Tunable electron and hole injection channels at plasmonic Al-TiO2 interfaces

Metallic nanostructures can strongly absorb light through their plasmon excitations, whose nonradiative decay generates hot electron-hole pairs. When the metallic nanostructure is interfaced with a semiconductor, the spatial separation of...

Plasmon-driven photocatalytic molecular transformations on metallic nanostructure surfaces: mechanistic insights gained from plasmon-enhanced Raman spectroscopy

This Review Article elaborates on the insights gained from in situ plasmon-enhanced Raman spectroscopy, which shed light on the complex mechanisms underpinning plasmon-driven photocatalytic molecular transformations on nanostructured metal surfaces.

White nanolight source for optical nanoimaging

Nanolight sources, which are based on resonant excitation of plasmons near a sharp metallic nanostructure, have attracted tremendous interest in the vast research fields of optical nanoimaging. However, being a resonant phenomenon, this ideally works only for one wavelength that resonates with the plasmons. Multiple wavelengths of light in a broad range confined to one spot within a nanometric volume would be an interesting form of light, useful in numerous applications. Plasmon nanofocusing can generate a nanolight source through the propagation and adiabatic compressions of plasmons on a tapered metallic nanostructure, which is independent of wavelength, as it is based on the propagation, rather than resonance, of plasmons. Here, we report the generation of a white nanolight source spanning over the entire visible range through plasmon nanofocusing and demonstrate spectral bandgap nanoimaging of carbon nanotubes. Our experimental demonstration of the white nanolight source would stimulate diverse research fields toward next-generation nanophotonic technologies.