Development of rainfall – runoff model for extreme storm events in the Bagmati River Basin, Nepal

This study is based on the Bagmati river basin that flows along with the capital city, Kathmandu which is a small and topographically steep basin. Major flood occurring in 1993 and 2002 as stated in the report of DWIDP shows that the basin is subjected to water-induced disaster in monsoon season affecting people and property. This study focuses on the development of a rainfall-runoff model for Bagmati basin in HEC-HMS using the Synthetic Unit Hydrograph (SUH) with Khokana as the outlet. The coefficients for SUH like Lag time coefficient (Ct), peak discharge coefficient (Cp), unit hydrograph widths at 50% and 75% of peak and base time were determined calibrating the Synder’s equation where Ct varies from 0.244 to 1.016 and Cp varies from 0.439 to 0.410. The rainfall-runoff model in HEC-HMS has been calibrated from daily data of 1992-2013 and validated from hourly data for July 2011, August 2012, and July 2013. Furthermore, the model has been tested to compare the discharge for various return periods with the observed ones which are in close agreement. The determination of Peak Maximum Flood (PMF) using the calculated Peak Maximum Precipitation (PMP) is also another application of the model which can be used to design various hydraulic structures. Thus the values of coefficients, Ct and Cp can be used to construct unit hydrograph for the basin. Moreover, the satisfactory performance of the model during calibration and validation proves the applicability of the model in flood forecasting and early warning.

Influence of Players’ Maximum Running Speed on the Team’s Ranking Position at the End of the Spanish LaLiga

The maximum running speed that a football player can attain during match play has become one of the most popular variables to assess a player’s physical talent. However, the influence of a player’s maximum running speed on football performance has not yet been properly investigated. The aim of this study was to determine the influence of a player’s peak/maximum running speed on the team’s ranking position at the end of a national league. A second aim was to investigate differences in maximum running speed among playing positions. To fulfil this aim, the peak/maximum running speeds of 475 male professional football players were recorded for 38 fixtures of the Spanish first-division league (LaLiga) from the 2017–2018 season (7838 data points). Players’ peak running speeds in each match were assessed with a validated multicamera tracking system and associated software (Mediacoach®). Players’ maximum running speed was established as the fastest running speed they attained during the entire season. Most players (53.5% of the total) had a maximum running speed in the range of 32.0–33.9 km/h, with only three players (0.6%) with a maximum running speed of over 35.0 km/h. Overall, forwards were faster than defenders and both types of players were faster than midfielders (33.03 ± 1.35 > 32.72 ± 1.32 > 32.08 ± 1.63 km/h; p < 0.001). There was no association between teams’ maximum running speed and ranking position at the end of the league (r = −0.356, p = 0.135). The correlations between teams’ maximum speeds and ranking position were low for defenders (r = −0.334, p = 0.163), midfielders (r = 0.125, p = 0.610), and forwards (r = −0.065, p = 0.791). As a result, the variance in the ranking position at the end of the season explained by a team’s maximum speed was of only 7.5%. Finally, as an average for all teams, players’ peak running speeds remained stable at ~30.7 ± 0.6 km/h throughout the whole season. These results suggest that successful and less successful football teams have squads with players able to obtain similar maximum running speeds during match play throughout the season. Hence, players’ maximum running speeds have a poor association with the team’s ranking position at the end of the Spanish professional national league.

Modeling electrochromic poly-dioxythiophene-containing materials through TDDFT

Here we report the first colormetric model using mPW1PBE/cc-PVDZ with CPCM to predict the chemical properties of three electrochromic polymers in which the largest UV-Vis absolute peak maximum difference when compared to experiment was 14 nm.

Biomechanical Behaviors in Three Types of Spinal Cord Injury Mechanisms

Clinically, spinal cord injuries (SCIs) are radiographically evaluated and diagnosed from plain radiographs, computed tomography (CT), and magnetic resonance imaging. However, it is difficult to conclude that radiographic evaluation of SCI can directly explain the fundamental mechanism of spinal cord damage. The von-Mises stress and maximum principal strain are directly associated with neurological damage in the spinal cord from a biomechanical viewpoint. In this study, the von-Mises stress and maximum principal strain in the spinal cord as well as the cord cross-sectional area (CSA) were analyzed under various magnitudes for contusion, dislocation, and distraction SCI mechanisms, using a finite-element (FE) model of the cervical spine with spinal cord including white matter, gray matter, dura mater with nerve roots, and cerebrospinal fluid (CSF). A regression analysis was performed to find correlation between peak von-Mises stress/peak maximum principal strain at the cross section of the highest reduction in CSA and corresponding reduction in CSA of the cord. Dislocation and contusion showed greater peak stress and strain values in the cord than distraction. The substantial increases in von-Mises stress as well as CSA reduction similar to or more than 30% were produced at a 60% contusion and a 60% dislocation, while the maximum principal strain was gradually increased as injury severity elevated. In addition, the CSA reduction had a strong correlation with peak von-Mises stress/peak maximum principal strain for the three injury mechanisms, which might be fundamental information in elucidating the relationship between radiographic and mechanical parameters related to SCI.

Dodenuclear [MnIII8LnIII4] clusters with 2-(hydroxymethyl)pyridine: syntheses, structures, and magnetic properties

Dodenuclear Mn/Ln clusters with 2-(hydroxymethyl)pyridine as a ligand have been synthesized. Complexes 1 and 5 showed a frequency-dependent decrease in χ′MT and an out-of-phase χ′′M peak maximum, indicating slow magnetic relaxation and potential SMM behaviour.