Abstract
Heavy metal pollution and its environmental and human risks have become one of the most important global environmental problems. In the current study, the potential heavy metals ecological risks and their pollution status were assessed in five important harbors (Sidi Krir, Dekhila, Western, Damietta, and Port Said) along the Egyptian coast of the Mediterranean Sea. Twenty-six sediment samples were collected from five harbors, where eight heavy metals (Fe, Mn, Zn, Cu, Ni, Cr, Pb and Cd) were identified as well as their texture and geochemistry. To gain deeper insights into the human and ecological hazards of the heavy metals, thirteen ecological indices, sediment quality guidelines and multivariate analysis as well as two pathways of exposures to non- carcinogenic and carcinogenic risk of heavy metals for children and adults were evaluated. The data shown that Sidi Kriri harbor recorded the lowest values for heavy metals, for Cu, while Western Harbor had the highest average for Zn Multivariate analysis revealed the contribution of heavy metals to sediment contamination and the geochemical characteristics as well as nearby sources of pollution. Geo-accumulation index, Contamination factor, Toxic units, sum of toxic units, sediment modified hazard quotient, and sediment hazard quotients reflected the significant contribution of Cd to sediments along all harbors. Non-carcinogenic hazard risk index (HI) values along the harbors gave the order: Western> Port Said> Damietta> Dekhila> Sidi Krir. Also, TLCR values for children and adults indicated the irregularly high abundance of heavy metals in harbor sediments that may cause adverse public health effects.