Analytical Study for Chlorpyrifos Breakdown Derivatives Qualification After Silver Vanadate (Agvo3) Nanoparticles Fragmentation Reaction

The use of pesticides in agriculture has become one of the basic necessities to meet the world's food requirements as a result of the continuous population increase. But sometimes the use of some of these pesticides in large quantities and in high concentrations poses a great danger to the environment and then to humans. Through weather factors, pesticides are transferred to the water and then harm aquatic organisms, which leads to a direct impact and harm to the fish wealth. Monitoring these compounds in the environment requires a large cost of time and money to ensure food safety. Therefore, a new method was used in this study in an attempt to get rid of these compounds in water. The silver vanadate nanoparticles (AgVO3) were synthesized using a novel method in an attempt to eliminate different groups of pesticides that had been detected in Egyptian agricultural crops and water. The effect of 0.1 g of AgVO3 nanoparticles were found on three compounds: chlorpyrifos, dimethoate and malathion. Where a concentration of these compounds, which is 0.5 mg / kg, was used and it was estimated using Exion HPLC coupled with Sciex Qtrap API 6500 + LC-MS/MS System. After 15 minutes of treatment with 0.1 g of AgVO3 nanoparticles, these compounds were undetectable on the device's chromatogram, which is regarded a short period in Affecting these compounds and changing their nature in an attempt to get rid of them. Determination of chlorpyrifos breakdown products by using mass scan of Qtrap API 6500 + LC-MS/MS System and Thermo Scientific Q Exactive Focus Orbitrap LC-MS/MS System was investigated. Supported AgVO3 NPs, according to the study, could be used in long-term environmental remediation because they can be used in aqueous solutions at room temperature without the need for additional stimulus such as UV light.

Optimized Tin Bismuth Alloy Modified with Silver Vanadate Nanorods Prepared via Powder Metallurgy: Search for Biomedical Application

In this study, a new bismuth tin eutectic alloy and other samples of the same composition doped with variable concentration of silver vanadate nanorods were prepared using new route powder metallurgy. X-ray diffraction of prepared silver vanadate approves the formation of  phase silver vanadate (-AgVO3). Transmission electron microscopy shows the formation of AgVO3 nanorods of radius ranging (20-40 nm). X-ray diffraction of alloys doped with silver vanadate and mechanical tests show that hardness and creep behavior data are composition-dependent parameters with silver vanadate content. Antimicrobial tests against pathogenic grams, fungi, and yeast showed that the addition of silver vanadate nanorods stimulates the action of hydride alloy and increases their activity against bacterial strains. In hospitals, biomedical devices may contaminate infection; doping devices with nanoparticles may make it auto clean besides conserving its mechanical properties.