Recent Advances in the Development of Highly Conductive Structured Supports for the Intensification of Non-adiabatic Gas-Solid Catalytic Processes: The Methane Steam Reforming Case Study

Structured catalysts are strong candidates for the intensification of non-adiabatic gas-solid catalytic processes thanks to their superior heat and mass transfer properties combined with low pressure drops. In the past two decades, different types of substrates have been proposed, including honeycomb monoliths, open-cell foams and, more recently, periodic open cellular structures produced by additive manufacturing methods. Among others, thermally conductive metallic cellular substrates have been extensively tested in heat-transfer limited exo- or endo-thermic processes in tubular reactors, demonstrating significant potential for process intensification. The catalytic activation of these geometries is critical: on one hand, these structures can be washcoated with a thin layer of catalytic active phase, but the resulting catalyst inventory is limited. More recently, an alternative approach has been proposed, which relies on packing the cavities of the metallic matrix with catalyst pellets. In this paper, an up-to-date overview of the aforementioned topics will be provided. After a brief introduction concerning the concept of structured catalysts based on highly conductive supports, specific attention will be devoted to the most recent advances in their manufacturing and in their catalytic activation. Finally, the application to the methane steam reforming process will be presented as a relevant case study of process intensification. The results from a comparison of three different reactor layouts (i.e. conventional packed bed, washcoated copper foams and packed copper foams) will highlight the benefits for the overall reformer performance resulting from the adoption of highly conductive structured internals.

Photobiocatalysis in Continuous Flow

In the last years, there were two fields that experienced an astonishing growth within the biocatalysis community: photobiocatalysis and applications of flow technology to catalytic processes. Therefore, it is not a surprise that the combination of these two research areas also gave place to several recent interesting articles. However, to the best of our knowledge, no review article covering these advances was published so far. Within this review, we present recent and very recent developments in the field of photobiocatalysis in continuous flow, we discuss several different practical applications and features of state-of-the art photobioreactors and lastly, we present some future perspectives in the field.

Plasmonic catalysis with designer nanoparticles

Catalysis is central to a more sustainable future and a circular economy. If the energy required to drive catalytic processes could be harvested directly from sunlight, the possibility of replacing...

Sustainability After Project Completion: Evidence from the GEF

This chapter examines the extent to which completed GEF projects are sustainable and the factors affecting sustainability. We considered only those projects that were covered through postcompletion evaluation at least 2 years after implementation completion, and where the evaluation reports provided adequate information related to observed sustainability during the postcompletion period. We assessed 62 projects to meet the selection criteria, then completed a desk review of the postcompletion evaluation reports and other relevant documents for these projects to assess the extent to which the project outcome was sustainable.We found that the projects covered through postcompletion evaluations were generally sustainable, with the sustainability outlook deteriorating for some projects while improving for others. The incidence of the catalytic processes that enhance sustainability—sustaining, mainstreaming, replication, scaling-up, and market change—was higher at postcompletion evaluation, as the passage of time allows long-term project outcomes to manifest. At the project level, we observed these catalytic processes in a wider set of activities at postcompletion evaluation than at implementation completion. Factors such as financial support for follow-up, political support, follow-up by and capacities of the executing agency, stakeholder buy-in, and project design seem to play a crucial role in determining project sustainability.

Selective Catalytic Reduction of NOx Over Hierarchical Cu-ZSM-5 Coated on Ceramic Foam Support

The development of structured catalysts for process intensification is of growing interest in catalytic processes due to heat and mass transfer limitations at an industrial scale. This limitation can be...