Application of local Monte Carlo method in neutronics calculation of EAST radial neutron camera

The Local Monte Carlo (LMC) method is used to solve the problems of deep penetration and long time in the neutronics calculation of the Radial Neutron Camera (RNC) diagnostic system on the Experimental Advanced Superconducting Tokamak (EAST), and the radiation distribution of the RNC and the neutron flux at the detector positions of each channel are obtained. Compared with the results calculated by the Global Variance Reduction (GVR) method, it is shown that the LMC calculation is reliable within the reasonable error range. The calculation process of LMC is analyzed in detail, and the transport process of radiation particles is simulated in two steps. In the first step, an integrated neutronics model considering the complex window environment and a neutron source model based on EAST plasma shape are used to support the calculation. The particle information on the equivalent surface is analyzed to evaluate the rationality of settings of equivalent surface source and boundary. Based on the characteristic that only a local geometric model is needed in the second step, it is shown that the LMC is an advantageous calculation method for the nuclear shielding design of tokamak diagnostic systems.

Magnetic Aromaticity of Cycloporphyrin Nanorings

The ascertainment of magnetic aromaticity is not necessarily straightforward, especially for large and bent systems, such as the cycloporphyrin nanorings recently synthesized by the group of Anderson. Six of these cycloporphyrin nanorings were studied here computationally. Indirect methods, based on nuclear shielding and magnetizabilities, and direct methods, based on standard quantum mechanics, were both used effectively to determine their magnetically induced current strength, which mostly confirmed Anderson’s classification. However, in the case of hexanions, and in particular for cyclohexaporphyrin hexacations, a significant cancellation of delocalized diatropic and paratropic flow occurred, showing that the resultant faint aromatic character was a result of competing aromatic and antiaromatic contributions, as also evidenced by the ipsocentric method. A warning is renewed on the use of isotropic shielding to determine the tropicity of the magnetically induced current.