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2022 ◽  
Author(s):  
Marco Yseki ◽  
Bruno Turcq ◽  
Sandrine Caquineau ◽  
Renato Salvatteci ◽  
José Solis ◽  
...  

Abstract. Reconstructing precipitation and wind from the geological record could help to understand the potential changes in precipitation and wind dynamics in response to climate change in Peru. The last deglaciation offers natural experimental conditions to test precipitation and wind dynamics response to high latitude forcing. While considerable research has been done to reconstruct precipitation variability during the last deglaciation in the Atlantic sector of South America, the Pacific sector of South America has received little attention. This work aims to fill this gap by reconstructing types of terrigenous transport to the central-southern Peruvian margin (12° S and 14º S) during the last deglaciation (18–13 kyr BP). For this purpose, we used grain-size distribution in sediments of marine core M77/2-005-3 (Callao, 12º S) and G14 (Pisco, 14º S). We analyzed end-members (EM) to identify grain-size components and reconstruct potential sources and transport processes of terrigenous material across time. We identified four end-members for both Callao and Pisco sediments. In Callao, we propose that changes in EM4 (101 μm) and EM2 (58 μm) contribution mainly reflect hydrodynamic energy and diffuse sources, respectively, while EM3 (77 um) and EM1 (11 μm) variations reflect changes in aeolian and fluvial inputs, respectively. In Pisco, changes in the contribution of EM1 (10 μm) reflect changes in river inputs while EM2 (52 μm), EM3 (75 μm) and EM4 (94 μm) reflect an aeolian origin linked to surface winds. At millennial-scale, our record shows an increase of the fluvial inputs during the last part of Heinrich Stadial 1 (~ 16–14.7 kyr BP) at both locations. This increase was linked to higher precipitation in Andes related to a reduction of the Atlantic Meridional Overturning Circulation and meltwater discharge in North Atlantic. In contrast, during Bølling-Allerød (~ 14.7–13 kyr BP), there was an aeolian input increase, associated with stronger winds and lower precipitation that indicate an expansion of the South Pacific Subtropical High. These conditions would correspond to a northern displacement of the Intertropical Convergence Zone-South Subtropical High system associated with a stronger Walker circulation. Our results suggest that variations in river discharge and changes in surface wind intensity in the western margin of South America during the last deglaciation were sensitive to Atlantic Meridional Overturning Circulation variations and Walker circulation on millennial timescales. In the context of global warming, large-scale precipitation and fluvial discharge increases in the Andes related to Atlantic Meridional Overturning Circulation decline and southward displacement of the Intertropical Convergence Zone should be considered.


2022 ◽  
Vol 312 ◽  
pp. 108734
Author(s):  
Han Chen ◽  
Jinhui Jeanne Huang ◽  
Sonam Sandeep Dash ◽  
Edward McBean ◽  
Han Li ◽  
...  

2021 ◽  
Vol 25 (12) ◽  
pp. 6261-6281
Author(s):  
Maxime Gillet ◽  
Corinne Le Gal La Salle ◽  
Pierre Alain Ayral ◽  
Somar Khaska ◽  
Philippe Martin ◽  
...  

Abstract. The increasing severity of hydrological droughts in the Mediterranean basin related to climate change raises the need to understand the processes sustaining low flow. The purpose of this paper is to evaluate simple mixing model approaches, first to identify and then to quantify streamflow contribution during low-water periods. An approach based on the coupling of geochemical data with hydrological data allows the quantification of flow contributions. In addition, monitoring during the low-water period was used to investigate the drying-up trajectory of each geological reservoir individually. Data were collected during the summers of 2018 and 2019 on a Mediterranean river (Gardon de Sainte-Croix). The identification of the end-members was performed after the identification of a groundwater geochemical signature clustered according to the geological nature of the reservoir. Two complementary methods validate further the characterisation: rock-leaching experiments and unsupervised classification (k-means). The use of the end-member mixture analysis (EMMA) coupled with a generalised likelihood uncertainty estimate (GLUE) (G-EMMA) mixing model coupled with hydrological monitoring of the main river discharge rate highlights major disparities in the contribution of the geological units, showing a reservoir with a minor contribution in high flow becoming preponderant during the low-flow period. This finding was revealed to be of the utmost importance for the management of water resources during the dry period.


2021 ◽  
Vol 5 (1) ◽  
Author(s):  
Aleksandar Matković ◽  
Lukas Ludescher ◽  
Oleg E. Peil ◽  
Apoorva Sharma ◽  
Kevin-P. Gradwohl ◽  
...  

AbstractIntrinsically magnetic layered materials – especially monolayers – suffer from the lack of ambient stability and mostly exhibit magnetic ordering only at cryogenic temperatures. These restrains impose a great challenge for the integration of two-dimensional magnetic materials into future technologies. We propose to overcome this by exploiting phyllosilicates, such as iron-rich talc. Via combined magnetic force microscopy in applied external magnetic fields, superconducting quantum interference device magnetometry, first-principle calculations, and structural analysis, we demonstrate that incorporated iron ions in talc are in a very robust high spin state, resulting in a weak ferromagnetic behavior at room temperature. Iron-rich talc can be thinned down to a monolayer, remaining fully stable under ambient conditions, and retaining magnetic properties even in monolayers. Finally, we propose iron-rich end members of the phyllosilicates as very promising platforms for air-stable magnetic monolayers.


2021 ◽  
pp. 1-9
Author(s):  
Fuyuan Gao ◽  
Junhuai Yang ◽  
Shuyuan Wang ◽  
Youjun Wang ◽  
Kaiming Li ◽  
...  

Abstract The mid-latitude Westerlies (MLW) are one of the most important atmospheric circulation systems in the Northern Hemisphere, exerting a huge influence on the climate of the region downwind, and thus on vegetation, water resources, and human wellbeing. However, the seasonal variation of the MLW during the Holocene is not yet been fully understood, especially when its contribution is the most important. Here, we used end-member (EM) modeling analysis of the grain-size distributions of a high-altitude aeolian sedimentary sequence (4452 m a.s.l.) from the Yarlung Zangbo River valley in the southern Tibetan Plateau to reveal variations in the winter MLW during the Holocene. Analysis of seasonal differences in modern atmospheric circulation suggests that the southern Tibetan Plateau was heavily influenced by the mid-latitude Westerlies at the 400, 500, and 600 hPa levels in winter, while it was seldom influenced at these levels in summer. Four grain-size end-members are identified, representing distinct aerodynamic environments, of which EM1 (modal grain size 8.1 μm) can be used as a proxy of the winter MLW. A reconstruction of the variation of the winter MLW during the Holocene based on EM1 revealed that a weaker winter MLW occurred during the Early to Middle Holocene, and a stronger winter MLW during the Middle to Late Holocene. Overall, we suggest that this change in the winter MLW was closely related to the insolation/temperature/pressure gradient between low and high latitudes in the Northern Hemisphere.


2021 ◽  
Vol 7 (11) ◽  
pp. 151
Author(s):  
Andrei N. Salak ◽  
João Pedro V. Cardoso ◽  
Joaquim M. Vieira ◽  
Vladimir V. Shvartsman ◽  
Dmitry D. Khalyavin ◽  
...  

The phase content and sequence, the crystal structure, and the magnetic properties of perovskite solid solutions of the (1−y)BiFeO3–yBiZn0.5Ti0.5O3 series (0.05 ≤ y ≤ 0.90) synthesized under high pressure have been studied. Two perovskite phases, namely the rhombohedral R3c and the tetragonal P4mm, which correspond to the structural types of the end members, BiFeO3 and BiZn0.5Ti0.5O3, respectively, were revealed in the as-synthesized samples. The rhombohedral and the tetragonal phases were found to coexist in the compositional range of 0.30 ≤ y ≤ 0.90. Magnetic properties of the BiFe1−y[Zn0.5Ti0.5]yO3 ceramics with y < 0.30 were measured as a function of temperature. The obtained compositional variations of the normalized unit-cell volume and the Néel temperature of the BiFe1−y[Zn0.5Ti0.5]yO3 perovskites in the range of their rhombohedral phase were compared with the respective dependences for the BiFe1−yB3+yO3 perovskites (where B3+ = Ga, Co, Mn, Cr, and Sc). The role of the high-pressure synthesis in the formation of the antiferromagnetic states different from the modulated cycloidal one characteristic of the parent BiFeO3 is discussed.


Geosphere ◽  
2021 ◽  
Author(s):  
Tanya Furman ◽  
Barry B. Hanan ◽  
Megan Pickard Sjoblom ◽  
Biltan Kürkcüoğlu ◽  
Kaan Sayit ◽  
...  

We present new Sr-Nd-Pb-Hf isotopic data on mafic lavas from the Sivas, Develidağ, Erciyes, and Erkilet volcanic complexes in central Turkey and Tendürek in eastern Turkey to evaluate the mantle sources for volcanism in the context of the geodynamic evolution of the Anatolian microplate. Early Miocene through Quaternary volcanism in Western Anatolia and latest Miocene through Quaternary activity in Central Anatolia were dominated by contributions from two distinct source regions: heterogeneous metasomatized or subduction-modified lithosphere, and roughly homogeneous sublithospheric ambient upper mantle; we model the source contributions through mixing between three end members. The sublithospheric mantle source plots close to the Northern Hemisphere reference line (NHRL) with radiogenic 206Pb/204Pb of ~19.15, while the other contributions plot substantially above the NHRL in Pb isotope space. The lithospheric source is heterogeneous, resulting from variable pollution by subduction-related processes likely including direct incorporation of sediment and/or mélange; its range in radiogenic isotopes is defined by regional oceanic sediment and ultrapotassic melts of the subcontinental lithospheric mantle. The geochemical impact of this contribution is disproportionately large, given that subduction-modified lithosphere and/or ocean sediment dominates the Pb isotope signatures of mafic Anatolian lavas. Subduction of the Aegean or Tethyan seafloor, associated with marked crustal shortening, took place throughout the region until ca. 16–17 Ma, after which time broad delamination of the thickened lower crust and/or the Tethyan slab beneath Central Anatolia allowed for sediment and/or mélange and slab-derived fluids to be released into the overlying evolving modified mantle. Aggregation of melts derived from both mantle and lithospheric domains was made possible by upwelling of warm asthenospheric material moving around and through the complexly torn younger Aegean-Cyprean slab that dips steeply to the north beneath southern Anatolia.


2021 ◽  
Author(s):  
Richard Patience ◽  
Mark Bastow ◽  
Martin Fowler ◽  
Julian Moore ◽  
Craig Barrie

Abstract Production allocation from petroleum geochemistry is defined here as the quantitative determination of the amount or portion of a commingled fluid to be assigned to two or more individual fluid sources (e.g., a pipeline, field, reservoir, well) at a particular moment in time, based on the fluid chemistry. It requires: i) knowledge of the original chemical compositions of each of the fluids prior to mixing (referred to here as the "end members"), and ii) that statistically valid differences in their chemistries can be identified. Petroleum geochemical-based methods for production monitoring and allocation are much lower cost than using production logging tools, as there is no additional rig time or extra personnel required at the well site. Additionally, no intervention to the production of hydrocarbons from a well is required and, hence, there is none of the risk entailed in additional operational activity. Geochemical methods are applicable to a wide range of fields, irrespective of pressure, temperature, reservoir quality and reservoir fluid type. The method has been in existence for over 30 years, during which time a number of different analytical methods, data pre-processing and treatment approaches have been applied. This paper summarises these approaches, and provides examples, but also describes a "best practice" which is not a "one size fits all" approach, as is sometimes seen in the literature. A successful production allocation study consists of the following steps: i) Selection of end member samples that contribute to the commingled production fluid; ii) Determination of the differences in chemical composition of the end members through laboratory analysis of the end members (e.g. by WO-GC), replicate analyses of samples and statistical treatment of the data (e.g. PCA); iii) If statistically significant differences exist, laboratory analysis of the end members and commingled fluids with appropriate replicate analyses of samples; iv) Data selection, pre-processing (e.g. selection of ratios or concentrations of components); v) Determination of end member contributions by solving equations (e.g. least squares best fit) and uncertainty estimation (e.g. Monte Carlo or Bootstrap methods). The differences in approach for conventional versus unconventional plays are also discussed.


2021 ◽  
Author(s):  
Dwaipayan Deb ◽  
Pavan Chakraborty

Abstract Surfaces of solid solar system objects are covered by layers of particulate materials called regolith originated from their surface bedrock. They preserve important information about surface geological processes. Often regolith is composed of more than one type of particle in terms of composition, maturity, size, etc. Experiments and theoretical works are being carried out to constrain the result of mixing and extract the abundance of compositional end-members from regolith spectra. In this work we have studied, photometric light scattering from simulated surfaces made of two different materials – one is highly bright quartz particles ≈ 80µm and the other moderately bright sandstone particles ≈ 250µm. The samples were mixed with varying proportions and investigated at normal illumination conditions to avoid the shadowing effect. Said combinations may resemble ice mixed regolith on various solar system objects and therefore important for in situ observations. We find that the combinations show a linear trend in the corresponding reflectance data in terms of their mixing proportion and some interesting facts come out when compared to previous studies.


Author(s):  
Luis A. Villaescusa ◽  
Jian Li ◽  
Alvaro Mayoral ◽  
Zihao Rei Gao ◽  
Miguel A. Camblor

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