuselage sheets and other inner structures in order to reduce weight and improve performance. An important topic related to damage tolerant structures is the development of techniques to retard fatigue crack propagation, such as the localized heating by a laser source. The aim of the present work was to find the most suitable parameters for the production of laser heating lines in 2198-T851 alloy sheets in order to reduce the fatigue crack growth rate in this material. Laboratory tests using C(T) specimens under two loading conditions (R = 0.1 and 0.5) provided a useful dataset on the laser heated material. The experimental results indicate a 200 W laser beam power at treatment speeds of 1 and 10 mm/s was sufficient to retard crack growth in the current setup. The more expressive results were obtained for 200 W laser power with a speed of 1 mm/s and cyclic loading with stress ratio R = 0.1.

Self-thermophoresis of laser-heated spherical Janus particles

An analytic framework is presented for calculating the self-induced thermophoretic velocity of a laser-heated Janus metamaterial micro-particle, consisting of two conducting hemispheres of different thermal and electric conductivities. The spherical Janus is embedded in a quiescent fluid of infinite expanse and is exposed to a continuous light irradiation by a defocused laser beam. The analysis is carried under the electrostatic (Rayleigh) approximation (radius small compared to wavelength). The linear scheme for evaluating the temperature field in the three phases is based on employing a Fourier–Legendre approach, which renders rather simple semi-analytic expressions in terms of the relevant physical parameters of the titled symmetry-breaking problem. In addition to an explicit solution for the self-thermophoretic mobility of the heated Janus, we also provide analytic expressions for the slip-induced Joule heating streamlines and vorticity field in the surrounding fluid, for a non-uniform (surface dependent) Soret coefficient. For a ‘symmetric’ (homogeneous) spherical particle, the surface temperature gradient vanishes and thus there is no self-induced thermophoretic velocity field. The ‘inner’ temperature field in this case reduces to the well-known solution for a laser-heated spherical conducting colloid. In the case of a constant Soret phoretic mobility, the analysis is compared against numerical simulations, based on a tailored collocation method for some selected values of the physical parameters. Also presented are some typical temperature field contours and heat flux vectors prevailing in the two-phase Janus as well as light-induced velocity and vorticity fields in the ambient solute and a new practical estimate for the self-propelling velocity. Graphic abstract

Laser Heating Study of the High-Temperature Interactions in Nanograined Uranium Carbides

Nanograined nuclear materials are expected to have a better performance as spallation targets and nuclear fuels than conventional materials, but many basic properties of these materials are still unknown. The present work aims to contribute to their better understanding by studying the effect of grain size on the melting and solid–solid transitions of nanograined UC2−y. We laser-heated 4 nm–10 nm grain size samples with UC2−y as the main phase (but containing graphite and UO2 as impurities) under inert gas to temperatures above 3000 K, and their behavior was studied by thermal radiance spectroscopy. The UC2−y solidification point (2713(30) K) and α-UC2 to β-UC2 solid–solid transition temperature (2038(10) K) were observed to remain unchanged when compared to bulk crystalline materials with micrometer grain sizes. After melting, the composite grain size persisted at the nanoscale, from around 10 nm to 20 nm, pointing to an effective role of carbon in preventing the rapid diffusion of uranium and grain growth.

Growth and Characterization of Ce-Doped Luag Single Crystal Fibers from Transparent Ceramics by Laser-Heated Pedestal Method

Scintillation single crystal fibers (SCFs) have great potential applications in the new generation of high-energy ray and particle detectors due to their morphological advantages. In this work; Ce:LuAG SCFs with a diameter of 1 mm were grown along the direction of [111] by laser-heated pedestal growth (LHPG) method using a transparent ceramic as the source rod; and a doping concentration was 0.1 at%, 0.3 at%, 1 at%, respectively. The effects of growth rate and annealing in air on the scintillation and optical properties of SCF are discussed in detail. The results of analyzing the absorption spectra; radioluminescence (RL) spectra; pulse-height spectra and fluorescence lifetime of SCFs show that the SCF maintains excellent scintillation performance while having a fiber structure. Therefore; Ce:LuAG SCF is a potential candidate material for detector.

Bamboo Charcoal/Poly(L-lactide) Fiber Webs Prepared Using Laser-Heated Melt Electrospinning

Although several studies have reported that the addition of bamboo charcoal (BC) to polylactide (PLA) enhances the properties of PLA, to date, no study has been reported on the fabrication of ultrafine BC/poly(L-lactide) (PLLA) webs via electrospinning. Therefore, ultrafine fiber webs of PLLA and BC/PLLA were prepared using PLLA and BC/PLLA raw fibers via a novel laser electrospinning method. Ultrafine PLLA and BC/PLLA fibers with average diameters of approximately 1 μm and coefficients of variation of 13–23 and 20–46% were obtained. Via wide-angle X-ray diffraction (WAXD) analysis, highly oriented crystals were detected in the raw fibers; however, WAXD patterns of both PLLA and BC/PLLA webs implied an amorphous structure of PLLA. Polarizing microscopy images revealed that the webs comprised ultrafine fibers with uniform diameters and wide variations in birefringence. Temperature-modulated differential scanning calorimetry measurements indicated that the degree of order of the crystals in the fibers was lower and the molecules in the fibers had higher mobilities than those in the raw fibers. Transmittance of BC/PLLA webs with an area density of 2.6 mg/cm2 suggested that the addition of BC improved UV-shielding efficiencies.

Hot Carrier Photocurrent through MOS Structure

Flow of photocurrent through the metal-oxide-semiconductor structure induced by the pulsed infrared CO2 laser is investigated experimentally. In the case of a perfect insulator, the photocurrent has a photocapacitive character. Its rise is based on the hot carrier phenomenon; no carrier generation is present, only redistribution of laser-heated carriers takes place at the semiconductor surface. The magnitude of this displacement current is related to the capacitance of the structure and is dependent on the rate of the laser pulse change as well as on the laser light intensity. This effect can find application in the detection of fast infrared laser pulses as well as in the development of infrared photovaractors. Operation of such devices would not require cryogenic temperatures what is usually needed by the long-wavelength infrared semiconductor technique.

Melting line of calcium characterized by in situ LH-DAC XRD and first-principles calculations

In this work, the melting line of calcium has been characterized both experimentally, using synchrotron X-ray diffraction in laser-heated diamond-anvil cells, and theoretically, using first-principles calculations. In the investigated pressure and temperature range (pressure between 10 and 40 GPa and temperature between 300 and 3000 K) it was possible to observe the face-centred phase of calcium and to confirm (and characterize for the first time at these conditions) the presence of the body-centred cubic and the simple cubic phase of calcium. The melting points obtained with the two techniques are in excellent agreement. Furthermore, the present results agree with the only existing melting line of calcium obtained in laser-heated diamond anvil cells, using the speckle method as melting detection technique. They also confirm a flat slope of the melting line in the pressure range between 10 and 30 GPa. The flat melting curve is associated with the presence of the solid high-temperature body-centered cubic phase of calcium and to a small volume change between this phase and the liquid at melting. Reasons for the stabilization of the body-centered face at high-temperature conditions will be discussed.