Export of ice sheet meltwater from Upernavik Fjord, West Greenland

Meltwater from Greenland is an important freshwater source for the North Atlantic Ocean, released into the ocean at the head of fjords in the form of runoff, submarine melt and icebergs. The meltwater release gives rise to complex in-fjord transformations that result in its dilution through mixing with other water masses. The transformed waters, which contain the meltwater, are exported from the fjords as a new water mass “Glacially Modified Water” (GMW). Here we use summer hydrographic data collected from 2013 to 2019 in Upernavik, a major glacial fjord in northwest Greenland, to describe the water masses that flow into the fjord from the shelf and the exported GMWs. Using an Optimum Multi-Parameter technique across multiple years we then show that GMW is composed of 57.8 ±8.1% Atlantic Water, 41.0 ±8.3% Polar Water, 1.0 ±0.1% subglacial discharge and 0.2 ±0.2% submarine meltwater. We show that the GMW fractional composition cannot be described by buoyant plume theory alone since it includes lateral mixing within the upper layers of the fjord not accounted for by buoyant plume dynamics. Consistent with its composition, we find that changes in GMW properties reflect changes in the AW and PW source waters. Using the obtained dilution ratios, this study suggests that the exchange across the fjord mouth during summer is on the order of 50 mSv (compared to a freshwater input of 0.5 mSv). This study provides a first order parameterization for the exchange at the mouth of glacial fjords for large-scale ocean models.

Experimental Quantification of the Lateral Mixing of Binary Solids in Bubbling Fluidized Beds

A novel experimental method for the lateral mixing of binary solids in bubbling fluidized beds was developed based on the capacitance probe technique. The evolutions of local mixing ratios in a fluidized bed which can be assumed as one mixing cell were analyzed in detail. The solids mixing within one mixing cell was resolved and the effect of convection and diffusion mechanism on lateral mixing was evaluated individually. The results show that at lower part of the fluidized bed, convection plays a more important role in the mixing process near the wall; meanwhile, diffusion is very important for the mixing around the center line. This is opposite with that at the higher part. A lateral micro dispersion coefficient was proposed to characterize the lateral mixing within the mixing cell and the value is generally between 0.005 and 0.025 m/s. A new mixing index was proposed to evaluate the lateral mixing quality of binary solids. It was found that at the lower part of the fluidized bed, the best mixing is acquired at the half radius, whereas mixing at the center line is the worst. At the higher part, solid mixing is better when increasing the distance from the wall. The influences of gas velocity and static bed on the lateral mixing were also discussed from a microscopic perspective.

Modelling of long-term Zn, Cu, Cd and Pb dynamics from soils fertilised with organic amendments

Soil contamination by trace elements (TEs) is a major concern for sustainable land management. A potential source of excessive inputs of TEs into agricultural soils are organic amendments. Here, we used dynamic simulations carried out with the Intermediate Dynamic Model for Metals (IDMM) to describe the observed trends of topsoil Zn (zinc), Cu (copper), Pb (lead) and Cd (cadmium) concentrations in a long-term (>60-year) crop trial in Switzerland, where soil plots have been treated with different organic amendments (farmyard manure, sewage sludge and compost). The observed ethylenediaminetetraacetic acid disodium salt (EDTA)-extractable concentrations ranged between 2.6 and 27.1 mg kg−1 for Zn, 4.9 and 29.0 mg kg−1 for Cu, 6.1–26.2 mg kg−1 for Pb, and 0.08 and 0.66 mg kg−1 for Cd. Metal input rates were initially estimated based on literature data. An additional, calibrated metal flux, tentatively attributed to mineral weathering, was necessary to fit the observed data. Dissolved organic carbon fluxes were estimated using a soil organic carbon model. The model adequately reproduced the EDTA-extractable (labile) concentrations when input rates were optimised and soil lateral mixing was invoked to account for the edge effect of mechanically ploughing the trial plots. The global average root mean square error (RMSE) was 2.7, and the average bias (overestimation) was −1.66, −2.18, −4.34 and −0.05 mg kg−1 for Zn, Cu, Pb and Cd, respectively. The calibrated model was used to project the long-term metal trends in field conditions (without soil lateral mixing), under stable climate and management practices, with soil organic carbon estimated by modelling and assumed trends in soil pH. Labile metal concentrations to 2100 were largely projected to remain near constant or to decline, except for some metals in plots receiving compost. Ecotoxicological thresholds (critical limits) were predicted to be exceeded presently under sewage sludge inputs and to remain so until 2100. Ecological risks were largely not indicated in the other plots, although some minor exceedances of critical limits were projected to occur for Zn before 2100. This study advances our understanding of TEs' long-term dynamics in agricultural fields, paving the way to quantitative applications of modelling at field scales.

Circulation timescales of Atlantic Water in the Arctic Ocean determined from anthropogenic radionuclides

The inflow of Atlantic Water to the Arctic Ocean is a crucial determinant for the future trajectory of this ocean basin with regard to warming, loss of sea ice, and ocean acidification. Yet many details of the fate and circulation of these waters within the Arctic remain unclear. Here, we use the two long-lived anthropogenic radionuclides 129I and 236U together with two age models to constrain the pathways and circulation times of Atlantic Water in the surface (10–35 m depth) and in the mid-depth Atlantic layer (250–800 m depth). We thereby benefit from the unique time-dependent tagging of Atlantic Water by these two isotopes. In the surface layer, a binary mixing model yields tracer ages of Atlantic Water between 9–16 years in the Amundsen Basin, 12–17 years in the Fram Strait (East Greenland Current), and up to 20 years in the Canada Basin, reflecting the pathways of Atlantic Water through the Arctic and their exiting through the Fram Strait. In the mid-depth Atlantic layer (250–800 m), the transit time distribution (TTD) model yields mean ages in the central Arctic ranging between 15 and 55 years, while the mode ages representing the most probable ages of the TTD range between 3 and 30 years. The estimated mean ages are overall in good agreement with previous studies using artificial radionuclides or ventilation tracers. Although we find the overall flow to be dominated by advection, the shift in the mode age towards a younger age compared to the mean age also reflects the presence of a substantial amount of lateral mixing. For applications interested in how fast signals are transported into the Arctic's interior, the mode age appears to be a suitable measure. The short mode ages obtained in this study suggest that changes in the properties of Atlantic Water will quickly spread through the Arctic Ocean and can lead to relatively rapid changes throughout the upper water column in future years.

Thermal Chains and Entrainment in Cumulus Updrafts. Part I: Theoretical Description

Recent studies have shown that cumulus updrafts often consist of a succession of discrete rising thermals with spherical vortex-like circulations. In this paper, a theory is developed for why this “thermal chain” structure occurs. Theoretical expressions are obtained for a passive tracer, buoyancy, and vertical velocity in axisymmetric moist updrafts. Analysis of these expressions suggests that the thermal chain structure arises from enhanced lateral mixing associated with intrusions of dry environmental air below an updraft’s vertical velocity maximum. This dry-air entrainment reduces buoyancy locally. Consequently, the updraft flow above levels of locally reduced buoyancy separates from below, leading to a breakdown of the updraft into successive discrete thermals. The range of conditions in which thermal chains exist is also analyzed from the theoretical expressions. A transition in updraft structure from isolated rising thermal, to thermal chain, to starting plume occurs with increases in updraft width, environmental relative humidity, and/or convective available potential energy. Corresponding expressions for the bulk fractional entrainment rate ε are also obtained. These expressions indicate rather complicated entrainment behavior of ascending updrafts, with local enhancement of ε up to a factor of ~2 associated with the aforementioned environmental-air intrusions, consistent with recent large-eddy simulation (LES) studies. These locally large entrainment rates contribute significantly to overall updraft dilution in thermal chain-like updrafts, while other regions within the updraft can remain relatively undilute. Part II of this study compares results from the theoretical expressions to idealized numerical simulations and LES.

Spatial Structure, Short-temporal Variability, and Dynamical Features of Small River Plumes as Observed by Aerial Drones: Case Study of the Kodor and Bzyp River Plumes

Quadcopters can continuously observe ocean surface with high spatial resolution from relatively low altitude, albeit with certain limitations of their usage. Remote sensing from quadcopters provides unprecedented ability to study small river plumes formed in the coastal sea. The main goal of the current work is to describe structure and temporal variability of small river plumes on small spatial and temporal scales, which are limitedly covered by previous studies. We analyze optical imagery and video records acquired by quadcopters and accompanied by synchronous in situ measurements and satellite observations within the Kodor and Bzyp plumes, which are located in the northeastern part of the Black Sea. We describe extremely rapid response of these river plume to energetic rotating coastal eddies. We reveal several types of internal waves within these river plumes, measure their spatial and dynamical characteristics, and identify mechanisms of their generation. We suggest a new mechanism of formation of undulate fronts between small river plumes and ambient sea, which induces energetic lateral mixing across these fronts. The results reported in this study are addressed for the first time as previous related works were mainly limited by low spatial and/or temporal resolution of in situ measurements and satellite imagery.

Circulation timescales of Atlantic Waters in the Arctic Ocean determined from anthropogenic radionuclides

The inflow of Atlantic Waters to the Arctic Ocean is a crucial determinant for the future trajectory of this ocean basin with regard to warming, loss of sea-ice and ocean acidification. Yet many details of the fate and circulation of these waters within the Arctic remain unclear. Here, we use the two long-lived artificial radionuclides 129I and 236U together with two tracer age models to constrain the pathways and circulation times of Atlantic waters in the surface and in the mid-depth Atlantic layer (250–800 m depth). We thereby benefit from the unique time-dependent tagging of Atlantic waters by these two isotopes. In the surface layer, a binary mixing model yields tracer ages of Atlantic Waters between 9–16 years in the Amundsen Basin, 12–17 years in the Fram Strait (East Greenland Current) and up to 20 years in the Canada Basin, reflecting the pathways of Atlantic Waters through the Arctic and their exiting through Fram Strait. In the mid-depth Atlantic layer (250 to 800 m), the transit time distribution (TTD) model yields mean ages in the central Arctic ranging between 15 and 65 years, while the mode ages representing the most probable ages of the TTD range between 2 and 30 years. The estimated mean ages are overall in good agreement with previous studies using artificial radionuclides or ventilation tracers. Although we find the overall flow to be dominated by advection, the shift of the mode age towards a younger age compared to the mean age reflects also the presence of a substantial amount of lateral mixing. For applications interested in how fast signals are transported into the Arctic's interior, the mode age appears to be a suitable measure. The short mode ages obtained in this study suggest that changes in the properties of Atlantic Waters will quickly spread through the Arctic Ocean and can lead to relatively rapid changes throughout the upper water column in future years.