The Influence of Surface Quality on Flow Length and Micro-Mechanical Properties of Polycarbonate

This study describes the influence of polymer flow length on mechanical properties of tested polymer, specifically polycarbonate. The flow length was examined in a spiral shaped mould. The mould cavity’s surface was machined by several methods, which led to differing roughness of the surface. The cavity was finished by milling, grinding and polishing. In order to thoroughly understand the influence of the mould surface quality on the flow length, varying processing parameters, specifically the pressure, were used. The polymer part was divided into several segments, in which the micro-mechanical properties, such as hardness and indentation modulus were measured. The results of this study provide interesting data concerning the flow length, which was up to 3% longer for rougher surfaces, but shorter in cavities with polished surface. These results are in disagreement with the commonly practiced theory, which states that better surface quality leads to greater flow length. Furthermore, evaluation of the micro-mechanical properties measured along the flow path demonstrated significant variance in researched properties, which increased by 35% (indentation hardness) and 86% by indentation modulus) in latter segments of the spiral in comparison with the gate.

Internal Flow Optimization in a Complex Profile Extrusion Die Using Flow Restrictors and Flow Separators

The control of flow balance at the die exit is the key for successful extrusion of polymers. The complex cross-sectional variation in real-world hollow extrusion profiles intrinsically promotes flow imbalance in the die cavity. Special considerations are required for designing extrusion dies for such profiles. The die design for a complex door frame profile was computationally optimized in this study with the aid of a commercially available software package. The velocity distribution at the die exit, post-die extrudate deformation, temperature distribution, and pressure distribution of a traditional die was investigated in detail and found to be inadequate. A modified die incorporated three distinct features, flow restrictors, flow separators and approach angle of the torpedoes, to achieve a balanced and uniform velocity at the die exit. The flow restrictors and flow separators were added in the pre-parallel zone. Flow restrictors were added on top and bottom of the torpedoes to increase the restriction on polymer flow. A unique inclined flow restrictor was introduced to achieve uniform internal melt flow. Flow separators were added at junctions of outer wall and inner vertical walls to separate the polymer flow into different sections and minimize cross flow between these sections. The addition of these features proved to be highly effective for balancing the velocity distribution at the die exit. The combination of 3-D modeling and simulation is an effective cost and time efficient approach for optimizing complex die designs before manufacturing.

In Situ Visualization for Control of Nano-Fibrillation Based on Spunbond Processing Using a Polypropylene/Polyethylene Terephthalate System

In situ generation of polyethylene terephthalate (PET) nanofibrils in polypropylene (PP) microfibers via fiber spinning in a spunbond process was studied in this work. The effects of polymer flow rate and air speed in the drafter on the formation of PET fibrils were investigated using a pilot scale machine. An in-situ visualization technique was applied to examine the fiber evolution events and stretch profile at die exit. A scanning electron microscope was used to analyze and investigate the morphology of the dispersed domain. The PET dispersed phase was fibrillated within the PP matrix such that a nonofibrillated composite containing fibrils with an average size around 100 nm was obtained. It was found that the final fibril size directly depends on the degree of die swell, the air speed and the polymer flow rate. It was also found that the in situ observed size of the micro-scale PP/PET fibers was well correlated to the size of the nano-scale PET fibers formed in the PP matrix. The visualization results revealed that a smaller fibril diameter was obtainable by increasing the stretching on the spin line and/or decreasing the die swell.

Measurements of periodically perturbed dewetting force fields and their consequences on the symmetry of the resulting patterns

We studied the origin of breaking the symmetry for moving circular contact lines of dewetting polymer films suspended on a periodic array of pillars. There, dewetting force fields driving polymer flow were perturbed by elastic micro-pillars arranged in a regular square pattern. Elastic restoring forces of deformed pillars locally balance driving capillary forces and broke the circular symmetry of expanding dewetting holes. The observed envelope of the dewetting holes reflected the symmetry of the underlying pattern, even at sizes much larger than the characteristic period of the pillar array, demonstrating that periodic perturbations in a driving force field can establish a well-defined pattern of lower symmetry. For the presented system, we succeeded in squaring the circle.

Modeling and experimental study of pore structure in melt-blown fiber assembly

It is widely known that the pore size of a meltblown fiber assembly extensively affects the final applications of its products. We have developed a model for simulating melt-blowing production to investigate the formation mechanism of a fiber assembly. In this study, we calculated the pore size under different production conditions using the model. The predicted results reveal the relationship between the pore size and the production conditions, namely, the air jet pressure, suction pressure, die temperature, polymer flow rate, die to collector distance, and collector speed. The predicted results also verified the experimental trends reported in previous studies. High air jet pressure and die temperature tend to generate smaller pores, while a large polymer flow rate, die to collector distance, and collector movement speed contribute to the production of larger pores in the fiber assembly. In addition, the circularity was predicted in this study to describe the pore shape. The numerical investigation of virtual production is a novel method in which the expected pore size and corresponding production conditions can be easily obtained using a computer with a few keystrokes and mouse clicks.

Modeling and Numerical Simulation of Laminated Thermoplastic Composites Manufactured by Laser-Assisted Automatic Tape Placement

A comprehensive numerical model is developed for the simulation of the laser-assisted automated tape placement process of carbon fiber/thermoplastic composites. After being heated with a laser, the thermoplastic is welded with the help of a consolidation roller onto a substrate made up of layers of tapes bonded onto one another. Under the pressure applied by the roller, the thermoplastic flows and the tape reaches its final thickness. The numerical model is developed in three sequential steps that can be used to identify the required pressure and temperature distribution to achieve a good bond. Firstly, a heat transfer simulation is performed to determine the temperature distribution into the incoming tape under the consolidation roller. Secondly, a rheological model is developed to examine the polymer flow under the roller and to obtain the pressure field. Finally, the consolidation level between the substrate and the tape is investigated through the degree of intimate contact, which is related to the processing parameters such as the roller velocity, the laser power density and the compaction force.