phosphorous compounds
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2021 ◽  
Vol 13 (20) ◽  
pp. 11337
Author(s):  
Krzysztof Stępniewski ◽  
Maksym Łaszewski

The influence of various types of agricultural activities on the dynamics of biogenic compounds of flowing water was broadly recognized in many spatial and temporal scales. However, relatively minor attention was paid to the hydrochemical functioning of horticultural catchments despite their importance and dominance in some regions of Europe. Thus, the current study investigated spatial and seasonal variations in inorganic nitrogen and phosphorous compounds in stream water in the Mogielanka River catchment, with 72% covered by apple orchards. Water samples were collected from fifteen sites distributed across the catchment in the monthly timescale from March 2020 to February 2021. Concentrations of NO3−, NO2−, NH4+, and PO43− were determined photometrically, while in situ water temperature, oxygen saturation, electrical conductivity, and pH, were measured with the use of portable devices. The impact of horticulture was mainly documented in the higher concentration of NO3− during the winter months; however, maximum values did not exceed 15 mg·dm−3 and were relatively low in comparison to catchments dominated by arable lands. The authors also found a clear impact of unstratified reservoirs and inflows from wastewater treatment plants on the dynamics of biogenic compounds. The correlations of PO43− with the sums of precipitation suggested, in turn, that increased PO43− concentration mainly results from poor sewage management. The results provided preliminary but unique and spatially extensive insight into the functioning of an orchard-dominated lowland catchment and allowed the researchers to point out the main recommendations for improving water quality in similar regions.


2021 ◽  
pp. 125529
Author(s):  
Helena Khatoon ◽  
Kwan Penz Penz ◽  
Sanjoy Banerjee ◽  
Mohammad Redwanur Rahman ◽  
Tashrif Mahmud Minhaz ◽  
...  

2021 ◽  
Author(s):  
Stefano Pantaleone ◽  
Marta Corno ◽  
Albert Rimola ◽  
Nadia Balucani ◽  
Piero Ugliengo

<p>Phosphorous is ubiquitous in planet Earth and plays a fundamental role in all living systems. Finding a reasonable prebiotic source of phosphorous is not trivial, as common sources where it is present nowadays are in the form of phosphate minerals, which are rather insoluble and non-reactive materials, and, accordingly, unavailable for being readily incorporated in living organisms. A possible source of phosphorous is from the exogenous meteoritic bombardment and, in particular, in iron/nickel phosphites. These materials, by simple interaction with water, produce oxygenated phosphorous compounds, which can easily react with organic molecules, thus forming C-O-P bonds. In the present work, periodic ab-initio simulations at PBE level (inclusive of dispersive interactions) have been carried out on metallic Fe<sub>2</sub>NiP-schreibersite, as a relative abundant component of metallic meteorites, in order to characterize structural, energetics and vibrational properties of both bulk and surfaces of this material. The aim is to study the relative stability among different surfaces, to characterize both the nanocrystal morphology and the reactivity towards water molecules. </p>


Author(s):  
Federico Battista ◽  
Chiara Masala ◽  
Anita Zamboni ◽  
Zeno Varanini ◽  
David Bolzonella

Abstract This work investigates an innovative process to valorise agricultural digestate by the exploitation of solar energy. Digestate has been located in a lab-scale greenhouse to evaporate the liquid phase. Digestate vapours, rich in ammonia, are sent in a Drechsler trap, filled with 38% w/w sulfuric acid solution, through three solar air fans. A concentration of about 2 M of ammonium sulphate solution was recovered. The remaining dried solid phase, rich in phosphorous compounds, was evaluated as alternative to the commercial fertilizers (46% P2O5) in the growth of maize plants. Equal amount of P was applied to each pot (25 mg/kg soil). The plants were evaluated along the 8 weeks in a greenhouse monitoring the growth parameters and leaf SPAD index, micro-, macronutrients and non-essential heavy metals. The results evidenced that the dried solid phase of digestate can be used as an alternative source of P. Graphic Abstract


2021 ◽  
Author(s):  
Stefano Pantaleone ◽  
Marta Corno ◽  
Albert Rimola ◽  
Nadia Balucani ◽  
Piero Ugliengo

<p>Phosphorous is ubiquitous in planet Earth and plays a fundamental role in all living systems. Finding a reasonable prebiotic source of phosphorous is not trivial, as common sources where it is present nowadays are in the form of phosphate minerals, which are rather insoluble and non-reactive materials, and, accordingly, unavailable for being readily incorporated in living organisms. A possible source of phosphorous is from the exogenous meteoritic bombardment and, in particular, in iron/nickel phosphites. These materials, by simple interaction with water, produce oxygenated phosphorous compounds, which can easily react with organic molecules, thus forming C-O-P bonds. In the present work, periodic ab-initio simulations at PBE level (inclusive of dispersive interactions) have been carried out on metallic Fe<sub>2</sub>NiP-schreibersite, as a relative abundant component of metallic meteorites, in order to characterize structural, energetics and vibrational properties of both bulk and surfaces of this material. The aim is to study the relative stability among different surfaces, to characterize both the nanocrystal morphology and the reactivity towards water molecules. </p>


2021 ◽  
Author(s):  
Stefano Pantaleone ◽  
Marta Corno ◽  
Albert Rimola ◽  
Nadia Balucani ◽  
Piero Ugliengo

<p>Phosphorous is ubiquitous in planet Earth and plays a fundamental role in all living systems. Finding a reasonable prebiotic source of phosphorous is not trivial, as common sources where it is present nowadays are in the form of phosphate minerals, which are rather insoluble and non-reactive materials, and, accordingly, unavailable for being readily incorporated in living organisms. A possible source of phosphorous is from the exogenous meteoritic bombardment and, in particular, in iron/nickel phosphites. These materials, by simple interaction with water, produce oxygenated phosphorous compounds, which can easily react with organic molecules, thus forming C-O-P bonds. In the present work, periodic ab-initio simulations at PBE level (inclusive of dispersive interactions) have been carried out on metallic Fe<sub>2</sub>NiP-schreibersite, as a relative abundant component of metallic meteorites, in order to characterize structural, energetics and vibrational properties of both bulk and surfaces of this material. The aim is to study the relative stability among different surfaces, to characterize both the nanocrystal morphology and the reactivity towards water molecules. </p>


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Bo Lin ◽  
Anthony Chun Yin Yuen ◽  
Timothy Bo Yuan Chen ◽  
Bin Yu ◽  
Wei Yang ◽  
...  

AbstractRecent discoveries of two-dimensional transitional metal based materials have emerged as an excellent candidate for fabricating nanostructured flame-retardants. Herein, we report an eco-friendly flame-retardant for flexible polyurethane foam (PUF), which is synthesised by hybridising MXene (Ti$$_3\hbox {C}_2$$ 3 C 2 ) with biomass materials including phytic acid (PA), casein, pectin, and chitosan (CH). Results show that coating PUFs with 3 layers of CH/PA/Ti$$_3\hbox {C}_2$$ 3 C 2 via layer-by-layer approach reduces the peak heat release and total smoke release by 51.1% and 84.8%, respectively. These exceptional improvements exceed those achieved by a CH/Ti$$_3\hbox {C}_2$$ 3 C 2 coating. To further understand the fundamental flame and smoke reduction phenomena, a pyrolysis model with surface regression was developed to simulate the flame propagation and char layer. A genetic algorithm was utilised to determine optimum parameters describing the thermal degradation rate. The superior flame-retardancy of CH/PA/Ti$$_3\hbox {C}_2$$ 3 C 2 was originated from the shielding and charring effects of the hybrid MXene with biomass materials containing aromatic rings, phenolic and phosphorous compounds.


Small Methods ◽  
2021 ◽  
pp. 2001068
Author(s):  
Yue Zhang ◽  
Taojian Fan ◽  
Sijie Yang ◽  
Fakun Wang ◽  
Sanjun Yang ◽  
...  

ScienceRise ◽  
2020 ◽  
pp. 66-72
Author(s):  
Sergii Shamanskyi ◽  
Sergii Boichenko ◽  
Lesia Pavliukh

The object of research: the process of wastewater treatment using bioconversion for subsequent motor fuel production. Investigated problem: improving the efficiency of bioconversion process for biofuel production with simultaneous wastewater treatment by removing nitrogen and phosphorous compounds. The main scientific results: providing the possibility of biofuel production with energy and economic inefficiency. It is done by combining the process of motor biofuel production with the process of treating wastewater from biogenic elements makes it perspective for commercial use. Traditional technology for the production of motor biofuels from microalgae includes cultivation, harvesting, dehydration and drying of biomass, extraction of oils from them and subsequent production of methyl esters and glycerol. Such technology is often not economically effective. It requires significant amount of energy for carrying out all necessary processes. In addition, it requires significant expenditures of water and nutrients. The use of nutrient-rich wastewater as a culture medium for the cultivation of microalgae allows not only to reduce costs, but also to purify wastewater from nitrogen and phosphorus compounds, which makes this process economically effective. The area of practical use of the research results: Sewage and gray water treatment plants. Industrial and agricultural effluents treatment plants. Different types of enterprises, which have wastewater enriched with nitrogen and phosphorous compounds. Innovative technological product: The technology of microalgae cultivation using wastewater as a culture medium. The technology allows effectively purifying used wastewaters from nitrogen and phosphorous compounds with no waste at the end. Scope of the innovative technological product: Improved technology of motor biofuel production with simultaneous wastewater purification, which is economically effective and environmentally safe.


Molecules ◽  
2020 ◽  
Vol 25 (17) ◽  
pp. 3779
Author(s):  
Aloshy Baby ◽  
Svetlana Tretsiakova-McNally ◽  
Malavika Arun ◽  
Paul Joseph ◽  
Jianping Zhang

Polystyrene, despite its high flammability, is widely used as a thermal insulation material for buildings, for food packaging, in electrical and automotive industries, etc. A number of modification routes have been explored to improve the fire retardance and boost the thermal stability of commercially important styrene-based polymeric products. The earlier strategies mostly involved the use of halogenated fire retardants. Nowadays, these compounds are considered to be persistent pollutants that are hazardous to public and environmental health. Many well-known halogen-based fire retardants, regardless of their chemical structures and modes of action, have been withdrawn from built environments in the European Union, USA, and Canada. This had triggered a growing research interest in, and an industrial demand for, halogen-free alternatives, which not only will reduce the flammability but also address toxicity and bioaccumulation issues. Among the possible options, phosphorus-containing compounds have received greater attention due to their excellent fire-retarding efficiencies and environmentally friendly attributes. Numerous reports were also published on reactive and additive modifications of polystyrene in different forms, particularly in the last decade; hence, the current article aims to provide a critical review of these publications. The authors mainly intend to focus on the chemistries of phosphorous compounds, with the P atom being in different chemical environments, used either as reactive, or additive, fire retardants in styrene-based materials. The chemical pathways and possible mechanisms behind the fire retardance are discussed in this review.


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