Solid-state Thermoelectric Characteristics of NiII, FeII, CoII, and CuII Borohydrides

Four transition metal borohydrides (MTBHs, MT = Ni, Fe, Co, and Cu) were prepared by sonicating a mixture of the desired MT salt with excess NaBH4 in a nonaqueous DMF/CH3OH media. The process afforded bimetallic (Ni-BH4), trimetallic (Fe-BH4, Co-BH4), and mixed-valence (Cu-H, Cu-BH4) amorphous, ferromagnetic nanoparticles as identified by thermal, ATR-IR, X-Ray diffraction, and magnetic susceptibility techniques. The electrical conductivity (σ) of cold-pressed discs of these MTBHs shows a nonlinear increase while their thermal conductivity (κ) decreases in the temperature range of 303 ≤ T ≤ 373 K. The thermal energy transport occurs through phonon lattice dynamics rather than electronic. The σ/κ ratio shows a nonlinear steep increase from 9.4 to 270 KV-2 in Ni-BH4, while a moderate-weak increase is observed for Fe-BH4, Co-BH4, and Cu-BH4. Accordingly, the corresponding thermoelectric (TE) parameters S, PF, ZT, and η were evaluated. All TE data shows that the bimetallic Ni-BH4 (S, 80 μVK-1; PF, 259 μWm-1K-2; ZT 0.64; η, 2.56%) is a better TE semiconductor than the other three MT-BHs investigated in this study. Our findings show that Ni-BH4 is a promising candidate to exploit low-temperature waste heat from body heat, sunshine, and small domestic devices for small-scale TE applications.

Three-Dimensional Ballistic-Diffusive Heat Transport in Silicon: Transient Response and Thermal Conductivity

Phonons are the main contributors to thermal energy transfer in thin films. The size dependence of the thermal transport characteristics alters the film properties such as thermal conductivity. Hence, in the present study, three-dimensional, transient phonon transport in dielectric material is studied through the Equation of Phonon Radiative Transport (EPRT) to assess the size dependence of thermal conductivity. The numerical scheme is introduced solving the EPRT in three dimensions and the governing algorithm is described in detail. A parametric study is carried out examining the effect of the \mathrm{Kn} number on the thermal energy transport characteristics in three-dimensional thermally excited film. The formulation and estimation of the effective thermal conductivity tensor is presented and discussed, thereby extending, to some extent, the one-dimensional results obtained earlier. We demonstrate that thermal conductivity changes in all directions, depending on the size effect. In addition, the directions of the temperature gradient and heat flux vectors differ as the \mathrm{Kn} number approaches unity.

Numerical Simulation on Convection and Thermal Radiation of Casson Fluid in an Enclosure with Entropy Generation

The goal of the current numerical simulation is to explore the impact of aspect ratio, thermal radiation, and entropy generation on buoyant induced convection in a rectangular box filled with Casson fluid. The vertical boundaries of the box are maintained with different constant thermal distribution. Thermal insulation is executed on horizontal boundaries. The solution is obtained by a finite volume-based iterative method. The results are explored over a range of radiation parameter, Casson fluid parameter, aspect ratio, and Grashof number. The impact of entropy generation is also examined in detail. Thermal stratification occurs for greater values of Casson liquid parameters in the presence of radiation. The kinetic energy grows on rising the values of Casson liquid and radiation parameters. The thermal energy transport declines on growing the values of radiation parameter and it enhances on rising the Casson fluid parameter.

National Energy and Climate Plans: Importance of Synergy

In the modern world, including the European Union, the Baltic States and Latvia, the power industry has a broad definition, area and content, several social life and economic existence, comfort and safety provision. It also covers the following segments: heat/thermal energy, transport/fuel, electricity, energy resources and their types, etc. More competent and wider synergy among different energy sectors and power industry and other areas provides the option to solve the global problems, for example, the mitigation of climate changes and the provision of energy sustainability by reducing the production of greenhouse gases, increasing the use of renewable energy sources, achieving higher energy efficiency and providing the careful use of energy resources. The results of synergy are of economic importance; they provide the efficiency and competitiveness of costs. In this paper, the necessity of synergy between renewables and conventional generation and synergy among energy sectors are considered to achieve the dimensions of national energy and climate plans.